U.S. patent number 3,648,882 [Application Number 05/015,570] was granted by the patent office on 1972-03-14 for package for highly viscous tacky materials.
This patent grant is currently assigned to Esso Research and Engineering Company. Invention is credited to Marcus H. Shelton.
United States Patent |
3,648,882 |
Shelton |
March 14, 1972 |
PACKAGE FOR HIGHLY VISCOUS TACKY MATERIALS
Abstract
A packaging container for highly viscous low molecular weight
tacky polymers comprising a container having at least one removable
end and a removable polymeric liner coated with a release
agent.
Inventors: |
Shelton; Marcus H. (Baytown,
TX) |
Assignee: |
Esso Research and Engineering
Company (N/A)
|
Family
ID: |
21772197 |
Appl.
No.: |
05/015,570 |
Filed: |
March 2, 1970 |
Current U.S.
Class: |
220/495.01;
206/447; 220/625; 220/62.11; 206/524.3 |
Current CPC
Class: |
B65D
25/14 (20130101) |
Current International
Class: |
B65D
25/14 (20060101); B65d 025/14 () |
Field of
Search: |
;220/63 ;150/50
;206/84 |
References Cited
[Referenced By]
U.S. Patent Documents
Foreign Patent Documents
Primary Examiner: Leclair; Joseph R.
Assistant Examiner: Garrett; James R.
Claims
What is claimed is:
1. A packaging container which comprises:
a. a tubular container body having at least one removable end
closure, the interior of said end closure being continuously coated
with a release agent;
b. a liner disposed in and substantially longer than said container
body, said liner being composed of a material capable of remaining
nonembrittled, nondegraded and substantially unsoftened at
temperatures equal to those of any substance to be packaged in said
container, which material has been continuously coated with a
release agent;
c. a removable bottom member inserted within said liner, said
member having a peripheral radially outwardly opening groove and
having disposed on its upper side and overlying said peripheral
groove a sheet of the material set forth in (b), said sheet also
being coated with said release agent; and
d. means for securing said liner and said sheet in the peripheral
groove so as to form a receptacle sealed at one end.
2. The packaging container of claim 1 wherein said material is
selected from the group consisting of a heat stabilized nylon, an
ethylene glycol-terephthalic acid polyester, and a clay coated
kraft paper.
3. The packaging container of claim 1 wherein said securing means
is a polymeric cord having a melting point above the temperature of
any substance to be packaged in said container.
4. The packaging container of claim 1 wherein said container is
cylindrical.
5. The packaging container of claim 1 wherein said release agent is
a silicone release agent.
6. The packaging container of claim 5 wherein said silicone release
agent is selected from the group consisting of dimethyl silicones,
methyl silicones containing silanic hydrogens, and hydroxy dimethyl
silicones.
7. The packaging container of claim 5 wherein said silicone release
agent has a viscosity at 77.degree. F. of from 10 to 30,000 cs.
8. The packaging container of claim 5 wherein said silicone release
agent has a viscosity at 77.degree. F. of from 50 to 1,000 cs.
9. The packaging container of claim 5 wherein said silicone release
agent has a viscosity at 77.degree. F. of from 100 to 500 cs.
Description
BACKGROUND OF THE INVENTION
Most highly viscous tacky polymers such as low molecular weight
polyisobutylene are mixed and packaged "hot," e.g., greater than
250.degree. F., so that the material will flow to some extent or at
least be pourable. Containers for these types of materials must be
able to withstand the hot packaging temperatures of approximately
200.degree. to 400.degree. F. and at the same time permit the
contents to be readily removed for final use.
These materials are presently packaged in expensive metal
containers which are of much lighter weight than is desired for
product protection and durability since the container must be
peeled from the product in use. These containers are generally
coated with a release coat which must be manually applied after the
can is manufactured and is therefore generally of poor quality.
SUMMARY OF INVENTION
It has now been found that low molecular weight tacky polymers may
be readily removed from their containers by providing the container
with a removable release agent-coated inner liner having a readily
detachable bottom member.
BRIEF DESCRIPTION OF DRAWING
The various objectives and features of the invention will be fully
understood by reference to the accompanying drawings, which show a
preferred embodiment thereof:
FIG. 1 is a perspective view of the packaging container constructed
in accordance with the teachings of the present invention.
FIG. 2 is a vertical cross-sectional view of the securing means
taken substantially along the line 2--2 of FIG. 1.
FIG. 3 is a perspective view of the bottom member of the inner
liner showing the securing slit for the cord.
THE INVENTION
It has now been discovered that it is possible to prepare an
improved packaging container which when used for highly viscous low
molecular weight tacky polymers affords much greater product
protection, is more durable, results in practically no loss of
product by attachment to the container or by leakage, and yet
allows removal of its contents within shorter times and with much
greater facility than had previously been possible.
The container of this invention is suitable for use for such tacky
polymers as polyisobutylene having a Staudinger molecular weight of
8,000 to 12,000, polybutenes having Staudinger molecular weights of
about 3,000 to 6,000, low molecular weight butyl rubbers and
halogenated butyl rubbers and like compounds which are normally not
pourable at room temperature, but exhibit cold flow at room
temperature and are sufficiently tacky to be removed from
conventional containers only with difficulty.
The packaging container comprises a container body supplied with an
inserted inner liner substantially longer than said container body,
said liner having attached to it a readily removable bottom member.
By the term "container body" is meant any suitable container having
vertical side walls and at least one end which can be removed or
opened. The container may be in any conventional shape, i.e.,
cylindrical, box, etc. However, the cylindrical shape is preferred
because of stress factors. Illustrative of the container materials
which may be used are fiberboard, corrugated boxes, metal drums and
the like.
The inner liner may be any suitable material capable of
withstanding hot packaging conditions without becoming embrittled
or being subject to degradation or any substantial softening, i.e.,
softening to the point of adhering to the polymer being packaged.
Various polymeric films have been found to be useful for this
purpose. Typical of the types of film which may be used are
polyester films and heat stabilized nylon. Preferably, the
polymeric film has a thickness of about 0.5 to about 5 mils; more
preferably, about 1 to about 3 mils.
A particularly suitable polyester film is the reaction product of
ethylene glycol and terephthalic acid which is known to the trade
by the duPont trademark "Mylar."
Heat stabilized nylons are well known and are prepared by specially
heat treating a nylon film. Particularly preferred are the nylons
prepared from a C.sub.6 monomer, i.e., "nylon 6." Illustrative of
such heat stabilized nylon films is Allied Chemical's Capran 80,
which has the following physical properties: at 72.degree. F.,
tensile strength of 10,000-14,000 p.s.i., yield strength of
5,000-8,000 p.s.i., tear strength of 70-100 g., elongation of
400-600 percent, negligible solubility in water, crystalline
melting point of 424.degree.-428.degree. F.; at 300.degree. F.,
tensile strength of 6,000-7,000 p.s.i., yield strength of
2,500-2,700 p.s.i., and elongation of 400-500 percent.
In order that the polymeric films release properly from the
packaged polymer, it is necessary to coat the film with a release
agent. Various release agents may be used in the practice of this
invention. Preferably, the release agents are silicone fluids
having a viscosity of about 10 to about 30,000 centistokes at
77.degree. F., preferably about 50 to about 1,000 centistokes, most
preferably about 100 to about 500 centistokes. The materials are
well known to the art, having carbon to silicon linkages such as
disclosed in U.S. Pat. Nos. 2,448,756; 2,484,595 and 2,541,137
incorporated herein by 2,541,137, These polymers have the general
structure:
wherein R.sub.1 and R.sub.2 are selected independently from methyl
and hydrogen wherein either R.sub.1 or R.sub.2 is methyl and the
other is methyl or hydrogen. Where both R.sub.1 and R.sub.2 are
methyl, the fluids are known as dimethyl silicones or dimethyl
siloxanes. The hydrogen attached to the silicon is termed a silanic
hydrogen.
The silicone fluids of this invention may, if desired, be cured
after application to the polymeric film. The fluids may be applied
as the neat oil or from a solvent solution. The solvent may be
C.sub.6 -C.sub.8 alkanes such as hexane, heptane or 2-ethyl hexane,
C.sub.6 to C.sub.8 aromatics such as benzene, toluene or xylene or
any of the well-known chlorinated solvents such as methylene
chloride or chlorobenzene. Generally, the silicone fluid is present
in the solvent at about 30 wt. %.
Where either R.sub.1 or R.sub.2 of the silicone fluid is hydrogen,
that is a methyl silicone having silanic hydrogens, the fluid is
moisture curable below 50.degree. C. in the presence of a catalyst
such as dibutyl tin dilaurate, or dibutyl tin di-2-ethyl hexoate.
High temperature cures are accomplished in the presence of
catalysts such as zinc octoate.
Where both R.sub.1 and R.sub.2 are methyl, the fluid may be
moisture cured by the addition of a silanol and a catalyst such as
an organic titanate, e.g., tetraisobutyl titanate and
tetra-2-ethylhexyl titanate.
The dimethyl silicones are also available as hydroxy terminated
polymers which may be cured in the presence of organic titanates
without the addition of silanols to the polymer.
Illustrative of the dimethyl silicones are Union Carbide and
Carbon's L-45 series fluids and General Electric Company's SF 96
series fluids, both products being available in a wide range of
viscosities up to about 100,000 cs. at 77.degree. F. Illustrative
of silicone fluids having silanic hydrogens are Union Carbide and
Carbon's L-31, a silicone fluid having a viscosity of about 35 cs.
at 77.degree. F. and Y-4006 fluids and Dow Corning's Dow Corning 23
silicone fluid. The Y-4006 and Dow Corning 23 fluids are supplied
at 30 wt. % neat oil in xylene. Illustrative of the hydroxy
terminated dimethyl silicones are Union Carbide and Carbon's W-900
and Y-1480.
It has been found that the thickness of the release agent coating
is not critical. However, it is essential that the coating be
continuous. For example, a continuous coating whose thickness is in
the angstrom range will suffice, whereas a discontinuous coating of
several mils will not release properly.
Though many coated release papers are available on the market, such
as silicone coated glassine, silicone coated parchment and silicone
coated latex treated stock, and are effective as release surfaces,
they are not generally suited for use in the practice of this
invention since they become excessively embrittled by the heat
history of hot packaging and can be removed only in small
pieces.
Surprisingly, it has been found that cellophane is a satisfactory
release surface for the purpose of this invention. It is not
embrittled by packaging heat history and may be removed from the
packaged polymer without the aid of a release agent.
The cellophane may be removed from the packaged polymer by wetting
with water. The water breaks the bond between the polymer and the
cellophane, and the cellophane, having sufficient cohesive
strength, is removed in one piece. Preferably, the cellophane film
is about 0.5 to about 5 mils in thickness, more preferably about 1
to about 3 mils.
The term "cellophane" as used in this specification and claims
means films produced from wood pulp by the viscose press, known in
the trade as "uncoated type" cellophanes.
Illustrative of suitable cellophane films are the cellophanes known
to the trade as type PD, type PUD and type PUD-O cellophanes which
are available from E. I. duPont de Nemours and Co.
Although other release papers have been found to be not generally
suitable for use in the practice of this invention, it has
surprisingly been found that clay coated kraft paper having a basic
weight of at least about 30 lbs. per 1,000 ft..sup.2, and
preferably at least about 50 lbs. per 1,000 ft..sup.2, coated with
a previously discussed silicone release agent, is a suitable
release surface for the purpose of this invention.
Further, kraft paper having the same basic weight requirements as
above, if coated with finely divided mica, is also a suitable
release surface. The finely divided mica should have a platelet
shape with a thickness of about 20 to about 200 angstroms and about
100 times thickness in diameter. Preferably, the mica is a
synthetic mica. Synthetic mica is a fluorine derivative of
phlogopite made by treating potassium fluorosilicates with alumina
under pressure and heat or by melting basic oxides, fluorides and
feldspar together.
Illustrative of the synthetic mica coatings which may be used is a
product known in the trade by the Minnesota Mining &
Manufacturing Co. trademark "Burnil" Brand Microplates. "Burnil"
Brand Microplates are extremely thin platelets of synthetic mica.
The average particle size is about 20-100 angstroms in thickness
and about 100 times thickness in diameter. The platelets have a
melting point of 1,800.degree. F., a density of 2.7 g./cc. and a
refractive index of 1.5.
The readily removable bottom member, which in the case of a
cylindrical container would be a disc, is constructed so as to have
a peripheral groove, as best illustrated in FIG. 2. One simple
method of constructing this bottom member is by lamination of two
equally shaped pieces of fiberboard in such a fashion that some 1
1/2 inches of the periphery remains unglued. Other similar
techniques (e.g., stapling) are equally applicable.
This member has its upper side, i.e., the side which will be
exposed to the substance to be packed, covered with a sheet of the
same material treated in the same fashion as that used for the
inner liner. This sheet extends beyond the periphery of the member
and is positioned so as to overlap the peripheral groove. The
bottom member is then inserted within the inner liner and the sheet
and liner secured within the peripheral groove so as to form a
receptacle or bag sealed at one end.
Securing the liner and bottom may be accomplished by any suitable
means; however, the preferable method involves wrapping a cord
around the exterior of the liner and tightening so as to draw both
the liner and the covering sheet into the groove of the bottom
member. The ends of the cord can then be secured in a slit placed
in the lower edge of the bottom member (as shown in FIG. 3),
thereby allowing ready removal of both the cord and bottom member
when desired. The slit should be approximately equal to the
thickness of the cord to insure the cord being held in place.
The cord should be one capable of withstanding the relatively high
temperatures of the substance to be packed without losing its
effectiveness. For polymeric materials this would mean having a
melting point above this temperature. Some examples of cords useful
in this invention are monofilament and braided heavy gauge nylon,
polyester, and soft metal wire.
In the preferred embodiment of this invention as shown in the
drawings, the packaging container comprises a cylindrically shaped
body 11 having a removable end 12 the interior of which is coated
with a silicone release agent, and being equipped with an inner
liner of heat stabilized nylon 13 continuously coated with the
silicone release agent and extending beyond the container body some
3 or 4 inches, a disc with a peripheral groove inserted in said
inner liner 14, said disc having its upper surface covered with a
sheet of the coated nylon which extends beyond the disc and
overlaps the peripheral crevice 15, and a nylon cord 16 wrapped
around the exterior of the liner and tightened to pull both liner
and sheet into the peripheral groove. The cord is then secured in a
slit 17 in the lower edge of the disc. The container is then filled
with the polymer, the extending portion of the inner liner folded
over the container body, and the removable end put in place and
sealed by means of tape, plastic or metal straps, and the like.
While the foregoing description and accompanying drawings
illustrate a preferred manner of employing this invention, many
different embodiments may be made without departing from the spirit
and scope thereof and it is to be understood that the present
invention is not limited to the specifically disclosed examples
thereof.
* * * * *