U.S. patent number 3,660,054 [Application Number 05/076,601] was granted by the patent office on 1972-05-02 for coal upgrading.
This patent grant is currently assigned to Atlantic Richfield Company. Invention is credited to Robert W. Rieve.
United States Patent |
3,660,054 |
Rieve |
May 2, 1972 |
COAL UPGRADING
Abstract
A method for upgrading coal to a higher quality fuel or feed
stock by mixing coal with water and heating the mixture in a
non-oxidizing atmosphere at a temperature near the critical
temperature of water and under a pressure sufficient to maintain
substantially all of the water in the liquid state. By this process
at least the sulfur and/or ash content of the coal is reduced.
Inventors: |
Rieve; Robert W. (Springfield,
PA) |
Assignee: |
Atlantic Richfield Company (New
York, NY)
|
Family
ID: |
22133063 |
Appl.
No.: |
05/076,601 |
Filed: |
September 29, 1970 |
Current U.S.
Class: |
44/500; 44/624;
208/403; 44/608; 44/627 |
Current CPC
Class: |
C10L
9/00 (20130101) |
Current International
Class: |
C10L
9/00 (20060101); C10l 009/00 () |
Field of
Search: |
;44/1R,4
;23/224,227 |
References Cited
[Referenced By]
U.S. Patent Documents
Foreign Patent Documents
Primary Examiner: Dees; C. F.
Claims
The embodiments of the invention in which an exclusive property or
privilege is claimed are defined as follows:
1. A method for upgrading coal comprising mixing subdivided coal
and water in the weight ratio range of coal/water of from about 2
to about 0.1, heating said mixture in a nonoxidizing atmosphere at
a temperature of from about 600.degree. to about 706.degree. F.,
said heating being under a pressure sufficient to maintain
substantially all of the water in the liquid state and for a time
sufficient to reduce at least one of the sulfur and ash content of
said coal, and recovering the treated coal.
2. A method according to claim 1 wherein said pressure is in the
range of from about 1,545 to about 3,226 p.s.i.a.
3. A method according to claim 1 wherein said coal is subdivided to
be substantially all no greater than about 1 inch effective
diameter particles.
4. A method according to claim 1 wherein said coal is at least one
of bituminous and lignite and is subdivided to be substantially all
no greater than about 1 inch effect diameter particles, said
temperature is from about 650.degree. to about 706.degree. F., and
said time is for at least about 1 minute.
Description
BACKGROUND OF THE INVENTION
Heretofore coal has been extensively used as a fuel for the
generation of electricity, and the like and has also been employed
as the feed stock in processes for its conversion to gaseous and
liquid hydrocarbonaceous products from which fuel gas, gasoline,
residual fuel oil, and the like can be obtained. One process
utilizing coal as a feed stock is the hydrogenation of coal to
gasify and liquify same, a particularly suitable process being that
disclosed by U.S. Pat. No. Re. 25,770, the disclosure of which is
incorporated herein by reference.
It is highly desirable for evironmental purposes to reduce the
sulfur and ash content of any coal utilized as a fuel or as a feed
stock for a process which produces a fuel. Although sulfur
reduction can take place during the treatment of a coal feed stock
to convert the coal into a liquid or gaseous product from which
fuels can be obtained and although it is possible to reduce the
sulfur and ash content of stack gases after the coal or fuel
product obtained therefrom has been burned, it is most desirable to
reduce the content of these materials in the coal initially. This
is desirable because it renders the conditions of subsequent
burning or processing of the coal more flexible since they do not
have to provide extensive sulfur and ash treating facilities at
each location.
Accordingly, it is very desirable to be able to substantially
reduce at least the sulfur and/or ash content of a coal before it
is burned as a fuel or otherwise gasified and/or liquified for
further processing into specific fuels.
SUMMARY OF THE INVENTION
It has now been found that if coal is mixed with water and heated
in a non-oxidizing atmosphere at a temperature near the critical
temperature of water, but not above the critical temperature of
water, at least the sulfur and/or ash content of that coal is
reduced.
Accordingly, it is an object of this invention to provide a new and
improved process for upgrading coal. It is another object to
provide a new and improved process for the removal of at least a
portion of at least one of sulfur and ash from raw coal. It is
another object to provide a new and improved method for rendering a
raw coal more acceptable as a fuel or feed stock for further
processing into a fuel.
Other aspects, objects, and advantages of this invention will be
apparent to those skilled in the art from this disclosure and the
appended claims.
DETAILED DESCRIPTION OF THE INVENTION
According to this invention a coal, which can be one or a mixture
of two or more of anthracite, bituminous, semi-bituminous,
sub-bituminous, lignite, peat, and the like, is subdivided, for
example so that substantially all of the coal particles are no
larger than one inch in their largest cross-sectional dimension
(effective diameter), and mixed with water.
The mixing can be carried out in any desired manner so long as an
intimate mixture of coal particles and water is achieved and can be
conducted at sub-ambient, ambient, or super-ambient conditions of
temperature and pressure. Preferably, the coal and water are simply
mixed together at ambient conditions of temperature and pressure.
The mixture is preferably composed of coal and water in the weight
ratio range of coal/water of from about 2 to about 0.1.
The mixture is then heated in a non-oxidizing atmosphere, e.g.,
steam, inert gas, reducing gas, and the like, at a temperature of
from about 600.degree. F to about the critical temperature of
water, i.e., 706.degree. F. Although a broad temperature range of
from about 600.degree. to about 706.degree. F. can be employed, a
presently preferred range is from about 650.degree. to about
706.degree. F. It is important that the temperature of the water
during the reaction be near but not above the critical temperature
so that the water will be more monomeric than polymeric and more
adidic than normal. It is also important that the water not be in
the vaporous state to any substantial extent. The pressure should
be maintained sufficiently elevated so that substantially all of
the water will be maintained in a liquid state at the temperature
prevailing. The pressure therefore can be the autogenous pressure
of water vapor at the temperature of reaction and will generally
range from about 1,545 to about 3,226 p.s.i.a.
By following the above conditions substantial amounts of sulfur
and/or ash can be removed from the coal. The reaction should
therefore be carried out for a time sufficient to achieve these
results. This time will generally be at least about one minute,
preferably at least about five minutes, e.g., from about five
minutes to about sixty minutes.
The coal, after completion of the reaction time, can be recovered
with or separate from the water present in the reaction. The
recovered coal can be utilized, either with or without drying, as a
solid fuel or as a feed stock for a coal gasification and
liquifaction process.
EXAMPLE
Pittsburg No. 8 seam coal subdivided so that substantially all
passes a 100 mesh sieve and is retained on a 200 mesh sieve (Tyler)
was mixed with water in a weight ratio of coal/water of 0.25 by
simple stirring at ambient conditions of temperature, pressure and
under one atmosphere of nitrogen to provide an intimate mixture of
the coal particles and water.
The mixture was then heated in an autoclave at 650.degree. F. under
an autogenous pressure of 2,350 p.s.i.g. for 1 hour after which the
autoclave was vented to the atmosphere and most of the water
thereby expelled.
The standard coal analysis for the coal before and after treatment
was as follows:
Analysis, Wt. % MAF Coal Raw Coal Treated Coal Carbon 76.16 80.77
Hydrogen 5.21 4.76 Oxygen 5.96 5.49 Nitrogen 1.55 1.61 Sulfur 2.74
1.27 Ash 8.38 6.10 Volatile Matter 39.06 33.66 Fixed Carbon 52.56
60.24
It can be seen from the above data that the sulfur content was
reduced by 53.6 percent and that the ash was also reduced by 27.3
percent. With such a substantial reduction in both sulfur and ash
content, the treated coal was a much more acceptable burning fuel
and liquid fuel feed stock since it would introduce substantially
less sulfur and ash into the combustion products or other liquid
and gas products obtained therefrom.
Reasonable variations and modifications are possible within the
scope of this disclosure without departing from the spirit and
scope of this invention.
* * * * *