U.S. patent number 3,696,627 [Application Number 05/107,105] was granted by the patent office on 1972-10-10 for liquid cryogen transfer system.
This patent grant is currently assigned to Air Products and Chemicals, Inc.. Invention is credited to Ralph C. Longsworth.
United States Patent |
3,696,627 |
Longsworth |
October 10, 1972 |
LIQUID CRYOGEN TRANSFER SYSTEM
Abstract
A system for transferring a cryogenic liquid from a storage
vessel to a remote point of use at a constant temperature, pressure
and flow rate wherein the transfer tube is jacketed with a second
tube along substantially its entire length and these tubes are
enclosed in an evacuated jacket. Use of a nozzle in the second tube
entry end causes the liquid entering the jacket to decrease in
pressure and temperature thereby subcooling the liquid in the
transfer tube to prevent said liquid from boiling. The jacketing
fluid absorbs heat entering the transfer system from the
atmosphere. Included in the system as accessories are an adaptor
for attaching the system to the storage vessel in pressure tight
relationship and flow control on the delivery end of the
system.
Inventors: |
Longsworth; Ralph C.
(Allentown, PA) |
Assignee: |
Air Products and Chemicals,
Inc. (Allentown, PA)
|
Family
ID: |
22314866 |
Appl.
No.: |
05/107,105 |
Filed: |
January 18, 1971 |
Current U.S.
Class: |
62/48.1 |
Current CPC
Class: |
F17C
9/00 (20130101); F17C 2250/0636 (20130101); F17C
2221/014 (20130101); F17C 2205/0382 (20130101); F17C
2205/0323 (20130101); F17C 2223/047 (20130101); F17C
2223/0161 (20130101); F17C 2250/0626 (20130101) |
Current International
Class: |
F17C
9/00 (20060101); F17c 007/02 () |
Field of
Search: |
;62/45,50,52,51,55,514 |
References Cited
[Referenced By]
U.S. Patent Documents
Primary Examiner: Perlin; Meyer
Assistant Examiner: Capossela; Ronald C.
Claims
I claim:
1. A cryogenic transfer system for transferring a liquid cryogen
from a storage container to a remote point of use with the liquid
being delivered at constant temperature pressure and flow rate
comprising:
a liquid transfer conduit having a first end disposed in a source
of liquid cryogen and a second end with a nozzle therein for
delivering the liquid cryogen to a point of use;
surrounding said liquid transfer conduit in spaced relation thereto
a second conduit, said second conduit extending for substantially
the length of said liquid transfer conduit;
a nozzle on one end of said second conduit the end containing the
nozzle disposed within the liquid inventory of the source of liquid
cryogen;
surrounding said second conduit containing said liquid transfer
conduit and in spaced relationship thereto an outer jacket, said
outer jacket being in vacuum tight relationship to said transfer
and second conduits;
means for venting said second conduit outwardly of said jacket;
and
means for connecting said transfer system in pressure tight
relationship to said cryogen storage container.
2. A cryogenic transfer system according to claim 1 wherein there
is included valve means to vary the flow of liquid cryogen at the
delivery end of the system.
3. A cryogenic transfer system according to claim 1 wherein the
means for venting said second conduit includes a separate conduit
for returning said second conduit flow to a point near the cryogen
storage end of the system for venting.
4. A cryogenic transfer system according to claim 1 wherein there
is provided a multilayer insulation surrounding said conduits.
5. A cryogenic transfer system comprising
a first liquid cryogen transfer conduit having a supply end
disposed in a cryogen supply vessel and a delivery end for
providing cryogen at a point of use;
a nozzle in the delivery end of the liquid cryogen transfer
conduit;
a second conduit spaced apart from said first conduit and
concentric therewith for substantially the length of said first
conduit;
said second conduit being in fluid tight relation to the first
conduit and including a nozzle at the end adjacent the supply end
of the first conduit;
a jacket surrounding a substantial length of the first and second
conduits and forming a vacuum tight closure around the
conduits;
a third conduit extending from the delivery end of the second
conduit to a point near the supply end of the second conduit and
outwardly of the jacket to form a vent;
an adaptor to fix the system to a cryogen supply vessel in pressure
tight relation thereto; and means for metering the flow of liquid
cryogen at the supply end of the system.
6. A system according to claim 5 wherein the metering includes a
variable needle valve attached to the supply end of the system.
7. A system according to claim 6 including a heat exchanger on the
delivery end of the system.
8. A system according to claim 7 wherein the heat exchanger is
disposed between the needle valve and means for supporting an
object to be cooled by the cryogen, the object supporting means
including a control heater in contact with the heat exchanger.
Description
BACKGROUND OF THE INVENTION
This invention pertains to liquid cryogen transfer systems for
transferring a liquid cryogen from a storage vessel to a remote
point of use. U. S. Pat. No. 3,433,028 and 3,364,689 are examples
of cryogenic transfer lines that are known in the art. Transfer
lines such as this are produced in smaller diameter versions for
use in transferring a liquid cryogen, e.g., helium, from a storage
dewar to a remote point of use such as instruments and the like
used for infrared spectrophotometry.
In building a transfer system for use with instruments requiring a
liquid cryogen for cooling it is desirable to deliver the liquid to
the point of use at a very low flow rate but with a constant flow
rate. In the past this has been extremely difficult because the
cryogen vaporizes resulting in what is known as "vapor binding" in
the transfer line. This "vapor binding" results from the gas
bubbles having a greater volume than the liquid thus forming a
temporary block in the transfer line. This causes pressure to build
up in the line to the point where the liquid is actually forced
back into the storage dewar. At the delivery end of the transfer
line the fluid is delivered in spurts with accompanying pressure
and temperature cycling. The "vapor binding" results from heat
leaking into the transfer line from the atmosphere and has been
found with systems employing vacuum and solid type insulation
between the actual liquid transfer tube and the outer jacket.
SUMMARY OF THE INVENTION
In order to avoid the above described problems, and to, in general,
provide an improved transfer system it has been discovered that if
the liquid cryogen is caused to flow in a separate conduit
surrounding the actual cryogen transfer conduit of the system for
substantially the length of the transfer conduit that this second
source of cryogen acts as a shield fluid to the initial transfer
conduit absorbing heat and preventing "vapor binding" in the
transfer line. The second conduit surrounding the transfer conduit
is provided with a nozzle in the end that is disposed in the source
of liquid cryogen to provide for a pressure and temperature drop in
the shield gas as it flows along the outer surface of the transfer
conduit thereby subcooling the liquid in the center transfer
conduit and preventing boiling thereof. The fluid in the annular
space around the transfer conduit absorbs the energy radiated and
conducted to the transfer line and evaporates as it proceeds from
the supply end to the delivery end of the transfer system. The
shield gas conduit is then vented outwardly of the covering jacket
of the transfer system. It has also been found that the transfer
system can be coupled to the source of the liquid cryogen by a
special adaptor so that the normal boiling off of the cryogen in
the storage vessel causes pressurization of the liquid cryogen to
aid in steady state flow. It has also been found that a needle
valve at the delivery end can be used to control the flow of the
liquid cryogen and a heat exchanger in combination with the needle
valve can be used to provide multiposition orientation of the
delivery end of the transfer system.
Therefore it is the primary object of this invention to provide an
improved liquid cryogen transfer system.
It is another object of this invention to provide a liquid cryogen
transfer system that employs the liquid cryogen as a shield gas to
prevent vaporization of the cryogen in the transfer tube.
It is still another object of this invention to provide a liquid
cryogen transfer system that can be used in combination with
self-pressurization of the storage vessel and metered flow at the
delivery end of the transfer system.
It is yet another object of this invention to provide a cryogen
transfer system wherein the actual transfer tube can be of small
diameter to make the entire transfer system flexible.
BRIEF DESCRIPTION OF THE DRAWING
FIG. 1 is a cross sectional schematic diagram of the transfer
system according to the present invention shown in operating
position on a cryogenic storage vessel.
FIG. 2 is a section taken along line 2--2 of FIG. 1.
FIG. 3 is an enlarged schematic of the delivery end of the
cryogenic transfer system shown in conjunction with the needle
valve and heat exchanger system.
DESCRIPTION OF THE PREFERRED EMBODIMENT
Referring to FIG. 1 there is shown a cryogenic transfer system 10
disposed with a cryogenic storage vessel 12 such as commonly
referred to as a dewar wherein there is a quantity of cryogenic
fluid 14.
The transfer system comprises a central transfer tube 16 that is
disposed within the cryogenic fluid 14 and which actually transfers
the cryogen from the dewar 12 to the remote point of use (not
shown). Surrounding the transfer tube 16 is a complimentary tube 18
spaced apart from the tube 16 and held in fluid tight relation
thereto. At the lower end 20, which is also referred to as the
supply end of the cryogen transfer system, there is a nozzle 22.
The tube 18 extends for almost the entire length of the actual
cryogen transfer tube 16. At the delivery end 24 of the surrounding
tube 18 there is a return conduit 26 which returns toward the
supply end 20 of the conduit 18 and then exits outwardly of the
jacket 28 through a suitable fitting 30. The entire system is
covered by the jacket 28 which is in vacuum tight relationship to
the inner conduits. The jacket 28 can be rigid but it also can be
fabricated from flexible metallic coverings as are well known. The
flexible metallic covering is preferred especially if the entire
transfer line is to be flexible which can be accomplished by using
small diameter conduits for the transfer tube 16 and the shield gas
tube 18 and return tube 26. The end of transfer tube or conduit 16
that projects through the upper end 29 of jacket 28 contains a
nozzle 31. A preferred method of achieving a flexible transfer
system is disclosed in U.S. Pat. application Ser. No. 106,167 filed
Jan. 13, 1971 and owned by the assignee of the present
application.
The transfer system 10 is disposed in dewar 12 by means of a dewar
adaptor 32. The dewar adaptor 32 includes a housing 34 which
communicates with the neck 36 of dewar 12 and is held in fluid
tight relation therewith. Included within housing 34 is sealing
means 38 including O-ring sealing devices 40 as are well known in
the art. Included with housing 34 is a conduit 42 and a pressure
release valve 46 to prevent over pressurization of the system.
In operation the dewar is fitted with the adaptor 32 and the
transfer system 10 thereby enabling the vaporizing cryogen in the
dewar to increase the pressure inside the dewar and force liquid
into both tubes 16 and 18. The nozzle 31 in conduit 16 is included
to assure that the cryogen fluid in conduit 16 remains at the
pressure inside dewar 12, thereby maintaining its boiling point
above the boiling point of the cryogenic fluid in tube 18. As the
cryogen enters tube 18 through nozzle 22 it drops in both
temperature and pressure. The net effect of this drop in
temperature and pressure is to subcool the liquid in tube 16 and
thus prevent that liquid from boiling. For example at a dewar
pressure of 2.5 psig liquid helium would have a boiling temperature
of 4.4.degree.K. At essentially atmospheric pressure (inside tube
18) the helium has a boiling temperature of 4.2.degree.K. The
liquid flowing in the annulus defined by tubes 16 and 18 also
absorbs any energy radiated or conducted to the transfer line by
evaporating the liquid as it proceeds from the supply end 22 to
delivery end 24 of conduit 18. The liquid plus vapor is then
conducted by a conduit 26 outwardly of the vacuum jacket 28 through
the fitting 30. Because the cryogen flowing in the annulus defined
by conduits 16 and 18 intercepts all heat leaking into the transfer
line it is referred to as a shield gas conduit. The shield gas flow
is a non-steady flow as a result of this heat input. However, if
sufficient shield gas flow is present so that it is in a saturated
state as it is vented through port 30 the cryogen flowing in
conduit 16 will be subcooled and will be pure liquid.
With the device of FIG. 1 and 2 it is possible to achieve a steady
flow of cryogenic liquid in the transfer line at a very low flow
rate. Because the liquid is delivered in a saturated or subcooled
state the size of a vacuum pump required to get to sub-atmospheric
saturation pressure in the vessel to which the liquid is delivered
is minimized. The fact that small cryogen transfer tubes can be
used minimizes heat leak and allows for the system to be made
flexible so that it can be readily bent into a variety of
positions. The shield gas requirement is small thus enabling the
transfer efficiency for the overall system to be very high. Another
benefit arises from the fact that the small transfer tubes having
small thermal mass make the cooldown time very minimal.
There is shown in FIG. 3 a CRYO-TIP refrigerator 44 which receives
the transfer system 10 by means of an adaptor 46 from which the
conduit 16' and 18' project toward the end of refrigerator 44
through a suitable refrigerator body 48. Conduits 16' and 18' are
the delivery end counterparts of conduits 16 and 18 of FIG. 1. The
projecting end 45 of the transfer system terminates at a needle
valve 50 which serves to control the flow of the liquid cryogen.
The needle valve 50 has a valve member 52 that can be adjusted by
means of adjusting nut 54 at the top of the refrigerator body 48.
The refrigerator body 48 includes suitable heaters to raise the
temperature of the venting gas as it is conducted outwardly of the
system through vent 60, lead through ports 58, and vacuum connector
62 for evacuating the system.
At the needle valve 50 end of the refrigerator there is a sample
holder 64 which contains a suitably threaded aperture 66 and a
heater 68 for warming the delivered cryogen. Between the needle
valve 50 and the specimen holder 64 there is a heat exchanger 70.
The heat exchanger 70 serves to transfer the heat from the sample
holder to the cryogenic fluid. Because the cryogenic fluid is
forced through the exchanger the tip can operate in any
orientation. The heat transfer is counter flow, thus it is possible
to have the liquid enter from the needle valve and be warmed to a
high temperature as it flows through the heat exchanger. For
example, if liquid helium is being used, it flows from the needle
valve 52 as a saturated liquid at 4.2.degree. Kelvin and can then
be warmed to 300.degree. Kelvin as it flows through the heat
exchanger. The refrigerator 44 contains the necessary ports 71 for
venting the warmed cryogenic fluid from the entire system through
vent 60. The refrigerator 44 is shown inserted in a receptacle 73,
such as an instrument adaptor or the like, by known sealing means
to assure a pressure-tight fit.
Referring back to FIG. 2 there is shown an insulating layer 27
surrounding conduits 16, 18, and 26. This layer can be a
multi-layer insulation such as synthetic sheet material with a
metalized coating. The insulation extends to the delivery end of
the system and is disposed around conduit 16', 18' and 26' of FIG.
3.
Having thus described my invention the following is desired to be
secured by Letters Patent of the United States.
* * * * *