U.S. patent number 3,652,410 [Application Number 04/820,630] was granted by the patent office on 1972-03-28 for multifunctional lubricant additive compositions and lubricating oils containing.
This patent grant is currently assigned to Mobil Oil Corporation. Invention is credited to Ralph Hollinghurst, Andrew G. Papay.
United States Patent |
3,652,410 |
Hollinghurst , et
al. |
March 28, 1972 |
**Please see images for:
( Certificate of Correction ) ** |
MULTIFUNCTIONAL LUBRICANT ADDITIVE COMPOSITIONS AND LUBRICATING
OILS CONTAINING
Abstract
Balanced oil additive compositions can be used in the engine,
gears and elsewhere of mobile equipment. Appropriate concentrations
of basic detergents, dispersants, antioxidants, extreme pressure
agents and friction modifiers are balanced.
Inventors: |
Hollinghurst; Ralph (Rayleigh,
EN), Papay; Andrew G. (Gloucester, NJ) |
Assignee: |
Mobil Oil Corporation
(N/A)
|
Family
ID: |
10219323 |
Appl.
No.: |
04/820,630 |
Filed: |
April 30, 1969 |
Foreign Application Priority Data
|
|
|
|
|
May 24, 1968 [GB] |
|
|
24,918/68 |
|
Current U.S.
Class: |
508/237; 508/398;
508/442; 508/438; 508/399; 508/435 |
Current CPC
Class: |
F24H
9/2085 (20130101); F23N 1/027 (20130101); F23N
5/02 (20130101); C10M 163/00 (20130101); C10M
3/00 (20130101); C10M 2219/088 (20130101); C10M
2215/28 (20130101); C10M 2219/024 (20130101); C10N
2010/14 (20130101); C10M 2217/046 (20130101); C10M
2215/042 (20130101); C10M 2207/027 (20130101); C10M
2215/08 (20130101); C10M 2219/087 (20130101); C10M
2207/40 (20130101); C10M 2219/046 (20130101); C10M
2223/042 (20130101); C10M 2215/12 (20130101); C10M
2207/129 (20130101); C10M 2207/026 (20130101); C10M
2207/125 (20130101); C10M 2219/044 (20130101); C10N
2010/04 (20130101); C10M 2207/028 (20130101); C10M
2207/283 (20130101); C10M 2207/023 (20130101); C10M
2221/041 (20130101); C10N 2040/02 (20130101); C10M
2207/404 (20130101); C10M 2217/06 (20130101); C10M
2215/26 (20130101); C10M 2219/082 (20130101); C10M
2219/089 (20130101); C10M 2223/065 (20130101); C10M
2215/086 (20130101); C10M 2215/102 (20130101); C10M
2223/045 (20130101); C10N 2040/08 (20130101); C10M
2225/02 (20130101); C10M 2219/022 (20130101); C10M
2215/04 (20130101); C10M 2207/287 (20130101); C10M
2219/02 (20130101); C10M 2223/04 (20130101); C10M
2209/084 (20130101); C10M 2207/34 (20130101); C10M
2215/082 (20130101); C10M 2207/024 (20130101); C10M
2207/282 (20130101); C10M 2225/00 (20130101); C10M
2225/041 (20130101) |
Current International
Class: |
C10M
163/00 (20060101); F23N 5/02 (20060101); F24H
9/20 (20060101); F23N 1/02 (20060101); F16B
39/24 (20060101); F16B 39/00 (20060101); C10m
001/48 () |
Field of
Search: |
;252/32.7E,33,42.7 |
References Cited
[Referenced By]
U.S. Patent Documents
Primary Examiner: Wyman; Daniel E.
Assistant Examiner: Vaughn; I.
Claims
What is claimed is:
1. An additive composition for a multipurpose lubricating oil,
comprising
A. from about 2 to about 15 parts by weight of a composition
comprising
i from about 50 to about 95 percent by weight of a mineral oil
soluble or dispersible, overbased metal salt selected from the
group consisting of alkaline earth metal sulfonates and phenates
and having a Total Base Number of at least 75, and
ii. From about 5 to about 50 percent by weight of a mineral oil
soluble antioxidant selected from the group consisting of tertiary
ditertiary alkylated phenols and a metal alkyl dithiophosphate, the
metal of which is selected from the group consisting of zinc,
cadmium and nickel, and the alkyl groups of which each have from
about 4 to about 12 carbon atoms, and
B. from about 1 to about 8 parts by weight of a composition
comprising
i. from about 30 to about 95 percent by weight of
1. a sulfurized C.sub.12-24 fat, or
2. from about 30 to about 95 percent by weight of a combination of
from about 50 to about 80 percent by weight of a sulfur-containing
compound selected from the group consisting of an alkyl sulfide and
an alkyl polysulfide the alkyl groups of which each have from 1 to
about 8 carbon atoms, and sulfurized polyolefins wherein the
olefins have from 2 to about 8 carbon atoms per molecule, and from
about 20 to about 50 percent by weight of a friction modifying
agent selected from the group consisting of sperm oil, a
C.sub.12-24 fatty acid and a C.sub.12-24 alkenyl sarcosine, and
ii. from about 5 to about 70 percent by weight of
3. an organic phosphite containing at least two alkyl or alkenyl
group having from about 12 to about 24 carbon atoms or an organic
acid phosphate each alkyl or alkenyl group of which has from about
12 to about 24 carbon atoms, or
4. a combination of 50 to about 80 percent by weight of an organic
di-alkyl phosphite, the alkyl groups of which have from 1 to about
8 carbon atoms, and from about 20 to about 50 percent by weight of
said friction modifying agent.
2. An additive formulation of claim 1 containing from 5 to 10 parts
by weight of (A) and from 2 to 5 parts by weight of (B).
3. An additive formulation according to claim 1, wherein the
detergent (A) (i) is a calcium sulfonate having a Total Base Number
of about 300.
4. An additive formulation according to claim 1, wherein the
antioxidant (A) (ii) is zinc dihexyl dithiophosphate.
5. An additive formulation according to claim 1 containing a
dispersing amount of an alkenyl succinic anhydride polyalkylene
polyamine.
6. An additive formulation according to claim 5 wherein the alkenyl
anhydride polyalkylene polyamine is a polybutene succinic anhydride
tetraethylene pentamine.
7. An additive formulation according to claim 1, wherein the
sulfurized fat (B) (a) (1) is sulfurized sperm oil containing about
13 percent by weight of sulfur.
8. An additive formulation according to claim 1, wherein the
sulfurized polyolefin (B) (a) (2) is a sulfurized polybutene
containing about 40 percent by weight of sulfur.
9. An additive formulation according to claim 1, wherein the
C.sub.12-24 alkenyl sarcosine is oleyl sarcosine.
10. An additive formulation according to claim 1 wherein the
organic phosphite (B) (b) (3) is dioleyl phosphite.
11. An additive formulation according to claim 1, wherein the
organic acid phosphate (B) (b) (3) is a C.sub.14-18 mixed alkyl
acid phosphate.
12. A multipurpose lubricating oil composition comprising an oil of
lubricating viscosity and from about 3 to about 23 percent by
weight, based upon the total oil composition of an additive
formulation of claim 1.
Description
BACKGROUND OF THE INVENTION
The present invention relates to multifunctional lubricant additive
compositions and to lubricating oils containing the same. More
particularly, the invention relates to oil compositions suitable
for use not only in the engine but also in the gears and elsewhere,
of mobile equipment such as a vehicle powered by an internal
combustion engine, especially a diesel engine.
The invention is particularly useful in the lubrication of
tractors, especially large tractors, dumpers, graders and other
heavy duty applicances, and in vehicles having common sump
lubrication of engine and axle wherein a limited slip differential
is used.
The art has developed an increasing variety of oil-based fluids
designed or adapted to perform many specific functions. Among such
functions are engine lubrication, power transmission, hydraulic
control and lubrication of gears such as those in the final drive
axle of a vehicle. Other such functions of particular interest in
connection with the present invention, are the oil immersion of
disc brakes, which we refer to as wet brakes, and use in power
take-off facilities for instance on a tractor.
Whereas these various functions may be served individually by
several separate oils each closely adjusted to a specific function,
it is a disadvantage to have to deal with so many different oils in
the operation and maintenance of one vehicle, being not only
inconvenient but liable to lead to serious and costly error on the
part of the less skilled operator. There is, therefore, a
preference for single oil compositions which can perform
satisfactorily more than one such function. This preference calls
for additives or additive combinations for lubricants which are
capable of fulfilling diverging demands.
Requirements of oils for various functions which give rise to
imcompatibility with other functions, include those tabulated
below.
ENGINE LUBRICATION
Detergents and dispersants for prevention of sludge, prevention of
ring sticking and maintenance of general cleanliness.
Antioxidants.
Mild antiwear agents to protect the valve train.
TRANSMISSION:
Mild antiwear agents.
Critical viscosity requirements (for hydrostatic transmission)
HYDRAULIC SYSTEM
Mild antiwear agents in some cases.
Temperature/viscosity control additives.
POWER TAKE-OFF CLUTCHES
High enough static friction (to permit torque transmission).
FINAL DRIVE AXLE GEARS
Moderate to considerable antiwear and extreme pressure agents.
WET BRAKES AND LIMITED SLIP DIFFERENTIALS
Specific friction modifiers to prevent objectionable chatter.
The problems encountered in attempts to reconcile these
requirements, are many. The detergents and dispersants commonly
used in engine oils may interfere with the operation of antiwear
and extreme pressure agents, and reduce axle gear protection.
Long-chain friction modifiers necessary to reduce static friction
and achieve acceptable wet brake anti-chatter may break down in the
engine and cause deposit problems. Excess friction modifier may
prevent proper power take-off operation by reducing torque
capacity; insufficient modifier will permit brake chatter. (Chatter
is a `stick-slip ` effect which appears when static friction in
disc brakes is too high and dynamic friction is too low). Some of
the most efficient friction modifiers, such as soaps, may interfere
with axle gear protection.
The use of oil thickeners of a polymeric nature, for example
polymethacrylates, will tend to set up top groove carbon filling
problems in many diesel engines, and necessitate increased
detergent.
The selection of detergents, extreme pressure agents and friction
modifiers is thus a critical matter in respect of the nature, the
relative balance, and the total dosage, of these ingredients.
Attempts have hitherto been made to satisfy the requirements of
more than one of the aforesaid functions in a single oil
Multifunctional tractor oils are known but they are deficient in
axle gear protection and in any case such oils are not envisaged
for use in wet brakes. Other multipurpose oils for application to
wet brakes, transmission, hydraulic systems or axle gears, have not
been envisaged for engine lubrication. A truly universal oil
satisfying the requirements of all the aforesaid functions has not
hitherto been considered.
It is an object of the present invention to provide an additive
composition and an oil containing said composition suitable for use
at least in the engine, and elsewhere, such as in powered axle
gears and wet brakes, of a mobile powered appliance, for example a
tractor.
In accordance with the present invention, there is provided an
additive formulation for a multipurpose lubricating oil comprising
a balanced combination of:
A. from about 2 to about 15 parts by weight of a composition
comprising
i. from about 50 to about 95 percent by weight of a mineral oil
soluble or dispersible, basic detergent having a Total Base Number
(TBN) of at least about 75,
ii. from about 5 to about 50 percent by weight of a mineral oil
soluble antioxidant selected from a metal alkyl dithiophosphate and
a phenol, and
B. from 1 to about 8 parts by weight of a composition
comprising
i. from about 30 to about 95 percent by weight of a sulfurized
C.sub.12 -C.sub.24 fat, or
ii. from about 30 to about 95 percent by weight of a combination of
from about 50 to about 80 percent by weight of a sulfur-containing
compound selected from the group consisting of alkyl sulfides and
alkyl polysulfides wherein the alkyl groups have from 1 to 8 carbon
atoms, and sulfurized polyolefins wherein the olefins have from 2
to 8 carbon atoms per molecule, and from about 20 to about 50
percent by weight of a friction modifying agent selected from the
group consisting of sperm oil, a C.sub.12 -C.sub.24 fatty acid and
a C.sub.12-24 alkenyl sarcosine, and
iii. from about 5 to about 70 percent by weight of (3) an organic
phosphite or an organic acid phosphate containing at least one
alkyl or alkenyl group having from about 12 to about 24 carbon
atoms, or (4) from about 5 to about 70 parts by weight of a
combination of an organic phosphite, the alkyl groups of which have
from 1 to about 8 carbon atoms and said friction modifying
agent.
Preferred additive formulations comprise from about 5 to about 10
parts by weight of (A) and from about 2 to about 5 parts by weight
of (B).
COMPONENT (A)
Component (A) can be considered to constitute an engine oil
additive composition.
In component (A), the basic detergent is preferably present to the
extent of from about 60 to about 90 percent by weight. The
antioxidant is present preferably in an amount of from about 5 to
about 25 percent by weight.
It is also contemplated that a portion of the detergent can be
replaced by a dispersant of the character defined below. Thus, up
to about 60 and preferably up to about 40 percent by weight of said
detergent can be replaced by one or more of the dispersants.
As a further modification, a portion of the antioxidant can be
replaced by an antiwear agent of the character defined below.
BASIC DETERGENT
The basic detergents are basic alkaline earth metal sulfonates and
phenates which include those in which excess metal has been
combined with the normal metal salts thereof. These compounds are
referred to as "overbased" metal sulfonates and phenates. The
higher the degree of overbasing the less is necessary to form the
oil soluble complex. The metal used in these overbased salts are
taken from Group II of the Periodic Table: barium, calcium, and
magnesium are especially effective. Those overbased sulfonate salts
described in U.S. Pat. Nos. 3,133,019 and 3,158,572 are
representative of suitable sulfonate reactants. They include the
petroleum and aromatic sulfonates. The alkaline earth metal
phenates described in U.S. Pat. No. 2,916,454 are examples of
suitable phenate reactants.
Still other typical basic detergents are described in U.S. Pat.
Nos.: 2,739,124; 3,036,971; 3,046,224; 3,133,019; 3,213,019;
3,259,576; and 3,350,310.
The amount of metal in the overbased salts may range from about 1
to about 20 percent of the total compound. These basic compounds
are also rated for alkalinity by a total base number (TBN) in terms
of milligrams of potassium hydroxide per gram of sample, using the
ASTM D-664 method. Suitable basic salts having TBN's ranging from
about 150 to 400 may be used.
It is also contemplated that a portion of the basic detergent can
be replaced by a neutral or low base number (TBN of 10-100),
metal-containing detergent such as a calcium, barium or magnesium
sulphonate, phosphonate or phenate, or of a reaction complex
containing such a compound, such as a phosphosulfurized polybutene
barium phenate sulphonate. Thus, the neutral or low TBN detergent
can be included with one or more basic detergents, with the proviso
that the TBN of the detergents is at least about 75.
ANTIOXIDANTS
Antioxidants used herein include phenols and metal alkyl
dithiophosphates, the metals of which are either zinc, cadmium or
nickel, and the alkyl groups of which contain from about 4 to about
12 carbon atoms.
Typical phenols include:
4-tertiary butyl catechol,
2,4-ditertiary butyl p-cresol,
2,6-ditertiary butyl-4-methyl phenol, and
2,2'-ethylene bis-2-6-ditertiary butyl p-cresol.
The metal alkyl dithiophosphates are illustrated by zinc dihexyl
dithiophosphate, zinc dioctyl dithiophosphate, cadmium dibutyl
dithiophosphate and nickel diamyl dithiophosphate.
DISPERSANT
The dispersant is substantially ash-free and preferably comprises
an alkenyl succinic anhydride polyalkylene polyamine. Such
dispersants are formed by reacting alkenyl succinic acid anhydrides
having from about 8 to about 18 carbon atoms in the alkenyl group
thereof, with a polyamine having the formula H.sub.2 N(R-NH).sub.n
H, wherein R is ethylene or propylene and n is an integer of from 1
to 6.
Methods for preparing the alkenyl succinic acid anhydrides are well
known, the most feasible method comprising the reaction of an
olefin with maleic acid anhydride (U.S. Pat. No. 2,638,450).
Examples of the alkenyl succinic acid anhydrides include: butenyl
succinic acid anhydride; and polybutene (molecular weight, 900)
succinic acid anhydride. Representative polyamines include:
ethylenediamine, propylenediamine, diethylenetriamine,
triethylenetetramine, tetraethylenepentamine, dipropylenetriamine
and amino substituted alkylamines, the latter having the formula
RNHCH.sub.2 CH.sub.2 Ch.sub.2 NH.sub.2 wherein R represents a
mixture of alkyl groups derived from a fatty acid.
Other suitable dispersants include glycol esters of said alkenyl
succinic acid anhydrides, obtained by esterifying the anhydrides
with glycols. Typical glycols for such reaction include ethylene
glycol, propylene glycol and trimethylene glycol.
Still other suitable dispersants include hydroxylamine esters of
said alkenyl succinic acid anhydrides. These are obtained by
esterifying the anhydrides with hydroxyl alkyl amines typified by
ethanolamines and propanolamines.
A preferred dispersant is a polybutene (molecular weight, 900)
succinic anhydride tetraethylene pentamine.
ANTI-WEAR AGENTS
There can also be present in component (A) from about 0.1 to about
2 percent by weight of an anti-wear agent comprising a metal alkyl
dithiophosphate, wherein the metal is zinc, cadmium or nickel and
the alkyl groups have from about 4 to about 12 carbon atoms. A
preferred agent is zinc dihexyl dithiophosphate.
COMPONENT (B)
Component (B) can be considered to have friction modifying and
extreme pressure characteristics.
In component (B), the sulfurized fat (a) (1) is preferably present
in an amount of from about 60 to about 90 percent by weight. The
sulfur-containing compound or polymer based thereon (a) (2) is
preferably present in an amount of from about 50 to about 80
percent by weight of (B), with the balance a friction modifier.
The phosphites or phosphates (b) (3) and (b) (4) are preferably
present in an amount of from about 10 to about 30 percent by weight
of (B). Friction modifying agents can be present in amounts of from
about 20 to about 50 percent by weight of a combination of (b) (4)
of (B). When either or both of the respective compounds providing
sulfur (a) and phosphorus (b) is a short chain compound (C.sub.1
-C.sub.8 alkyl), it is preferred to use 5-50 percent by weight of
the friction modifier.
In component (B), the weight ratio (a)/(b) can range from about
10:1 to about 1:1, more preferably 5:1 to 2:1. The weight ratio of
sulfur to phosphorus is preferably from 5:1 to 20:1. Fatty acid
compounds can be replaced by their corresponding salts.
SULFURIZED FATS
Conventional sulfur-containing compositions can be employed in the
additive compositions. These are compositions in which sulfur is
loosely or firmly bound. Typical of such compositions are
sulfurized animal, marine or vegetable oils and terpenes containing
up to about 20 percent by weight of sulfur. Sulfurized lard and
sulfurized sperm oils are representative compositions. Procedures
for preparing such compositions are provided in U.S. Pat. No.
2,993,858.
Other suitable sulfur-containing products include sulfurized
cardanyl alkyl ethers (2,361,353) and
sulfur-perchloromethylmercaptan products (2,329,324).
The sulfur-containing compounds, (B) (2), are alkyl sulfides, alkyl
polysulfides or sulfurized polyolefins. Representative of such
compounds are: diamyl sulfide; di tertiary butyl disulfide and
sulfurized polybutenes containing up to about 50, and preferably
about 40, percent by weight of sulfur.
Friction modifying agents include sperm oil, C.sub.12-24 fatty
acids such as lauric, myristic, palmitic, stearic and oleic acids,
and substituted fatty acids typified by oleyl sarcosine.
ORGANIC PHOSPHITES AND ORGANIC ACID PHOSPHATES
As indicated, the phosphites can be those containing at least one
alkyl group having from about 12 to about 24 carbon atoms,
illustrated by dioleyl phosphite and dilauryl phosphite. Other
phosphites are those in which the alkyl groups have from 1 to about
8 carbon atoms, and are illustrated by dibutyl phosphite and amyl
phenyl phosphite.
The organic acid phosphates are represented by: mono- and
di-stearyl acid phosphates; mixed C.sub.14 -C.sub.18 alkyl acid
phosphate; lauryl acid phosphates; and oleyl acid phosphates.
LUBRICANT COMPOSITIONS
The components of the additive thus selected are blended to obtain
a combination which, when incorporated in a suitable base oil,
provides a balance of properties. That is to say, the requirements
of the various functions to be served by the oil are all met by the
balancing of the contending factors; the actual numerical
proportions of each ingredient to satisfy such a balance vary
according to their specific nature and that of the oil and
according to other factors such as the type of appliance and
performance called for, but are readily determined in practice
within the area of choice provided by the invention. It will be
appreciated for instance that the extreme maximum or minimum
specified amounts of the various ingredients are not necessarily
applicable together in the same composition.
According to the present invention, therefore, a multipurpose
lubricating oil composition comprises 3 to 23 parts by weight in
100 parts of the total oil composition, i.e. 3 to 23 percent by
weight, of an additive composition comprising (A) and (B) as
defined above, dispersed in an oil of lubricating viscosity of
synthetic, mineral or mixed origin. Any oil can be used which is
suitable as a lubricant base. Other additives can be incorporated
for various known purposes such as viscosity index improvers, e.g.
polymethacrylates.
It has been found surprisingly that oils of the present invention
not only fulfill requirements for engine oil, transmission and
hydraulic fluids but also those for wet brakes and power take-off
clutches, so that the oil of the invention represents a major
advance in providing a universal oil for a powered vehicle of the
type referred to.
The lubricating vehicles employed can comprise any of the
conventional oils of lubricating viscosity including mineral or
synthetic lubricating oils, or mixtures thereof. Mineral
lubricating oils can be of any suitable lubricating viscosity
ranging from about 45 SSU at 100.degree. F., to about 2,000 SSU at
100.degree. F. and preferably from about 50 to about 250 SSU at
210.degree. F. These oils may have viscosity indexes, varying from
below 0 to about 100 or higher. Viscosity indexes from about 70 to
about 95 are preferred.
The following Examples, given in Table 1 for the purpose of
illustrating the invention, represent additive combinations
according to the invention, with varying balances of requirement,
for engine, rear axle and wet brake performances. The figures
represent parts by weight. ##SPC1##
Each of the foregoing Examples of additive combination is
incorporated in a base mineral oil stock with suitable viscosity
index improver, namely, to make up to 100 parts by weight,
including optional amounts of for example 0.15 parts of a silicone
defoamant such as dimethyl silicone (DCF 200 of Dow Corning).
The base mineral oil stock and viscosity index improver will, of
course, be selected according to known requirements, within the
limits of requirements set by the various functions to be served. A
typical balanced oil contains by weight
65 percent 150-second neutral paraffinic stock
22.5 percent 500-second neutral paraffinic stock
10 percent 100-second solvent naphthenic stock together with as
viscosity index improver
2.5 percent high molecular weight polymethacrylate (Acryloid 940 of
Rohm & Haas).
This oil has a final viscosity in the SAE 20/30 region, and a low
temperature viscosity of 4,000 c.p.s. at 0.degree. F. If in order
to increase low temperature fluidity a too volatile naphthenic
component is used, engine oil consumption problems are
encountered.
The foregoing additive combinations of Examples 1 to 8, made up
with the aforesaid base oil and viscosity index improver, were
tested and compared with two prior art multifunctional oils, I and
II, with the results tabulated below in Table 2. Oil I was a
conventional "universal" tractor oil containing a
detergent/dispersant combination with an anti-oxidant, employing an
overbased calcium sulphonate and a low base number barium
phosphonate/sulphonate, with zinc dithiophosphate. Oil II was a
multi-purpose oil containing a proprietary additive combination
which is recommended for use in wet brake oils, and includes a low
base number barium detergent, a friction modifier and zinc dialkyl
dithiophosphate.
The test methods used to obtain the results in Table 2 are as
follows:
Viscosity at 210.degree. F: IP * 71.
Viscosity at 0.degree. F: Brookfield viscosity determination
according to CRC Designation L-45-1262.
IAE Gear Test IP 166.
Petter AV-1 IP 175 (DEF ** 2101D, modified)
Petter W-1 IP 176 (DEF 2101D, modified)
(* IP: Institute of Petroleum
** DEF: British Ministry of Defense Specification)
WET BRAKE TRACTOR CHATTER TEST
Chatter is a loud rattling, clanking sound which is entirely
different from any noise usually heard on a tractor, and which
occurs most noticeably in field service when the brake on one side
is applied while the tractor is moving slowly. This test procedure
simulates such service, and most resembles turning the tractor
around with one wheel stationary when reversing to run back down an
adjacent crop row.
A John Deere 4010 tractor, with right brake and planetary housing
especially compartmented to permit testing of 1-gallon quantities
of lubricant, is operated on a stationary pad with the left axle
locked. Each test consists of a series of stepwise brake
applications covering a range of speeds and brake pressures. Runs
are started with the brake friction surface approximately
10.degree. F. above ambient temperature. Observations of brake
chatter are obtained from recordings of locked axle torque, taken
with strain gauge instrumentation, on a CED oscillograph. Axle
revolutions per minute, and friction pad surface temperature, are
also recorded. A new brake disc and new friction pads are fitted
before each test.
Wet brake chatter is assessed by comparing friction and torque
gauge readings obtained on the test oil with those obtained on a
reference oil. The good antichatter performance of the reference
oil has been confirmed by field experience. ##SPC2##
The data in the foregoing Table 2 show the essential advantages of
the composition of the invention, namely the ability to lubricate
engines (which multipurpose wet brake oils cannot) and wet brake
anti-chatter and load-carrying performance superior to those of a
conventional "universal" tractor oil.
The invention thus provides for the first time an oil which can be
used effectively in all lubricating functions of vehicles of the
type referred to.
* * * * *