U.S. patent number 3,657,085 [Application Number 04/804,848] was granted by the patent office on 1972-04-18 for method of marking a transparent material.
This patent grant is currently assigned to Carl Zeiss-Stiftung, Carl Zeiss. Invention is credited to Dietrich Hoffmeister, Fritz Schleich.
United States Patent |
3,657,085 |
Hoffmeister , et
al. |
April 18, 1972 |
METHOD OF MARKING A TRANSPARENT MATERIAL
Abstract
An identification mark is made on a transparent workpiece, such
as a lens for spectacles, by irradiating the material in a pattern
desired for an identification mark with radiations which produce
localized permanent stresses in the material that are visible by
double refraction in polarized light. Suitable irradiation may be
provided by corpuscular radiation, as by an electron beam, or
electromagnetic radiation, as by laser beams. The radiation is
preferably applied in an amount to produce the stresses within the
material, not on the surface.
Inventors: |
Hoffmeister; Dietrich
(Oberkochen, DT), Schleich; Fritz (Wasseralfingen,
DT) |
Assignee: |
Carl Zeiss-Stiftung, Carl Zeiss
(Wuerttemberg, DT)
|
Family
ID: |
5687962 |
Appl.
No.: |
04/804,848 |
Filed: |
March 6, 1969 |
Foreign Application Priority Data
|
|
|
|
|
Mar 13, 1968 [DT] |
|
|
P 16 96 714.9 |
|
Current U.S.
Class: |
204/157.41;
351/159.69; 204/157.44 |
Current CPC
Class: |
B41M
5/262 (20130101); B44F 1/06 (20130101); C03C
23/0025 (20130101); G02C 7/021 (20130101); H01J
37/301 (20130101); C03C 23/003 (20130101); C03C
23/004 (20130101); H01J 37/30 (20130101); B41M
5/267 (20130101); B41M 5/26 (20130101) |
Current International
Class: |
B44F
1/06 (20060101); B44F 1/00 (20060101); H01J
37/301 (20060101); H01J 37/30 (20060101); G02C
7/02 (20060101); C03C 23/00 (20060101); B01j
001/10 () |
Field of
Search: |
;204/157.1 ;351/159
;250/49.5R |
References Cited
[Referenced By]
U.S. Patent Documents
Foreign Patent Documents
Primary Examiner: Williams; Howard S.
Claims
What is claimed is:
1. A method of marking a transparent material for identification
comprising irradiating said material by means of radiation applied
thereto in a pattern desired for an identification mark, said
radiation being applied at an energy density which generates
sufficient internal heat to produce localized permanent stresses
within the interior only of the material without producing such
stresses in its surface layer, the stress pattern so produced being
normally invisible but capable of being rendered visible by double
refraction in polarized light.
2. The method of claim 1 which said irradiating is accomplished by
applying accelerated electrons to said material in the form of a
focused electron beam.
3. The method of claim 2 in which said electron beam is moved over
the material in said pattern more than once.
4. The method of claim 2 in which said electron beam is moved over
the material in said pattern.
5. The method of claim 4 in which said electron beam is moved with
such a speed, that each element of said material is impinged with
an energy density of from about 1 .times. 10.sup.-.sup.3 to about 5
.times. 10.sup.-.sup.3 Ws/cm.sup.2.
6. The method of claim 1 which includes masking portions of said
material as means for defining a predetermined pattern of localized
stresses to be produced.
7. The method of claim 2 in which said electron beam is focused in
a line on said mask and is moved across it thereby impinging along
said predetermined pattern.
8. The method of claim 1 in which said irradiating is accomplished
by applying a laser beam to said material.
Description
FIELD OF THE INVENTION
The present invention relates to a method and apparatus for placing
identification markings on transparent material, such as glass. In
particular, the invention is a method and apparatus for making such
identification markings by applying radiation to the material to
produce a predetermined pattern of localized permanent stresses
therein which are rendered visible by applying polarized light.
PRIOR ART
Various means of placing identifying marks on transparent material,
such as lenses of spectacles, are known. One means has been to
engrave identification marks on portions of the articles, such as
the edges of lens, where the marks will not interfere with the
appearance or intended use of the article. A disadvantage of
engraved marks is that they are difficult to find. Also, a
particular disadvantage with marks engraved on the edge portions of
spectacle lenses is that they are apt to be completely or partially
obliterated when shaping the edge portions for fitting the lenses
into frames.
Another means is to etch a mark on the surface of the article. The
etching is suitably done with a stamp coated with an etching
substance and applied lightly to the surface of the workpiece so as
to make a weak etching which will be substantially invisible under
normal observation and which will not interfere with the appearance
or optical properties of the article. Such a mark may be placed at
a preselected position on the article -- at the center of a lens,
for example, so that it can be found easily. Then by hazing the
surface of the article the etched mark is rendered visible by the
difference in the condensation on the etched and on the unetched
portions. The problem with these etched marks, however, is that
they must be so lightly etched that they are worn off by the
polishing action of repeated cleanings of the surface.
OBJECTS OF THE INVENTION
Objects of the present invention are to provide an article of
transparent material, such as a lens, an identification mark which
is normally invisible, which does not alter the appearance or
optical properties of the lens, or other article, which may be
applied quickly and economically, which is durable, which is
difficult to alter or falsify, and which can be made visible by
simple means.
SUMMARY OF THE INVENTION
In accordance with this invention identification marks are provided
by applying radiations to the transparent material for producing in
the material a selected pattern of permanent stresses which are
rendered visible by double refraction under polarized light. The
particular design for the identification is suitably formed by
applying the radiations through cut-out portions of a mask placed
on the workpiece.
In accordance with a preferred form of the invention the radiation
consists of accelerated electrons as provided by an electron beam,
which is preferably applied so that the stresses thereby produced
are in the interior of the material. The electrons impinging on the
solid material are scattered by collisions with the molecules of
the material so that their kinetic energy is thereby transformed
into heat which produces permanent stresses in the material. The
depth of penetration of an electron beam into the material depends
on its velocity. The depth of penetration is defined as the depth
at which the probability of there being an electron of the impact
velocity V.sub.o has declined to 1/e. For example, when applying an
electron beam at an accelerating voltage of 100 KV, the depth of
penetration -- depending substantially on the density of the
material and the square of the accelerating voltage -- will be
approximately 10 - 15 microns.
The electrons initially penetrating the material heat the surface
only to a small extent, this heating being insufficient to produce
permanent stresses in the surface layer. As the electrons approach
their depth of penetration below the surface of the material the
aforementioned scattering of the electrons generates an amount of
heat which produces localized permanent stresses in the interior of
the material. For producing a desired stress pattern in a selected
area within the material, the beam is, therefore, applied to a
given area for only a few microseconds at a time; this stress
pattern may be more pronounced, still within its localized area, by
reapplying the beam several times to the same area.
The stress patterns thus produced have proved to be stable and,
therefore, permanent. Being below the surface, these stress
patterns do not change the appearance of the article and are not
destroyed or distorted by cleaning and polishing.
Marking in this manner is particularly adapted for placing
identifying marks on lenses. The marks being normally invisible may
be placed in a preselected position on the lenses -- the center,
for example -- where they can readily be found when polarized light
is applied to render the marks visible. It is substantially
impossible to alter or falsify the marks. And the marks do not
disturb the optical properties of the lenses or change their
surfaces in any way; electron-microscopic and polarization-optical
pictures of the surfaces of lenses so marked did not reveal any
changes at all.
As mentioned above, these marks are made visible by the double
refraction produced by applying polarized light to the marked
article.
Radiations for producing stress pattern identification marks in
transparent material, in accordance with this invention, may be
corpuscular radiation provided by an electron beam, as already
explained above, or by electromagnetic radiations, such as laser
beams. The use of laser beams is particularly recommended for
producing these marks in mass colored materials.
DRAWINGS
The invention will now be described in greater detail with
reference to the accompanying drawings in which:
FIG. 1 is a diagrammatic illustration of apparatus for producing an
identification mark in a transparent workpiece by means of electron
beams;
FIG. 2 is a perspective view showing a mask in line with a
workpiece for defining a desired stress pattern to be produced in
the workpiece by the apparatus of FIG. 1;
FIG. 3 is a perspective view of a mask in line with a workpiece
illustrating the production of a stress pattern by the application
of a laser beam;
FIG. 4 is a diagrammatic illustration of apparatus for applying
polarized light to a masked article for making the mark
visible.
DETAILED DESCRIPTION OF APPARATUS
In the apparatus illustrated in FIG. 1 an electron beam produced by
a cathode-ray source 1 passes through a tubular passage, which is
through a diaphram 2, to a cylindrical lens 3. The lenses 3 focus
the beam through a deflecting system 5 onto a mask 4 which is
supported in line with a workpiece 8 (such as a spectacle lens as
shown) supported on a rotatable plate 7, which is also movable up
and down as indicated by the arrow 9. The mask 4 is suitably a
tungsten sheet from which a full scale design of the desired
identification mark has been cut out.
As shown, the beam-producing end of the cathode-ray source 1, the
diaphragm 2 and the deflecting system 5 are within a housing 22
which has an opening 23 in optical alignment with the lens 3 and
deflecting system 5, and the mask 4 is adapted to be supported over
the opening 23. A high-vacuum valve 10 is in the housing 22 in line
between the deflecting system 5 and the opening 23 and defines a
chamber 11 in the portion of the housing above it. Pumps 12 and 13
are connected into a chamber 11 for evacuating it when the valve 10
is closed, the pump 12 being connected into the upper, or beam
generating, portion of the chamber 11 which is above the diaphragm
2.
The bottom end of the housing 22 is provided with a seal ring 6
around the opening 23 to engage the surface of a workpiece 8 for
sealing off the area of the workpiece against which the electron
beam impinges for producing the identification mark.
In operation, the valve 10 is closed to seal off the chamber 11
which is then evacuated by the pumps 12 and 13; the closing of
valve 10 also blocks the path of the electron beam to the mask 4.
The electric power to the cathode-ray source is turned on, while
the beam is blocked by a bias voltage. The plate 7 carrying one or
more workpieces 8 is rotated to center one of the workpieces with
the seal ring 6 and opening 23, after which the plate 7 is moved
upward until the latter workpiece firmly abuts the ring 6 to seal
the portion of the chamber 11 below the valve 10, and the area of
the workpiece within the ring 6, against outside pressure.
Then the valve 10 is opened, so that a partial vacuum is created
through the chamber 11 (including the cathode-ray source and the
area of a workpiece 8 within the ring 6). Together with the opening
of the valve the beam from the cathode-ray source is released so
that the beam is focused by the cylindrical lens 3 in a line on the
mask 4, as indicated in FIG. 2. The beam 14 is thereafter moved
across the mask 4 by operation of the deflecting system 5 so that
the beam impinges on the workpiece 8 in a pattern defined by the
design cut out of the mask.
The deflecting system 5 is suitably operated to scan the mask so
that a surface area of approximately 100 microns in diameter is
impinged upon for only a few microseconds for providing an energy
density of the electron beam 14 from 1 .times. 10.sup.-.sup.3 to 5
.times. 10.sup.-.sup.3 Ws/cm.sup.2. The beam 14 may be moved over
the mask 4 one or more times; multiple passes increase the
visibility of the stress pattern under polarized light.
After the beam 14 has thus been moved over the entire pattern of
the mask to produce a corresponding stress pattern in the workpiece
thereunder the valve 10 is closed thereby sealing the upper portion
of the chamber 11 from the lower portion. At the same time the beam
14 is blocked by a suitable bias voltage. The plate 7 is moved down
to disengage one workpiece 8 from the ring 6, and is rotated to
move a different workpiece 8 in position under the ring. Then, when
the plate is moved up again to fix the new workpiece in sealing
engagement with the ring, the valve 10 is opened and the
above-described marking operation is applied to the new
workpiece.
FIG. 3 illustrates the manner in which a laser beam 15 is applied
to produce a stress pattern identification mark in accordance with
this invention. As shown, the laser beam 15 covers the entire area
of the design cut out of the mask 4. Therefore, only a short laser
pulse is generated at one time to produce the entire mark.
FIG. 4 illustrates the use of apparatus for rendering visible the
stress pattern which has been produced in a workpiece 8 in the
manner described above. The apparatus comprises a light source 16,
a condenser 17, two crossed polarizers 18 and 19 and a magnifier
lens 20 in optical alignment for light from the light source 16, to
pass through a workpiece 8 placed between the polarizers 18 and 19
for an observer indicated at 21. The identification mark, magnified
by the magnifier lens 20, appears bright against a dark background.
By moving the workpiece 8 the identification mark is seen to have a
brilliantly shining character which lightens and darkens so as to
be particularly easy to recognize.
* * * * *