U.S. patent number 3,691,270 [Application Number 05/008,719] was granted by the patent office on 1972-09-12 for cosmetic makeup removing or treating composition which is microencapsulated and incorporated in a flexible support.
This patent grant is currently assigned to Societe Anonyme dite: L'Oreal. Invention is credited to Roger Charle, Gregoire Kalopissis, Charles Zviak.
United States Patent |
3,691,270 |
Charle , et al. |
September 12, 1972 |
COSMETIC MAKEUP REMOVING OR TREATING COMPOSITION WHICH IS
MICROENCAPSULATED AND INCORPORATED IN A FLEXIBLE SUPPORT
Abstract
A cosmetic makeup base foundation cream composition for the skin
comprises an alveolar polymeric support containing a multiplicity
of rupturable microcapsules containing said makeup base foundation
cream.
Inventors: |
Charle; Roger
(Soisy-sous-Montmorency, FR), Zviak; Charles
(Franconville, FR), Kalopissis; Gregoire (Paris,
FR) |
Assignee: |
Societe Anonyme dite: L'Oreal
(Paris, FR)
|
Family
ID: |
19725910 |
Appl.
No.: |
05/008,719 |
Filed: |
February 4, 1970 |
Foreign Application Priority Data
Current U.S.
Class: |
424/401;
15/104.93; 132/320; 401/132; 424/59; 424/63; 424/69; 428/402.2;
428/402.22; 510/157; 510/136; 510/159 |
Current CPC
Class: |
A61K
8/11 (20130101); A61K 8/0208 (20130101); A61Q
5/10 (20130101); A61Q 1/14 (20130101); A61Q
17/04 (20130101); Y10T 428/2987 (20150115); A61K
2800/412 (20130101); Y10T 428/2984 (20150115) |
Current International
Class: |
A61K
8/11 (20060101); A61K 8/02 (20060101); A61Q
17/04 (20060101); A61Q 1/14 (20060101); A61Q
5/10 (20060101); A61k 007/02 () |
Field of
Search: |
;424/14,16,27,28,59,63,69 ;252/89-93,316 ;15/104.93 ;132/88.7
;401/132 |
References Cited
[Referenced By]
U.S. Patent Documents
Primary Examiner: Rose; Shep K.
Claims
We claim:
1. A cosmetic makeup base foundation cream composition for the skin
comprising an alveolar support adapted to be applied topically to
the skin and made of a polymer selected from the group consisting
of polyurethane, cellulose acetate, urea formaldehyde, polystyrene,
styrene-acrylonitile, polyvinyl chloride, polyethylene and epoxy
resin, and support containing a multiplicity of microcapsules
encapsulating said makeup base foundation cream, said microcapsules
being rupturable by mechanical pressure exerted on said support at
the time of application of said support on the skin, the walls of
said microcapsules being inert to said makeup base foundation cream
and being formed of a material selected from the group consisting
of polyamide, polycarbonate, chlorated polyether, epoxy resin,
polysulfone, silicone, urea formaldehyde, polyurethane, aromatic
polyimide, mixed esters of cellulose or starch with a dicarboxylic
acid selected from the group consisting of phthalic acid, succinic
acid and maleic acid, polyvinyl pyridine, polyvinyl quinoleine,
polyvinyl imidazole, polyethylene, polypropylene, formol treated
gelatin and gelatin treated with gum arabic, the density of said
microcapsules being substantially equal to the density of the solid
portion of said alveolar support to provide uniform distribution of
said microcapsules in said composition.
2. The cosmetic composition of claim 1, wherein the walls of said
microcapsules are formed from polypropylene or polyethylene, the
size of said microcapsules being from 1 to 100 microns and said
aveolar support having a density of about 0.01 to 0.60.
3. The cosmetic composition of claim 2, wherein said aveolar
support has a density of 0.05 to 0.25.
4. The cosmetic composition of claim 1, in the form of a towel
wherein said microcapsules having a size of 50 to 100 microns are
regularly distributed on the surface of said aveolar support and
are fixed thereon by an adhesive.
5. The cosmetic composition of claim 1, in the form of a cosmetic
cotton.
6. The cosmetic composition of claim 1, in the form of a thin
sheet.
Description
The present invention relates to a cosmetic makeup removing or
treating composition, characterized essentially in that it is
incorporated in a flexible support and that the activity of the
cosmetic agent that is utilized cannot be effected until sufficient
mechanical pressure has been exerted upon the said support at the
moment of its application.
Cosmetic makeup removing or treating towels are available, for
example, in the form of a "blotting paper" type paper which has on
its surface or in the body a known cleansing product. The
disadvantage of such paper is that the product on storage can be
altered or can spot adjacent objects.
The present invention is intended to obviate the above mentioned
disadvantages and to impart to the makeup removing or treating
cosmetic towel practically indefinite storage.
The present invention thus has as its subject a cosmetic makeup
removing or treating composition which softens or moisturizes the
skin, protecting it from the sun's rays, or acts as a
wrinkle-preventive.
The present invention also relates to the process for the
preparation of towels and "cotton" as cited above.
The term "cotton" as used here means a cosmetic support which is
presented as a bulk and not as a surface, the material which
constitutes the said cotton being extremely diverse.
According to the invention, it has been found possible to prepare
makeup removing or treating towels and cotton without the above
indicated drawbacks by microencapsulation of the cosmetic agents
and distribution thereof inside the support or even simply adhered
to the support surface.
The process of microencapsulation of the active cosmetic agents
does not in itself constitute part of the present invention when
the microencapsulation of the said agents is effected separately
and the microcapsules are then used as starting materials.
In accordance with the present invention the above described
cosmetic towels and cottons are prepared by a process characterized
in that the microcapsules containing the cosmetic agent are
introduced in the course of the preparation of the solid cosmetic
support itself and that there is then directly effected the workup
of the preparations thus obtained, the microcapsules remaining
unaltered in the course of this treatment.
According to a first method of preparation, the starting product is
a "blotting paper" paste, and there is incorporated in the said
paste the microcapsules here designated as C, which were prepared
beforehand. The preparation of cosmetic towels or cottons is then
effected similarly to the preparation of ordinary blotting paper,
operating however in conditions which are compatible on the one
hand with the cosmetic agent contained in microcapsules C and on
the other hand with the compounds that constitute their envelope,
here designated E.
Compounds are therefore selected for envelopes E which have good
mechanical resistance to heat and a sufficient degree of
elasticity.
According to a modification of the process of the present
invention, instead of blotting paper there is used as support a
synthetic polymer or copolymer which is thermosetting or obtained
by polycondensation or catalytic polyaddition. In any case, it is
necessary to satisfy the following conditions in the course of
their manufacture:
the monomers of prepolymers or the base products of polyaddition or
polycondensation which are used as starting material must be
sufficiently fluid to allow ready introduction of microcapsules C
and the good homogenization thereof, the respective densities of
capsules C and of the liquid phase possibly being adjusted; the
compounds of the constituents that form envelopes E must have good
heat resistance and sufficient elasticity;
envelopes E must chemically resist the action of the above
mentioned liquid phase.
The final preparation of the synthetic product containing the
microcapsules is effected by a thermal or catalytic treatment in
which the above conditions are observed, to obtain preferably,
depending upon the polymer compound that is used, either films or
foils that are quite thin, or a porous material with all desired
degrees of density and containing the cosmetic microcapsules
included in the body of the polymer.
The interest of cosmetic cottons thus prepared and in the form of a
thin foamed material is evident, the microencapsulated makeup
remover or treating product then appearing after pressure of the
fingers or pressure attained by application on the desired spot. A
thin cosmetic towel can also be made from the same material.
The films in which microcapsules containing makeup remover and/or
cosmetic treating agents are advantageously used in blotting paper
type towels which form pockets in which they are introduced as a
single cutout having the form of the pocket, or as a plurality of
preferably lamellar cutouts. Thus polyvalent towels can be
prepared, with different colors corresponding to the respective
locations of the microcapsule sheets which have different
properties.
According to another modification, the cosmetic towel of the
invention has one surface for makeup removal and one treating
surface. In this case, the blotting paper type towel presents two
separate pockets, separated by a tight film, the two sides
receiving respectively the makeup remover sheet and the treating
sheet.
As compounds utilized for preparation of envelope E of the
microcapsules which answer to the conditions indicated above, there
are preferably used the following resins: polyamides, chlorated
polyethers, epoxy resins, polysulfones, formaldehyde urea,
polyurethane, aromatic polyimides, mixed cellulose esters or starch
with dicarboxylic acids such as phthalic acid, succinic acid,
maleic acid, polyvinyl pyridines, polyvinyl quinoleines, polyvinyl
imidazoles, polyethylene, polypropylene, gelatin treated with
formol or with gum arabic. Many other types of resins can likewise
be used, but among the mentioned resins the polyamides, chlorated
polyethers, epoxy resins and polyalkylenes are most used.
The compounds used for preparation of the synthetic resin films
which contain microcapsules C are preferably selected from among
the following:
acetal homopolymers and copolymers, methyl polymethacrylate as well
as copolymers thereof formed with styrene and alphamethyl styrene,
ethyl cellulose, cellulose acetate, cellulose propionate, cellulose
acetobutyrate, vinyl polymers and copolymers such as vinylidene
chloride or polyvinyl dichloride, polystyrenes and copolymers of
styrene-acrylonitrile, allyl resins, casein base resins,
polyethylene, melamine formaldehyde resin, phenol formaldehyde
resins etc.
The compounds for formation of a porous support are selected from
among the following:
polyurethane, cellulose acetate, formaldehyde urea, polystyrene,
styrene-acrylonitrile, polyvinyl chloride, polyethylene, epoxy
resins etc.
Preferably densities of 0.01 to 0.60 and preferably 0.05 to 0.25
are used for the closed-cell or open-cell alveolar support prepared
with these resins.
An essential characteristic of the process of the invention resides
in the appropriate choice of support materials and of the compound
which forms envelopes E of capsules C so that the latter withstand
the conditions of manufacture, especially the thermal conditions,
the active agent that they contain being however readily released
by mechanical pressure at the moment of use.
Microcapsules C contain either makeup remover, or skin-treating
products as milk, oils, creams, emulsions, or they may contain
makeup foundation or cosmetic products in general for local
application such as gradual dyeing of the hair.
The manufacture of the towels and cosmetic cottons is accomplished
as follows:
The suspension or mixture of the initial liquid compounds that are
to constitute the support of capsules C in the final product is
prepared.
The said support is prepared, i.e. either blotting paper from paper
paste or synthetic polymer from the monomer or liquid prepolymer
which is thermosetting, or catalytically condensable products, the
latter possibly yielding foams, and microcapsules C which have been
prepared separately are introduced at an appropriate moment in this
process, conditions particularly of temperature and pressure being
appropriately adjusted.
Microcapsules C are introduced either directly into the mass at a
moment in which its fluidity is still sufficient, the density of
the microcapsules moreover being close to that of the liquid phase,
or they are introduced by spraying when it is desired to
incorporate them in a thin foil, before termination of the
polymerization of the said foil.
At the end of the manufacturing process, there are thus obtained
microcapsules C incorporated in the body of the support, the said
support being a blotting paper, a thin film, or a porous mass of
suitable synthetic material.
Workup or necessary cutting is then effected, to prepare towels or
cosmetic cottons of the invention.
In general, when the microcapsules are introduced in the course of
manufacture of the cosmetic support which is in the form of a
liquid or a suspension, the best possible homogenization is
obtained by suitable mixing by agitation, shaking or blowing in of
a gas. The density of the liquid or of the suspension is then
adjusted to that of the microcapsules by addition of one of the
components of the support or an appropriate inert substance, and
premixtures can be prepared which contain the microcapsules with a
fraction of the support or some of its components. It is also
possible to select microcapsules whose density corresponds to that
of the liquid or of the suspension at the moment of their
introduction.
Besides, the microcapsule envelopes are selected readily to resist
slight pressure as well as temperatures of the order of 50.degree.
to 60.degree.C and in certain instances temperatures distinctly
higher when such temperatures are required by the process for
preparation of the support.
The following non-limiting examples in which parts and percentages
refer to weight are given by way of illustration and allow a fuller
understanding of the present invention.
EXAMPLE 1
Towel containing a microencapsulated makeup remover milk:
The following makeup remover composition is prepared:
"O.E." stearyl alcohol (oxyethylene) 4.0 ropy vaseline 6.0
isopropyl myristate 5.0 glycerol 10.0 antiferment 0.1 perfume 0.3
water to make up 100.0
The makeup remover milk is then microencapsulated by the known
technique, using polypropylene, the microcapsules having an average
dimension of 50 to 100 microns and preferably from 60 to 80. The
said microcapsules are dispersed in a blotting paper paste at the
moment at which the density of the said paste is such that the
microcapsules are distributed in it with sufficient uniformity. The
said blotting paper is allowed to drain and it is dried on a form
in thin layers, possibly with slight pressure, or the microcapsules
are "flash" projected onto the surface of sheets of blotting paper
preliminarily coated with an adhesive layer. The sheets are cut to
the desired size and thus makeup remover towels ready for use are
obtained. The microcapsules release the makeup remover milk by
simple pressure that crushes the microcapsules.
EXAMPLE 2
Towel containing sun oil in microcapsules.
The following oily solution is prepared:
almond oil 93.99 cholesterol 0.50 rancidity preventer 0.01 benzyl
salicylate 5.00 perfume 0.50
This oil, which constitutes an excellent filter for solar
radiation, is used in the microencapsulated state, said
encapsulation being effected by a known process using ethyl
cellulose or polyvinyl acetal, the microcapsules having a size
between 50 and 100 microns, preferably 60 to 100 microns.
On cotton fabric cut to the desired shape and preliminarily coated
with an adhesive layer, the microcapsules are dispersed either by a
suitable mechanical device or by projection using compressed air or
gas.
A support ready for use is thus obtained. The microcapsules release
the sun-protection oil that they contain by simple pressure against
the skin.
The produce is thus made up in a way that is both light and easy to
use.
EXAMPLE 3
Films cut in thin sheets containing a microencapsulated cream
incorporated in cosmetic towels, possibly with a plurality of
separations.
A cream is prepared which contains:
tragacanth gum 2.0 extra fine kaolin 30.0 titanium dioxide 3.0
cerebromedullary extract 4.0 stabilizer 0.3 physiological serum
10.0 perfume 0.2 water to make up 100.0
This microencapsulated cream is prepared by the known process,
using styrene copolymers and vinyl ester or vinyl ether, or
polymers soluble at an alkaline pH and insoluble at an acid pH,
like acrylic acid polymers.
Microcapsules 1 to 100 microns in size are obtained, preferably 20
to 50 microns.
A liquid film is also prepared which has a thickness of 30 to 40
microns, constituted by cellulose acetobutyrate in a solvent, and
the above described microcapsules are sprayed onto this film, the
said microcapsules containing the above described treating
preparation comprising a softening cream.
According to a modification, the cellulose acetobutyrate and
microcapsule mixture is prepared and homogenized and spread in thin
films.
After evaporation of the solvent, a thin film is obtained which
contains the microcapsules and this film cut into sheets or in
layers of desired size and shape are incorporated into blotting
paper towels which form a pocket that may present separations.
EXAMPLE 4
Cosmetic cotton or towel of porous material containing
microencapsulated makeup base.
A makeup foundation of the following composition is prepared:
styrene 5.0 isopropyl myristate 6.0 vaseline oil 20.0 glycerol
stearate 3.0 propylene glycol 2.0 triethanolamine 2.0 preservative
0.2 titanium dioxide 10.0 carboxymethyl cellulose 1.5 yellow iron
oxide 2.0 red iron oxide 1.0 carbon black 0.3 demineralized water
to make up 100.0
This cream is microencapsulated by known processes using propylene
or polyethylene, the size of the microcapsules being 1 to 100,
preferably 30 to 40 microns.
Upon preparation of an alveolar polyurethane resin, before blowing
in of carbon dioxide, the above microcapsules containing the makeup
foundation cream are introduced.
After having effected a perfect distribution of the microcapsules
in the resin, preparation of the alveolar polymer is continued,
conditions of temperature and pressure, as well as the
characteristics of the microcapsules being respectively and
reciprocally appropriate.
Workup and cutting into cosmetic towels or cottons is then
effected.
When they are used, these preparations release a makeup foundation,
by pressure and crusing of the microcapsules, the said foundation
spreading on the skin as the user requires.
Or again, as in the preceding example, it is possible to project
the makeup foundation microcapsules onto the surface of a cut
support which has the selected thickness and configuration.
EXAMPLE 5
A flexible cosmetic towel containing a microencapsulated dye of the
following composition is prepared:
oxyethylene lauryl alcohol 5.0 substituted fatty amide 5.0 copra
amide 4.0 substituted aminophenol 2.0 substituted diaminobenzene
2.0 aqueous solution containing 20% ammonia 1.5 perfume 0.1 water
to make up 100.0
This dye composition is used in microcapsules prepared by a known
process, using casein or an epoxy resin, the microcapsules being 20
to 100 microns, preferably 40 to 60 microns in size.
These microcapsules are placed or projected onto a flexible support
which may be paper, cotton fabric or a film of suitable plastic
material, the above mentioned supports being preliminarily coated
with a suitable adhesive substance. There is thus obtained a
composition which is simple and practical in form, allowing local
application of a dye product whose shade develops by oxidation in
air.
* * * * *