U.S. patent number 3,667,655 [Application Number 05/023,600] was granted by the patent office on 1972-06-06 for method for the rapid assembly of diptubes into spray cans and a diptube useful therein.
This patent grant is currently assigned to The Dow Chemical Company. Invention is credited to Herman Knieriem, Jr..
United States Patent |
3,667,655 |
Knieriem, Jr. |
June 6, 1972 |
METHOD FOR THE RAPID ASSEMBLY OF DIPTUBES INTO SPRAY CANS AND A
DIPTUBE USEFUL THEREIN
Abstract
Method for the rapid assembly of long flexible diptubes into
spray cans wherein the diptube is fixed into a coiled configuration
prior to its insertion into the spray can and regains its normal
shape after assembly.
Inventors: |
Knieriem, Jr.; Herman (Ballwin,
MO) |
Assignee: |
The Dow Chemical Company
(Midland, MI)
|
Family
ID: |
21816122 |
Appl.
No.: |
05/023,600 |
Filed: |
March 30, 1970 |
Current U.S.
Class: |
222/464.4;
53/470; 138/177 |
Current CPC
Class: |
B65D
83/32 (20130101) |
Current International
Class: |
B65D
83/14 (20060101); B67d 005/60 (); B65b
003/04 () |
Field of
Search: |
;222/464,1,54,402.1,527,530,376 ;206/46H ;53/36
;138/110,118,177,178 |
References Cited
[Referenced By]
U.S. Patent Documents
Primary Examiner: Reeves; Robert B.
Assistant Examiner: Bartuska; Francis J.
Claims
I claim:
1. A method for the rapid assembly of relatively long, flexible,
weighted diptubes into a spray can substantially filled with a
sprayable liquid prior to the sealing thereof, the steps which
comprise
1. providing a long flexible diptube with a weighted end, and a
mounting cup on the opposite end,
2. coiling said diptube intermediate the ends thereof, to provide a
coiled and shortened diptube having adjacent coils in substantial
contact,
3. fixing said diptube in coiled relationship with a holding means
which is soluble in the contents to be dispensed in said spray can
and which is compatible with the contents and does not interfere
with the spraying function of said spray can,
4. inserting said coiled diptube into said substantially filled
spray can, and
5. sealing said mounting cup onto said spray can.
2. The method as set forth in claim 1 in which the holding means is
a soluble adhesive.
3. The method as set forth in claim 1 in which the holding means is
at least one soluble plastic ribbon disposed axially about the
coils of said diptube.
4. The method as set forth in claim 1 in which the sprayable liquid
is selected from the group consisting of water based compositions
and lower alkanol based compositions and the holding means is an
adhesive selected from the group consisting of cellulose ether
adhesives and polyvinyl alcohol adhesives.
5. The method as set forth in claim 1 in which the sprayable liquid
is selected from the group consisting of water based compositions
and lower alkanol based compositions and the holding means is a
ribbon of cellulose ether.
6. A diptube for use in spray cans comprising a flexible plastic
tube formed into a predetermined number of contiguous coils, and
means for holding said coils together which is soluble in the
contents of said spray cans and which is compatible with the
contents and does not interfere with the spraying function of said
spray cans.
7. A diptube as set forth in claim 6 in which the means for holding
said coils together is a soluble adhesive.
8. A diptube as set forth in claim 6 in which the means for holding
said coils together is at least one plastic ribbon forming a closed
loop around the axial length of said coils.
9. A diptube as set forth in claim 6 which comprises, in addition,
a weighted end.
10. A diptube as set forth in claim 9 in which weighted end
comprises a metal body through which said tube passes and is
permanently affixed.
11. A diptube as set forth in claim 6 which comprises, in addition,
a mounting cup on one end thereof adapted to retain said diptube in
operative relationship after said mounting cup is sealed onto said
spray can.
12. A diptube as set forth in claim 9 which comprises, in addition,
a mounting cup on the end remote from said weighted end whereby
said mounting cup is adapted to retain said diptube in operative
relationship after said mounting cup is sealed onto said spray can.
Description
BACKGROUND OF THE INVENTION
Pressurized aerosol containers or cans have recently been developed
for spraying diverse liquids and many different apparatus have been
developed to hold the formulation to be sprayed in the aerosol can
until it is released by the consumer.
It has long been a problem in the prior art to provide a flexible
or limber diptube for these aerosol containers which will enable
one to spray the contents from the discharge opening when the can
is held in any position.
U.S. Pat. No. 2,978,152 to Batty illustrates the prior art wherein
a long flexible diptube is provided with a weighted end so that the
contents of the spray can can be expelled from the can in any
position as well as when the contents are almost empty. However,
these prior art spray cans having long limber diptubes are
relatively hard to assemble on a production line since the operator
must take a considerable amount of time to insert the diptube into
the can. The present invention solves this problem by providing a
long flexible diptube which is coiled prior to insertion into the
can. Thus, the coiled diptube can be easily inserted into the spray
can prior to the sealing operation and the production rate of the
cans is thereby increased.
SUMMARY OF THE INVENTION
The main object of the present invention is to provide an improved
method for the rapid assembly of relatively long, flexible,
weighted diptubes into a spray can prior to sealing thereof. A
further object of the present invention is to provide a coiled
diptube which is readily inserted into the spray can during the
production of spray cans.
The steps of the present method consist of providing a long
flexible diptube having a weighted end and a mounting cup on the
opposite end, coiling said diptube intermediate the ends thereof to
provide a diptube having adjacent coils in substantial contact,
fixing said diptube in coiled relationship so that the diptube can
regain its normal shape under suitable conditions after the can is
sealed, inserting the coiled diptube into the spray can which is
substantially filed with a sprayable liquid and finally sealing the
mounting cup onto the spray can. The sealed spray cans are
subsequently pressurized with a propellant inserted through the
standard valve in the mounting cup. This latter operation is not a
part of the present process.
A further object of the present invention is to provide a diptube
for use in spray cans which comprises a flexible plastic tube
formed into a predetermined number of contiguous coils and means
for holding the coils together which is soluble in the contents of
said spray can and which is inert to said content.
A still more specific object of the present invention is to provide
a coiled diptube for use in spray cans wherein the coil is held
together with soluble adhesives or soluble plastic ribbons which
form a closed loop around the axial length of said coils.
DETAILED DESCRIPTION
The present invention is illustrated by the drawing in which
FIG. 1 illustrates the sub-assembly of the mounting cup, the coiled
diptube and the weighted end.
FIG. 2 illustrates the complete assembly of the elements of FIG. 1
into the final spray can with its contents and propellent after the
diptube has uncoiled.
FIG. 3 is an enlarged fragmentary cross-section of the coils of the
diptube with the coils held together by a plastic ribbon.
In FIG. 1 the normally long flexible diptube 1 is shortened by
providing a plurality of coils as shown. One end of the diptube is
secured in a standard mounting cup 4 having an internal valve. The
other end is secured in a weight 3 which can be made from any
relatively heavy, inert, substance such as metal, glass, or
ceramics. The coils are held together in this illustration by a
dried or set adhesive 2 to provide the subassembly.
In FIG. 2, the flexible diptube 1 is shown after the coils have
been uncoiled inside the pressurized container 5 to provide the
final assembled spray can. The sprayable contents 6 are pressurized
by a standard propellent shown at 7.
In FIG. 3, the coiled diptube 1 is held in place until it is
assembled into the spray can by one or more soluble plastic ribbons
8 which are tied or heat sealed about the axial length of the
coiled diptube.
In practicing the method of this invention, the long flexible
diptube is wound on a rod having the desired diameter and
temporarily fixed into this coiled configuration by freezing it in
an ice bath or other low temperature fluids, tying it with soluble
plastic ribbons, or applying a soluble adhesive.
It is essential that if adhesives or plastic ribbons are used that
they be readily soluble in the contents to be dispensed and at the
same time be inert to the active ingredients thereof. This can be
readily ascertained by a simple test with each sprayable
formulation prior to the insertion of the coiled diptubes. For
sprayable formulations using a large amount of water or lower
alkanols, it has been found that plastic ribbons or adhesives made
from cellulose ethers such as methyl cellulose and ethyl cellulose
are satisfactory. Likewise, polyvinyl alcohol adhesives are
operable. Other plastic ribbons or adhesives can be readily found
by those skilled in the art for different formulations.
Any of the normal propellents such as the Freons or lower
hydrocarbons such as isobutane can be used as the propellents in
the present invention since these materials are inert to the
sprayable formulations.
As a specific illustration of the invention, commercial aerosol
valves assembled with their mounting cups and long flexible
polyethylene diptubes are each provided with a cylindrical weight
on the end of the diptubes. The tubes are then coiled over a
cylindrical form and tied together with ribbons of soluble plastic
such as ethyl cellulose and methyl cellulose.
The coiled diptubes are then placed in open cylindrical spray cans
having diameters of 2 11/16 inches and lengths of 6 3/4 inches,
partially filled with 420 grams of a sprayable liquid formulation,
crimped in place, pressurized with a propellent and given three
shakes. The following table gives the time in which it took the
metal weight to contact the bottom of the upright cans which is
indicative of the fact that the diptube had uncoiled.
TABLE
Time in Contents Tying Ribbon Can No. Seconds
__________________________________________________________________________
Tire traction compo- Ethyl cellulose 1 200 sition* pressurized 2
304 with 80 psi carbon 3 115 dioxide 4 450 5 495 Bathroom Cleaner
Methyl cellulose 6 l95 composition** 7 440 pressurized with 80 8
500 psi isobutane
__________________________________________________________________________
* Composition consists substantially of methanol with polymerized
trimethyl quinoline dissolved therein. See patent 3,27l,170. **
Composition consists substantially of ater with minor amounts of
surfactants and chelating agents dissolved therein.
The above cans are used to spray the contents thereof and it is
found that they spray well in all positions with no change in the
spray pattern in any position. This indicates that the soluble
tying ribbons are compatible with the contents and do not interfere
with the spraying function.
Similar results to the foregoing are obtained when the coiled
diptubes are glued together with an adhesive made from methyl
cellulose, ethyl cellulose or polyvinyl alcohol, and are dried in
contiguous relationship prior to their insertion into the spray
cans.
* * * * *