U.S. patent number 3,676,342 [Application Number 04/881,331] was granted by the patent office on 1972-07-11 for lubricant for textile machinery.
This patent grant is currently assigned to Esso Research and Engineering Company. Invention is credited to Albert Gathman, George W. Gleim.
United States Patent |
3,676,342 |
Gathman , et al. |
July 11, 1972 |
LUBRICANT FOR TEXTILE MACHINERY
Abstract
A lubricating composition that is uniquely designed for the
lubrication of textile machinery such as a circular knitting
machine comprises a lubricating oil containing zinc oxide as an
antiwear agent. The zinc oxide is incorporated in the lubricating
oil composition by first preparing an additive concentrate wherein
up to 10 weight percent of zinc oxide has been dispersed in a
lubricating oil using as a dispersing agent zinc naphthenate,
magnesium naphthenate or mixtures thereof. The lubricating
composition also preferably contains an oiliness agent, an
antioxidant and an extreme pressure agent. The zinc naphthenate or
magnesium naphthenate not only serves to suspend the zinc oxide but
also imparts scourability to the composition, thereby aiding in the
removal of the lubricant from the textile processed by the textile
machinery.
Inventors: |
Gathman; Albert (Belmar,
NJ), Gleim; George W. (Springfield, NJ) |
Assignee: |
Esso Research and Engineering
Company (N/A)
|
Family
ID: |
25378256 |
Appl.
No.: |
04/881,331 |
Filed: |
December 1, 1969 |
Current U.S.
Class: |
508/172;
516/33 |
Current CPC
Class: |
C10M
1/08 (20130101); C10M 2223/041 (20130101); C10N
2070/02 (20200501); C10N 2040/46 (20200501); C10M
2219/024 (20130101); C10M 2207/129 (20130101); C10M
2207/026 (20130101); C10M 2207/122 (20130101); C10N
2010/04 (20130101); C10N 2010/00 (20130101); C10M
2207/121 (20130101); C10M 2201/14 (20130101); C10M
2215/065 (20130101); C10M 2207/125 (20130101); C10M
2201/062 (20130101); C10M 2223/045 (20130101); C10M
2207/16 (20130101) |
Current International
Class: |
C10m 001/24 ();
C10m 001/10 () |
Field of
Search: |
;252/18,25,309,314 |
References Cited
[Referenced By]
U.S. Patent Documents
Primary Examiner: Wyman; Daniel E.
Assistant Examiner: Vaughn; I.
Claims
What is claimed is:
1. A process for preparing a stable dispersion of zinc oxide of
about 0.02 to 0.25 micron size in a liquid lubricating oil
composition which comprises the following steps:
a. mixing together about 0.1 to 10 weight percent of zinc oxide,
about 0.5 to 50 weight percent of zinc naphthenate or magnesium
naphthenate or a mixture thereof, and about 40 to 99.4 weight
percent of mineral lubricating oil, said weight percents being
based on the resulting mixture;
b. grinding said mixture in a mill whereby a zinc oxide concentrate
is obtained from which no more than about 1 weight percent of zinc
oxide will settle within a period of 48 hours;
c. thereafter dispersing about 0.5 to 5 weight percent of said
concentrate into a liquid lubricating oil composition.
2. Process as defined in claim 1 including the step of precoating
said zinc oxide with the zinc salt of a C.sub.2 to C.sub.4 fatty
acid.
3. Process as defined in claim 2 wherein said zinc salt is zinc
propionate.
Description
BACKGROUND OF THE INVENTION
This invention relates to an improved lubricating composition that
is uniquely designed for the lubrication of small machine parts
that operate at high speeds where it is necessary that the parts
must be protected against high rates of wear and frictional power
losses must be minimized, and where the oil must not damage the
material being handled by the machine. Thus, the lubricating
composition is particularly useful for textile machinery and still
more particularly for the lubrication of a circular knitting
machine, e.g. one used in the manufacture of seamless stockings.
The invention also concerns a lubricant additive concentrate that
is adapted for formulation of a finished lubricant composition of
the invention.
In the manufacture of certain textile goods such as stockings,
circular knitting machines are used. A representative machine of
this type has a knitting head which may be briefly described as
follows: The knitting head has a cylinder of steel about 5 inches
in diameter, the wall of the cylinder being about one-half inch in
thickness and provided with a large number of vertical slots
distributed around the periphery of the cylinder. Each of these
slots, which is about 32nd of an inch thick, receives a needle that
moves rapidly up and down in the slot during the knitting
operation. The knitting head is lubricated with an automatic
lubricating device which feeds measured amounts of lubricant onto
the moving parts. This lubricant is not recirculated and some of it
necessarily finds its way onto the textile being knitted and thus
must be later washed out of the knitted product. Thus, the
lubricant for the knitting machine must have adequate scourability
so that it can be removed from the textile. Other properties of the
lubricant that are desired include rust inhibition, low coefficient
of friction, good oxidation resistance and good load-carrying
capabilities. Adequate load-carrying and antiwear properties in the
lubricant are needed because of the large number of moving surfaces
that require lubrication. Friction losses must be low in order to
reduce frictional heat and to reduce the tremendous power load
encountered during the start-up of the machinery.
In the prior art, load-carrying and antiwear properties were
imparted to lubricants for knitting machines by incorporating
finely divided molybdenum disulfide into the lubricants. While this
additive did provide adequate load-carrying and antiwear
properties, it had the disadvantage of tending to settle out of the
lubricant so that the lubricant supply had to be continuously
agitated to prevent such settling. Furthermore, the molybdenum
disulfide tended to stain the textiles.
In accordance with the present invention, zinc oxide is used as the
antiwear and load-carrying agent because zinc oxide will not stain
the textiles. Furthermore, in the present invention the zinc oxide
is maintained in suspension in the lubricant by means of an
eminently stable suspending agent and by means of a novel procedure
for preparing the zinc oxide suspension. More particularly, the
zinc oxide is first suspended as a concentrate in a lubricating oil
with the aid of zinc napthenate, magnesium naphthenate or mixtures
of the two and the concentrate is thereafter blended into the
finished lubricating composition in the desired concentration. It
is not possible to prepare a finished lubricant of this nature that
will be satisfactory by simply dispersing zinc oxide in the mixture
of other components of the finished lubricant because the zinc
oxide will tend to settle out of the mixture. It is thus necessary
to first prepare the described concentrate. In a preferred aspect
of the invention the zinc oxide is first coated with a zinc salt of
a lower fatty acid before preparing the concentrate.
The essential component of a textile machine lubricant of the
present invention is a suspension of zinc oxide in a mineral
lubricating oil. The zinc oxide is of microscopic particle size of
the order of about 0.02 to 0.25 micron and has a surface area of
from about 5 to 25 square meters per gram. Preferably, the zinc
oxide is treated with a C.sub.2 to C.sub.4 carboxylic acid to form
a zinc salt on its surface, e.g. zinc propionate as taught in U.S.
Pat. No. 2,303,330, and thereby aid in the dispersion of the zinc
oxide.
The amount of zinc oxide in the additive concentrate will range
from about 0.1 to about 10 weight percent, preferably from about
0.5 to 5 weight percent. To maintain the zinc oxide in suspension
in the concentrate as well as in the finished lubricant, there is
employed in the concentrate from about 0.5 to about 50 weight
percent, preferably from about 1 to about 30 weight percent, of
either zinc naphthenate or magnesium naphthenate or mixtures
thereof. These metal naphthenates are prepared from petroleum
naphthenic acids. The preferred naphthenic acids are those having
molecular weights of from about 200 to about 350 and neutralization
numbers of from about 150 to 230. A convenient procedure for
dispersing the zinc oxide in the concentrate is to place the zinc
oxide, metal naphthenate and lubricating oil in a ball mill and run
the ball mill for from about 1 to 2 hours.
To prepare the finished textile machine lubricating oil the zinc
oxide concentrate and the other desired components of the lubricant
are incorporated in the desired base stock by simple mixing. The
finished composition will contain from about 0.5 to about 5 weight
percent of the zinc oxide concentrate along with other desired
components such as an antioxidant, e.g. a zinc dialkyl
dithiophosphate, phenyl-alpha-naphthylamine tertiarybutyl
paracresol, or the like, an oiliness agent such as oleic acid or
zinc oleate, and an extreme pressure agent such as sulfurized sperm
oil, tricresyl phosphate or the like. A particularly preferred
composition will contain, in addition to the zinc oxide concentrate
dispersion, from about 0.1 to about 2 weight percent of a zinc
dialkyl dithiophosphate, from about 0.2 to 1.5 weight percent of
oleic acid, and from about 1 to about 5 weight percent of
sulfurized sperm oil. The zinc dialkyl dithiophosphate will
comprise one or more oil-soluble dithiophosphates wherein the alkyl
groups have from about three to 18 carbon atoms, e.g. a mixture
obtained from mixed isopropanol and methyl isobutyl carbinol, a
mixture of amyl alcohols and technical lauryl alcohol, etc. The
sulfurized sperm oil can be one containing from about 5 to 35
weight percent sulfur, preferably 8 to 20 per cent sulfur.
The zinc naphthenate or magnesium naphthenate that is present in
the finished composition not only keeps the zinc oxide in
suspension, but also imparts washability or scourability, thus
aiding in the removal of any of the lubricant that gets picked up
by the textile being processed by the textile machine.
The lubricating oil constituting the base oil in the compositions
of this invention can be any well refined mineral lubricating oil
distillate. The oil is preferably obtained from a naphthenic or
paraffinic base crude oil, e.g. a Mid-Continent oil. The viscosity
of the oil can range from about 50 to 250 SUS at 100.degree. F.
Usually the viscosity will be within the range of about 75 to 200
SUS at 100.degree. F.
The nature of this invention will be better understood when
reference is made to the following examples.
EXAMPLE 1
A concentrate of a zinc oxide dispersion was prepared by mixing
together 94 parts by weight of a solvent neutral mineral
lubricating oil of 100 SUS viscosity at 100.degree. F., 5 parts by
weight of zinc naphthenate derived from naphthenic acids of about
280 molecular weight, and one part by weight of zinc oxide. The
zinc oxide had been surface-treated with propionic acid as
described in U.S. Pat. No. 2,303,330. The zinc oxide had a mean
particle size of 0.11 micron and a surface area of 10 square meters
per gram. It analyzed 99.1% ZnO. The mixture was placed in a ball
mill and the dispersion was prepared by running the ball mill for 2
hours at ambient temperature.
EXAMPLE 2
A finished lubricant suitable for the lubrication of a circular
knitting machine was prepared by blending together the following
components in the weight percentages indicated below:
Wt. % Base oil* 95 Zinc dialkyl dithiophosphate 0.5 Oleic acid 0.5
Sulfurized sperm oil 3.0 Zinc Oxide Concentrate of Example 1
1.0
the zinc dialkyl dithiophosphates mentioned above, were in the form
of a 75 weight percent concentrate in lubricating oil of the zinc
salts prepared from the dithiophosphoric acids obtained by reacting
P.sub.2 S.sub.5 with 65 weight percent of isobutanol and 35 weight
percent of mixed primary C.sub.5 alcohols. The sulfurized sperm oil
had a sulfur content of about 12 percent by weight.
The finished lubricant had a viscosity of 139.6 SUS at 100.degree.
F., a viscosity of 43.2 SUS at 210.degree. F., and a viscosity
index of 115.7. It was found to be a very suitable lubricant for a
circular knitting machine, and left no stains on seamless hosiery
knit by the machine, after said hosiery had been washed by standard
procedures.
An attempt to prepare a finished lubricant with the same components
in the same proportions as above, but simply dispersing the zinc
oxide into the mixture of other components was not successful,
because the zinc oxide would not remain in suspension.
EXAMPLE 3
A concentrate similar to that described in Example 1 was prepared
using 5 weight percent of zinc oxide and 5 weight percent of zinc
naphthenate. The dispersion was prepared by blending the mixture
for 2 hours in a ball mill filled with steel balls. A portion of
the product was set aside and observed for settling tendencies. No
zinc oxide settled out of the concentrate in a period of 18 hours.
About one-half weight percent of zinc oxide settled out after 48
hours. When the concentrate was used to prepare a finished textile
machine oil of the same nature as described in Example 1, i.e. an
oil containing about 0.01 weight percent of zinc oxide, there was
no settling of zinc oxide even after the composition had been
allowed to stand for 1 year.
EXAMPLE 4
Example 3 was repeated using magnesium naphthenate in place of the
zinc naphthenate. The resulting dispersion was about as stable as
that of Example 2, i.e. no more than about 1/2 to 1 weight percent
of zinc oxide settled out of the concentrate after 48 hours.
COMPARATIVE EXAMPLE A
Example 3 was repeated using 5 weight percent of zinc oxide and 5
weight percent, in respective individual preparations, of lead
naphthenate, barium sulfonate, calcium sulfonate, and aluminum
stearate. In none of these cases was a satisfactory stable
concentrate obtained. In the case of lead naphthenate, there was
100 percent settling of the zinc oxide after 18 hours. In the case
of both the barium sulfonate and the calcium sulfonate, there was
90 percent separation of zinc oxide by settling after 18 hours. The
sulfonates employed were the barium and calcium salts of petroleum
sulfonic acids of about 400 molecular weight.
COMPARATIVE TEST B
The finished oil composition of Example 2, the base composition
(i.e. the finished lubricant of Example 2 without the added zinc
oxide concentrate) and a lubricant of the same composition as that
of Example 2 with the exception that the 0.01 weight percent of
zinc oxide was replaced with an equal quantity of molybdenum
sulfide, were each subjected to the well known 4-Ball Wear Test.
The test was conducted as follows:
The test lubricant is placed in the cup of the machine and heated
to 75.degree. C. The test cup contains three steel balls which are
fixed in position by a screw cap. A fourth steel ball held in a
chuck is pressed against the three lower balls with a force of 40
kilograms and is rotated at 1,200 r.p.m. for 1 hour. At the end of
the test, the amount of wear is determined by measuring the
diameter of the wear scar on each of the steel balls and averaging
the results.
The results obtained in the 4-Ball Wear Test with each of the two
blends as well as with the base oil are given in Table I which
follows. It will be seen that the lubricant containing zinc oxide
was more effective in reducing wear than was the lubricant
containing the molybdenum disulfide.
TABLE I
Oil Blend 4-Ball Wear, mm.
__________________________________________________________________________
Base Oil 0.658 Composition with Zinc Oxide 0.399 Composition with
Molybdenum Disulfide 0.433
__________________________________________________________________________
It is to be understood that the examples presented herein are
intended to be merely illustrative of the invention and not as
limiting it in any manner.
* * * * *