U.S. patent number 3,675,715 [Application Number 05/102,824] was granted by the patent office on 1972-07-11 for processes for secondarily recovering oil.
This patent grant is currently assigned to Forrester A. Clark. Invention is credited to Frank N. Speller, Jr..
United States Patent |
3,675,715 |
Speller, Jr. |
July 11, 1972 |
PROCESSES FOR SECONDARILY RECOVERING OIL
Abstract
A secondary recovery process for oil wet sands using underground
combustion to produce a makeup effluent gas containing carbon
dioxide. The effluent gas is mixed with a wet casing head gas
enriched by ethane plus hydrocarbons and the mixture is injected
into the reservoir at relatively low pressures to promote oil flow
toward a production well. The enriched injected gas mixture reduces
the oil's adhesion to the sand and promotes oil flow. The
production well is maintained under a vacuum pressure so as to pull
the injected mixture through the formation. The mixture is
recovered and reinjected. The production well vacuum pulls ethane
plus hydrocarbons from the oil at the formation face to enrich the
casinghead gas.
Inventors: |
Speller, Jr.; Frank N. (Tyler,
TX) |
Assignee: |
Clark; Forrester A. (Boston,
MA)
|
Family
ID: |
22291879 |
Appl.
No.: |
05/102,824 |
Filed: |
December 30, 1970 |
Current U.S.
Class: |
166/256; 166/266;
166/402 |
Current CPC
Class: |
E21B
43/243 (20130101) |
Current International
Class: |
E21B
43/243 (20060101); E21B 43/16 (20060101); F21b
043/24 () |
Field of
Search: |
;166/256,257,258,261,272,266 |
References Cited
[Referenced By]
U.S. Patent Documents
Primary Examiner: Leppink; James A.
Claims
I claim:
1. The method of secondary recovery of oil from a reservoir having
oil wet sands including the steps of producing a fire flood in a
reservoir adjacent a thermal injection well, withdrawing products
of combustion from the flood so formed through a second well,
mixing the products of combustion with wet casing head gas
containing ethane plus gas, with the resultant mixture having on
the order of 20 to 35 percent ethane plus gas by volume, injecting
the gas mixture thus formed into a second injection well in
proximity to one or more production wells in the reservoir,
withdrawing the injected gas from the production well, withdrawing
oil from the production well, and recycling the withdrawn gas to
the second injection well.
2. The method of claim 1 wherein the combustion is controlled and
the mixture of casing head gas with the products of combustion is
controlled so that the injected gas mixture has on the order of
approximately two parts ethane plus to approximately one part of
carbon dioxide.
3. The method of claim 2 wherein the gas mixture injected in the
second injection well is on the order of 50,000 to 150,000 MCF per
day.
4. The method of claim 1 characterized by and including the step of
additionally withdrawing oil from the second well.
5. The method of secondary recovery of oil from a reservoir having
oil wet sands including the steps of mixing an exhaust gas,
containing carbon dioxide and other gases resulting from combustion
of a hydrocarbon oil, with a wet casing head gas having an ethane
plus gas component, controlling the relative volumes of carbon
dioxide and ethane plus in the mixture so that approximately two
parts ethane plus to one part carbon dioxide are present in the
mixture, injecting the controlled mixture in a reservoir well at
pressures and temperatures such as to maintain the mixture during
injection as a gaseous phase for driving oil in the reservoir
toward a production well, maintaining the production well under
vacuum, and separately withdrawing oil and gas from said production
well.
6. The method of claim 5 wherein the withdrawn gas is recycled
through the injection well at said pressures and temperatures.
Description
The present invention is directed to improvements in processes for
secondary recovery of oil.
A number of secondary recovery processes for the recovery of oil
from oil bearing sands are known. In the past water flooding
techniques have been utilized in order to drive oil towards a
producing well. "Fire flood" processes are also known in which
combustion is initiated underground in order to create pressure
while reducing viscosity of oil and adhesion of oil to the
reservoir sand to thereby promote flow of the oil toward a
producing well. In some cases carbon dioxide with or without
hydrocarbon gases has been utilized in connection with water flood
processes to promote flow of oil towards a recovery well. It has
also been known to utilize butane, propane, and equivalent
hydrocarbon gases under relatively high pressures, for example,
exceeding 2,000 psi in a water or gas mixture for driving oil from
the oil bearing sands to a producing well. Air injection processes
which produce oxidation without ignition and low pressure gas
injection techniques have also been proposed in secondary recovery
processes.
Water flooding techniques can be economically effective in the case
of water wet sands. However, in the case of oil wet sands the water
flooding technique is usually ineffective to free the oil from the
formation and drive it to a producing well with satisfactory
economy. The term "oil wet sands" as used herein is intended to
refer to those sands in which oil is found on the face of the sands
and in formations having an absence of formation water. Use of
carbon dioxide in water flooding techniques increases equipment
corrosion to the extent that the economies of the overall operation
may be unsatisfactory. Fire flood techniques are satisfactory in
some cases with oil wet sands but in some cases a fire flood
operation is not economical, because of the extent and intensity of
burning necessary to produce a given amount of oil. The use of
injected gas mixtures at high pressures has the disadvantage that
the gases so used then become quite dense or may become liquid at
the high pressures, with the result that the high pressures
utilized with gas injected mixtures usually require plugging of
those wells of the field which are not operative in the process in
order to maintain the high pressures and to avoid contamination of
the atmosphere. Air injection is sometimes satisfactory but this
process does not reduce oil adhesion as much as fire flood or
carbon dioxide processes. Low pressure gas injection can be
satisfactory to promote oil flow in some cases, but the low
pressures may not be sufficient to drive oil to a production well
in some formations and the gas supply may not be sufficient for
production.
With the foregoing in mind, the present invention is directed to a
new and improved process for secondary recovery of oil from
formations having oil wet sands, and in those instances where a
casing head gas which is rich in ethane plus hydrocarbon or the
equivalent is present in suitable quantities at the site of the
recovery operation.
The major purposes of the invention are to provide a method for
secondary recovery of oil from oil wet sands while utilizing
relatively low working pressures for gas injection with the result
that over a prolonged period of time plugging of the wells not
actually involved in the operation and in the field being worked is
unnecessary; and in such a way that pollution of the surrounding
atmosphere is avoided, all while increasing the recovery of oil at
an overall cost less than that which can be obtained with known
fire flood, or a water flood, carbon dioxide, air injection or gas
injection processes.
These and other purposes will appear from time to time in the
course of the ensuing specification and claims when taken in
conjunction with the accompanying drawing, in which:
FIG. 1 is a diagram of the process constituting the present
invention.
In accordance with the present invention, combustion is initiated
underground in accordance with known fire flood techniques. The
combustion, however, is not initiated for the main purpose of
driving oil towards a recovery well but rather for the purpose of
producing an effluent gas containing carbon dioxide and other
constituents which are then mixed with a wet casing head gas and
reinjected for the purpose of promoting flow of oil towards a
producing well. Oil and injected gas are then separately recovered
from the producing well, whereupon the recovered part of the
injected gas can be recycled.
As shown in FIG. 1, for example, the numeral 10 designates a
thermal injection well in which a suitable compressor or the like
11 delivers air to the bottom of the well for the purpose of
controlling the combustion. The combustion may be initiated by
means of any known system for initiating a fire flood operation. A
fire flood as designated generally at 12 produces heat and
pressures which are effective in driving the products of combustion
and some oil toward an effluent well generally designated at 13.
Temperatures at the flame front may be 600.degree. F. or greater.
The casing of effluent well 13 is maintained at or near atmospheric
pressure and the products of combustion from the fire in the form
of effluent gases pass up the casing 14 of the well. Some oil may
be driven to the oil inlet of well 13 and this oil may be recovered
through the tubing 15 within the well.
Pumping facilities (not shown) may be utilized to withdraw the oil
through the tubing 15.
The oxygen in the air pumped underground to the fire is converted
to an equivalent volume of CO.sub.2 and this conversion may be as
much as 85 percent efficient. Heat from the fire volatilizes light
components of the oil in the immediate vicinity and the volatilized
components are in the form of rich vapors until they partially
condense as they are driven away from the burn area. Some of the
partially condensed components then go into solution with other
formation oil and others go into the mixture of the combustion gas.
The recovered vapors usually include an ethane plus component; thus
the effluent gas is a mixture enriched by ethane, heavier
hydrocarbons and carbon dioxide for reinjection.
The heavier hydrocarbons are butane, propane, etc. The term "ethane
plus" as used herein refers to the heavier hydrocarbons in a gas
and designates the ethane and heavier hydrocarbons in the gas.
Since the main purposes of the thermal injection well is not to
drive oil towards the well 13 but rather to produce an enriched
product of combustion gas, the volume of oxygen or air supplied to
the injection well 10 may be considerably lower than that used in
normal fire flood processes. In normal fire flood processes the
intention is to create an intensity of burning such as to produce
temperatures and pressures which cause maximum oil flow.
Nonetheless, in the process of this invention, any oil recovered
from the effluent well 13 is of value and helps to pay for the cost
of operation.
It should be understood that one or more effluent wells 13 may be
utilized. They may be advantageously situated in surrounding
relation to the thermal injection well 10. It should also be
understood that control of the underground combustion in processes
of this type is effected through the air supply control. By
shutting off the air supply, the combustion may be extinguished
eventually. The degree of combustion may also be increased by
increasing air supply.
In accordance with the invention, the air supply is controlled so
as to produce carbon dioxide in the effluent mixture of gases on
the order of 16 to 25 percent by volume of the total effluent gas
mixture. The following Table No. I shows typical gaseous mixtures
by volume in five effluent gas wells surrounding a thermal
injection well:
TABLE I
Comp. 1. 2. 3. 4. 5. Avg.
__________________________________________________________________________
Oxygen 3.30 4.00 4.03 1.57 1.38 2.86 Nitrogen 69.88 72.03 67.93
77.20 76.68 72.74 Methane 0.33 0.20 0.56 0.10 0.18 0.27 Carbon
17.98 17.64 20.09 18.23 18.63 18.51 Dioxide Ethane 8.51 6.13 7.39
2.90 3.13 5.62 Plus
__________________________________________________________________________
In further accordance with the invention, a wet casing head gas,
which is available from producing wells at the field being
operated, is utilized for mixture with the effluent gas and for
reinjection into the formation. Casing head gas is that gas
normally present in the casing of a well and which is sometimes
recovered for sale or other use. It normally has little or no
carbon dioxide therein. The casing head gas is mixed with the
effluent gas from the well 13. Suitable piping connections pass the
mixture to a compressor 17. Suitable valves and controls,
diagrammatically indicated at 18 and 19, may be used to control the
relative volumes of the two gases in the mixture before delivery to
the compressor 17. Compressor 17 delivers the mixture to a second
injection well 20. Producing wells are diagrammatically represented
at 21. The wells 21 are the source of the casing head gas.
The producing wells 21 surround the gas injection well 20. Oil is
pumped from the production wells 21 through the tubing of the wells
to conveniently located stock tanks. Gas is recovered from these
wells by pulling a vacuum on the casing of the wells which causes
the gas to be separated from the oil at the formation face and be
conducted up the casing and then passed to the compressor 17 for
injection. The vacuum on the casing of the production wells 21 is
on the order of -5 to -7.5 psi or 10-15 inches mercury vacuum. The
vacuum which is maintained on the casing of each production well
has the effect of pulling ethane plus hydrocarbons out of the oil
at the point of separation, thereby enriching the gas and making it
into what may be termed a "wet" casing head gas. The invention
contemplates a casing head gas of this type which contains an
average of 6 gallons or more, per thousand cubic feet of gas, of 26
lb. Reid vapor pressure at 70.degree. F., gasoline content which is
in a vapor phase in the gas.
The mixture injected into the well 20 thus has a beneficial carbon
dioxide component which results mostly from the effluent gas as
well as a beneficial ethane plus component.
Approximately one quarter of the gas mixture injected into the
formation from the injection well 20 is lost from various causes
such as a portion of it going into solution with unproduced oil
while another portion repressurizes the formation and maintains it
under pressure. The remaining part of the injected gas mixture,
together with some gas components from the recovered oil as
aforementioned, is recovered at the formation face by the casings
of the production wells. The effluent gas, in addition to supplying
the beneficial effect of CO.sub.2, as well as some ethane plus
component to the gas mixture, acts as a source of makeup gas to
maintain a total volume of gas mixture injected per day. The carbon
dioxide component in the mixture is believed to act in a manner
equivalent to the ethane plus hydrocarbons in enriching the gas for
oil recovery purposes.
In cold weather some of the gas from the producing wells may
condense into liquid drops which may be caught in surface drips or
traps in the piping leading to the compressor blank.
The control of the gas mixture is maintained so that there is a
greater amount of ethane plus component in the gas by volume than
the carbon dioxide.
In a typical example, the casing head gas is mixed with the
relatively dry effluent gas in the proportion of three parts of
casing head gas and one part of effluent gas by volume, while each
injection well receives 50-150 MCF of the gas mixture per day. The
actual total volume of gas injected per well per day will depend
upon the thickness of the sand layer in the formation. Usually, an
injected volume of 50 to 100 MCF of the mixture per well per day is
a practical working volume. Preferably the mixture is such that
there are on the order of two parts of ethane plus to one part of
carbon dioxide in the mixture. The ethane plus component in the
mixture is on the order of 20 to 35 percent of the total mixture by
volume, while the carbon dioxide is on the order of 10 to 20
percent of the total mixture by volume. The actual percentage of
ethane plus gas component in the casing head gas as well as the
actual percentage of carbon dioxide in the effluent gas will vary
from time to time. The gases are analyzed periodically and the
valves controlled to control the relative amounts of carbon dioxide
and ethane plus in the mixture supplied to the compressor 17 in the
amounts stated.
It may be noted that the casing head gas or the effluent gas is not
suitable for injection at high pressures because of the tendency of
the ethane plus and carbon dioxide components to liquefy at high
pressure. However, the compressor 17 is operated at relatively low
pressures. These low pressures are on the order of 125 lbs. psi for
delivery into the gas injection well diagrammatically represented
at 20 in the drawings. The actual injection pressure may vary
somewhat but the pressure developed by the compressor 17 as well as
the temperature of the injected gas mixture should be such that the
mixture is injected in a gaseous state. Injection well 20 is
located with sufficient proximity to the production well or wells
21 so that the injected gas mixture drives the oil in the reservoir
toward the production well where it may be withdrawn through the
pipe 22 of the well. Suitable pumping facilities (such as rod
pumps) may be used to withdraw the oil. The vacuum together with
the injection pressure creates a "push-pull" effect and serves to
drive and pull the gas through the oil in the reservoir between the
second injection well 20 and the production well 21. The vacuum
also pulls from the oil hydrocarbons heavier than ethane. The
withdrawn gas is then delivered through suitable piping 23 and
valve controls 24 for recycling through compressor 17 to the second
injection well 20. The withdrawn gas is mixed with the effluent gas
as may be necessary to maintain the injection mixture in the
volumetric proportion stated and in the total volume per day as
stated. A typical gas analysis withdrawn from five production wells
is shown in the following table II.
TABLE II.
Comp. Mol % -1 -2 -3 -4 -5 Avg.
__________________________________________________________________________
Oxygen .06 .02 .08 .02 .04 .05 Nitrogen 47.67 50.86 52.24 50.14
51.02 50.39 Methane 6.54 9.68 8.38 8.27 9.36 8.45 Carbon 14.11
15.16 16.04 16.25 15.48 15.41 Dioxide Ethane 31.62 24.28 23.26
25.32 24.10 25.72 Plus
__________________________________________________________________________
The components shown in Table II illustrate the component parts of
the mixture which is pulled through the formation together with
some components which are added to the mixture from the oil in the
formation from time to time. The carbon dioxide content is due
primarily to that which results from the added effluent gas while
the ethane plus components are due for the most part to the gas
originally within the formation being worked.
The process is relatively inexpensive because the gas materials
used are available at the site and because the low pressures
require less expensive compressor operation than that required in
high pressure techniques. Use of the process enables continuous use
of gas native to the formation. The corrosive effect of CO.sub.2 is
minimized because the process is intended for oil wet sands rather
than water wet sands. The volume of combustion air supplied may be
less than that in normal fire flood processes.
The process recovers oil more efficiently than other processes
because of the tendency of the enrichers (carbon dioxide and ethane
plus hydrocarbons) to partially go into solution with oil in the
formation, thereby reducing the oils adhesion to the sand grains
and making the oil susceptible to being swept by the low pressure
injected gas to a producing well bore.
* * * * *