U.S. patent number 3,654,928 [Application Number 05/013,588] was granted by the patent office on 1972-04-11 for flushable wrapper for absorbent pads.
This patent grant is currently assigned to Kimberly-Clark Corporation. Invention is credited to David V. Duchane.
United States Patent |
3,654,928 |
Duchane |
April 11, 1972 |
FLUSHABLE WRAPPER FOR ABSORBENT PADS
Abstract
A flushable wrapper for sanitary napkins and other absorbent
pads. The wrapper comprises a non-woven fiber web bonded by
cold-water soluble polyvinyl alcohol and subsequently treated with
an insolubilizing agent which renders the polyvinyl alcohol
resistant to solubilization in a moisture laden environment. A web
thus bonded has enough wet strength and abrasion resistance to
perform satisfactorily at moisture levels encountered during normal
use, yet disintegrates sufficiently fast after soaking in excess
water to permit disposal by flushing.
Inventors: |
Duchane; David V. (Menasha,
WI) |
Assignee: |
Kimberly-Clark Corporation
(Neenah, WI)
|
Family
ID: |
21760706 |
Appl.
No.: |
05/013,588 |
Filed: |
February 24, 1970 |
Current U.S.
Class: |
604/364; 604/372;
604/375 |
Current CPC
Class: |
A61F
13/15211 (20130101); A61F 2013/530131 (20130101); A61F
2013/530182 (20130101) |
Current International
Class: |
A61F
13/15 (20060101); A61f 013/16 () |
Field of
Search: |
;128/284,287,290,296
;117/14A,161UE,139.5A |
References Cited
[Referenced By]
U.S. Patent Documents
Primary Examiner: Rosenbaum; Charles F.
Claims
What is claimed is:
1. An improved wrapper especially for use with sanitary napkins and
with pads for absorbing body fluids comprising a non-woven web of
textile-length fibers bonded by a normally cold-water soluble
polyvinyl alcohol, a portion of said polyvinyl alcohol being
cross-linked with borax in an amount sufficient to render said
polyvinyl alcohol water-resistant to an extent that under
conditions wherein the web picks up moisture in excess of 500
percent by weight the cross-linked portion of said binder remains
substantially insoluble, and under conditions wherein said web is
soaked in excess water said borax is leached out to destroy said
cross-links and to nullify substantially all of said water
resistance.
2. The improved wrapper of claim 1 wherein said cross-linked
portion comprises at least the exposed surface areas of said
polyvinyl alcohol.
3. The improved wrapper of claim 1 wherein said polyvinyl alcohol
is present in the amount of from about 5 percent to about 15
percent based on the weight of the fiber and the borax is present
in the amount of from about 2 percent to about 10 percent based on
the weight of the polyvinyl alcohol.
4. The improved wrapper of claim 1 wherein said polyvinyl alcohol
has a percent hydrolysis in the range of about 74 to about 98 and
in a 4 percent water solution at 20.degree. C has a viscosity of
about 21 to about 28.
5. The improved wrapper of claim 1 wherein said fibers are
cellulosic.
6. The improved wrapper of claim 5 wherein said fibers are
rayon.
7. A flushable sanitary napkin and the like comprising an absorbent
core enwrapped in a fluid pervious wrapper capable of being readily
disintegrated when soaked in excess water, said wrapper comprising
a non-woven web of textile-length fibers bonded by a normally
cold-water soluble polyvinyl alcohol, a portion of said polyvinyl
alcohol being cross-linked with borax in an amount sufficient to
render said polyvinyl alcohol water-resistant to an extent that
under conditions wherein the web picks up moisture in excess of 500
percent by weight the crosslinked portion of said binder remains
substantially insoluble, and under conditions wherein said web is
soaked in excess water said borax is leached out to destroy said
crosslinks and to nullify substantially all of said water
resistance, whereby the fibers in said web and in said napkin are
free to disperse completely in said water.
8. The napkin of claim 7 wherein said cross-linked portion
comprises at least the exposed surface areas of said polyvinyl
alcohol.
9. The improved wrapper of claim 7 wherein said polyvinyl alcohol
is present in the amount of from about 5 percent to about 15
percent based on the weight of the fiber and the borax is present
in the amount of from about 2 percent to about 10 percent based on
the weight of the polyvinyl alcohol.
10. The improved wrapper of claim 7 wherein said polyvinyl alcohol
has a percent hydrolysis in the range of about 74 to about 98 and
in a 4 percent water solution at 20.degree. C. has a viscosity of
about 21 to about 28.
Description
BACKGROUND OF THE INVENTION
Many attempts have been made to produce sanitary napkins and other
absorbent pads which for disposal purposes may be flushed away
safely in conventional toilets. While the individual absorbent
components of a sanitary napkin, i.e. wood fluff, absorbent cotton
batts, cellulose wadding and the like, are of such construction
that they easily disintegrate when agitated in water, the necessary
strength requirements for the fluid-pervious wrapper enclosing such
components is usually such that it will not disintegrate even after
extended exposure to water. Therefore, such wrapper elements must
first be removed by the user when an attempt is made to dispose of
the napkin in a toilet, otherwise the absorbent components will not
disintegrate because they cannot escape the confines of the
wrapper. Since such napkins will retain most of their bulk form if
retained in the wrappers, they frequently cause stoppages in the
disposal system when attempts at disposal are made, either
accidentally or intentionally, without first removing the wrapper.
The wrapper, of course, can be stripped off, but this procedure is
extremely inconvenient and unsanitary, and for that reason the user
usually prefers not to go to that trouble, and instead, will
dispose of the used napkin in a disposal bag or other container for
solid wastes.
Accordingly, there is a need to provide sanitary napkins and
similar absorbent pads with a wrapper which is strong enough to
perform its support and pad-retaining function and yet which will
disintegrate readily after a short time exposure in flowing water.
Non-woven fiber webs bonded by cold-water soluble adhesives such as
polyvinyl alcohol, polyvinyl methylether, glycol cellulose,
cellulose glycolate, methyl cellulose, and the like, have been
tried as sanitary pad wrappers and found to be readily
disintegratable in excesses of water. However, while the latter
characteristic was easily achieved, it was also found that these
water-soluble adhesives tended to soften and dissolve prematurely
in the presence of body moisture generated by perspiration and
discharged body fluids with the undesirable result that the wrapper
often weakened and ruptured while worn. Accordingly, such wrappers
were considered unsatisfactory for general use.
The present invention is directed to a non-woven napkin wrapper
which disintegrates in excess water after a short period, but which
also has sufficient wet strength to retain its integrity in use
when exposed to the moist environment of the body.
SUMMARY OF THE INVENTION
In accordance with this invention, a flushable nonwoven fabric,
suitable for use as a wrapper for sanitary napkins and other
absorbent pads, is provided by first applying to a web of fibers a
cold water soluble polyvinyl alcohol binder, such as by spraying,
impregnating, or printing. Before the polyvinyl alcohol treated web
is dried to set the binder, it is oversprayed with a solution of a
gelling or insolubilizing agent, such as borax. This agent, when
applied to the polyvinyl alcohol treated web before the polymer has
set to a film, reacts with the binder to cross-link at least the
exposed surface areas of the polymer sufficiently to render the
reacted binder somewhat water resistant after the web is dried.
Webs treated in this manner are found to retain much greater
strengths at the intermediate moisture levels normally encountered
during use, than webs bonded by untreated or unmodified polyvinyl
alcohol. Yet in large excesses of water, the insoluble nature of
the treated binder is nullified, and the web bonded with borax
treated binder disintegrates almost as fast as a web bonded by a
polyvinyl alcohol which is untreated. The large excess of water is
instrumental in leaching out the borax to destroy enough of the
cross-links in the polymer to reduce water-resistance to a
non-effective level.
Accordingly, it is an object of the present invention to provide an
improved fluid-pervious wrapper for sanitary napkins and other
absorbent pads, which wrapper retains sufficient strength to retain
its integrity during normal use in the presence of body moisture,
but disintegrates readily after a short time when deposited in
excess water such as in a toilet bowl, and when agitated in its
course through a sewer line.
Another object is to provide a sanitary napkin or the like in which
all the structural components, including the wrapper, will break
down to flushable size after a relatively short time when deposited
in the excess water found in conventional toilet systems.
These and other objects will become apparent by reference to the
following specification wherein various selected embodiments of the
invention are described.
DESCRIPTION OF THE PREFERRED EMBODIMENTS
A carded web composed of 1.5 denier rayon fibers having an average
length of 1 9/16 inch and weighing approximately 14 grams per
square yard was sprayed with a 3 percent solution of cold water
soluble polyvinyl alcohol, to provide a solids pickup of about 10
percent based on the web weight. The wet web was immediately
oversprayed with a 2 percent solution of borax to provide about 0.5
percent salt pickup based on the web weight and dried at about
90.degree. C. for about 20 minutes.
Another base web of the type described above was sprayed with the
same amount of polyvinyl alcohol in the manner indicated and then
oversprayed with a 2 percent solution of borax to provide about 1.0
percent salt pickup based on the web weight, and then dried.
A third web was treated in the same way, but with about 2.0 percent
salt pickup.
As a base for comparison, still another web of the same type was
prepared by bonding it with 10 percent by weight of polyvinyl
alcohol as indicated above while omitting the borax treatment
completely before drying.
Each of these webs was then tested for burst strength with the
following results:
---------------------------------------------------------------------------
BURST STRENGTH IN g./cm..sup.2
After Soaking In Excess Water Air 100% 500% 1/2 1 2 Sample Dry
Moisture Moisture Min. Min. Min.
__________________________________________________________________________
10% PVA alone 173 28.6 10.5 0.0 0.0 0.0 10% PVA- 0.5% borax 122
51.0 15.1 1.7 0.0 0.0 10% PVA- 1.0% borax 135 53.5 33.0 24.2 8.3
<1.6 10% PVA- 2.0% borax 153 73.5 38.5 37.0 16.0 7.9
__________________________________________________________________________
Percent moisture is calculated by spraying a web of known weight
with a predetermined amount of water.
Wet burst is measured by a simplified penetration tester. A 6-inch
square piece of the dry web, or the moistened web containing the
specified amount of moisture or soaked for the specified time, is
clamped between two 6-inch square plates of clear acrylic plastic
having a 5-inch diameter aperture in the center. The inner surface
of each plastic plate is covered with rubber to increase its
frictional grip on the clamped web. The plates are suspended from
blocks of wood so that the exposed area of web in the center of the
plates is disposed parallel to the surface of the laboratory
counter at a distance of about 3 1/2 inches. A 400 ml. stainless
steel beaker with a bottom surface area of 38.15 cm.sup.2 is placed
in the center of the suspended web and loaded with lead shot until
the beaker breaks through the web. The beaker plus shot is then
weighed and the weight divided by the area of the bottom surface of
the beaker to give the burst strength in grams per square
centimeter.
As indicated above, at each of the moisture levels shown, the borax
treated webs, while lower in dry strength, had significantly higher
wet burst strengths than the same web treated with polyvinyl
alcohol alone. The figures also indicate that as the amount of
borax picked up by, and reacting with, the binder in the web is
increased, the wet burst strength figures also increase. The
additional wet strength may be accounted for by either a larger
cross-linked surface area of the polymer, or a deeper penetration
of the borax into the polymer to give more interior
cross-linking.
In any event, after depositing each of the wrappers in excess water
to subject it to a short soaking period the following results were
noted. Strengths of the webs bonded with 10 % PVA alone and with 10
% PVA-0.5% borax were reduced to zero after 1 minute soaking so
that each of these wrappers readily disintegrated. The web bonded
with 10% polyvinyl alcohol crosslinked with 1% borax had a much
improved air dry strength and wet burst strength at 100 percent and
500 percent moisture, but nevertheless was reduced to a wet burst
strength of less than 1.6 g/cm.sup.2 after soaking for 2 minutes.
However, the web bonded with 10% PVA-2.0% borax did not degrade
sufficiently after even a 2 minute soak to disintegrate readily.
For comparison purposes, and as a basis for evaluating these
strength figures, it is noted that a bonded non-woven wrapper with
a wet burst strength of less than about 2 gm/cm.sup.2 is generally
weak enough to disintegrate sufficiently to be considered
flushable. Accordingly when borax substantially in excess of 1.0
percent based on the weight of the web, (or 10 percent of the
weight of the polyvinyl alcohol) is applied to the polyvinyl
alcohol bonded web, wet strength is too high for the intended
purpose.
In additional trials, sanitary napkins utilizing covers comprised
of the first three samples identified above were prepared and
tested in actual use. The users found that the wrappers bonded with
the PVA-borax treated binders held up well in contact with body
moisture and menstrual fluid, while a large number of the wrappers
bonded with untreated PVA failed. When the used napkins were placed
in a toilet bowl and allowed to soak for 30 seconds to 2 minutes,
the binder in wrappers of both the treated and untreated types
dissolved sufficiently to allow the entire napkin to disintegrate
upon flushing.
Limited trials of napkins wrapped with webs bonded with the 10%
PVA-2.0% borax binder found that wrappers bonded with this less
soluble binder did not disintegrate sufficiently fast after soaking
a suitable period to be considered satisfactory for toilet
disposal.
The polyvinyl alcohol employed in the above-described tests was of
a type which was about 79-82% hydrolyzed, had a viscosity of about
22 cps (4 percent solution at 20.degree. C.), and was readily
soluble in cold water. Other polyvinyl alcohols were also found to
perform well as long as they were cold-water soluble. For example,
polyvinyl alcohols having a percent hydrolysis in the range of 74
to about 98 are generally cold-water soluble and are suitable for
the described use. While a wide range of viscosities may be used
with various degrees of success, viscosities of about 21 to about
28 (4 percent solution at 20.degree. C.) are preferred.
When using cold-water soluble polyvinyl alcohols with the degree of
hydrolysis indicated above, the borax treatment was found to give
the bonded web a better burst strength at high moistures than webs
bonded with untreated polyvinyl alcohol binder of the same degree
of hydrolysis, while not substantially inhibiting ultimate solution
of the binder in excess water.
Functional wrappers were prepared using from 5% to 15% polyvinyl
alcohol by weight of fibers, and from 2% to 10% borax based on the
weight of the PVA (i.e. 0.1% to 1.5% borax on the weight of the
fibers). Below about 2% borax there was not sufficient
cross-linking to affect the wet strength. Above 10% the resulting
amount of crosslinking provided too much wet strength.
With regard to the amount of polyvinyl alcohol used to bind the
web, the following was noted; as the amount used was decreased
below 5% the web became too weak for practical use, and when the
amount used was increased above 15% the web tended to become too
sticky when moist to be of practical use. It was also found that as
the amount of adhesive is increased over 10 percent the degree of
strength added per unit of adhesive declines, so that the 10
percent level appears to be the most economical use of adhesive for
strength desired.
In addition to the rayon fibers of textile length described in the
specific examples, other synthetic textile fibers especially other
types of regenerated cellulose may be suitably used in the
non-woven wrapper, as well as natural cellulose fibers and various
mixtures of synthetic and natural fibers.
The polyvinyl alcohol may be applied by spraying, impregnation,
printing or the like. However, a printing application can be better
controlled and usually gives better softness and drying
qualities.
The borax should be applied after the polyvinyl alcohol binder has
been applied to the web, and preferably before the polyvinyl
alcohol has set to a film form. Spraying or wetting the web with
borax before applying the polyvinyl alcohol binder is not
satisfactory, since it causes the polyvinyl alcohol to gel
prematurely, making for a weaker bond, and causing the crosslinking
to take place in an area remote from the area which is contacted
first by the moisture during use, whereby it is less effective in
producing the desired results.
Any suitable absorbent core which is disintegratable in water may
be used for the pad filler in the sanitary napkin structure.
Soluble or insoluble baffle members as found in various sanitary
napkin structures may be used. While insoluble baffles such as thin
sheets of polyethylene film will not disintegrate in water, such
baffles are usually so thin, flexible and small that they will not
cause stoppages in sewerage systems having standard diameter
pipelines.
While the above described preferred embodiments relate particularly
to sanitary napkins, it will readily be seen that the wrapper is
equally applicable to other absorbent pads such as diapers,
hospital pads, absorbent bandages and the like.
* * * * *