U.S. patent number 3,646,248 [Application Number 05/117,475] was granted by the patent office on 1972-02-29 for electric cable.
This patent grant is currently assigned to Anaconda Wire and Cable Company. Invention is credited to Ting H. Ling, Marwick H. Solomon.
United States Patent |
3,646,248 |
Ling , et al. |
February 29, 1972 |
ELECTRIC CABLE
Abstract
An electric cable is insulated with a cross-linked olefinic
terpolymer and has a semiconducting cross-linked olefinic
terpolymer jacket closely applied over the insulation. Different
curing systems are employed for the insulation and jacket with the
result that the jacket will maintain a void-free contact with the
insulation but may still be stripped cleanly from it.
Inventors: |
Ling; Ting H. (Marion, IN),
Solomon; Marwick H. (Marion, IN) |
Assignee: |
Anaconda Wire and Cable Company
(N/A)
|
Family
ID: |
22373147 |
Appl.
No.: |
05/117,475 |
Filed: |
February 22, 1971 |
Current U.S.
Class: |
174/120SC;
174/102SC; 174/105SC; 427/118; 427/120 |
Current CPC
Class: |
B29C
48/06 (20190201); H01B 13/14 (20130101); H01B
9/027 (20130101); H01B 7/02 (20130101); B29C
48/022 (20190201); B29C 48/304 (20190201); B29K
2101/10 (20130101); B29K 2105/20 (20130101); B29K
2301/10 (20130101); B29L 2031/3462 (20130101) |
Current International
Class: |
B29C
47/00 (20060101); B29C 47/06 (20060101); H01B
9/02 (20060101); H01B 13/14 (20060101); H01B
13/06 (20060101); H01B 7/02 (20060101); H01B
9/00 (20060101); H01b 007/02 () |
Field of
Search: |
;174/12R,12SR,12SC,12AR,12SC,11R,15SC,16SC ;117/215 |
References Cited
[Referenced By]
U.S. Patent Documents
Primary Examiner: Myers; Lewis H.
Assistant Examiner: Grimley; A. T.
Claims
We claim:
1. An electric power cable comprising:
A. an elongated conductor,
B. a wall of electrical insulating composition surrounding said
conductor, said composition comprising:
1. an olefinic terpolymer, and
2. a first curing system for said terpolymer, said insulating
composition being cured by means of said system, and
C. a wall of semiconducting composition directly surrounding said
wall of insulating composition comprising:
1. an olefinic terpolymer and
2. a second curing system for olefinic terpolymers differing
essentially from said first curing system, said semiconducting
composition being cured by means of said second system.
2. The cable of claim 1 wherein said first curing system comprises
an organic peroxide.
3. The cable of claim 1 wherein said first curing system comprises
di-.alpha.-cumyl peroxide.
4. The cable of claim 1 wherein said second curing system comprises
sulfur.
5. The cable of claim 2 wherein said second curing system comprises
sulfur.
6. The cable of claim 3 wherein said second curing system comprises
sulfur.
7. The method of making an electric power cable comprising the
steps of:
A. continuously extruding a wall of insulating composition,
comprising an olefinic terpolymer and a first curing system, over
an elongated conductor,
B. before curing said insulating composition continuously extruding
a wall of semiconducting composition comprising an olefinic
terpolymer and a second different curing system directly over said
insulating wall, and
C. continuously heating said cable so as to cure said insulating
and said semiconducting compositions.
Description
BACKGROUND OF THE INVENTION
Power cables for operation above about 2,000 volts are required to
have an electrical shielding layer surrounding the outer surface of
the cable insulation. This layer should be intimately in contact
with all points of the entire outer surface of the insulation so
that there will, at no time, be any voids or pockets of ionized air
or vapor adjacent to the insulation. It is well documented that
ionization or corona on an insulation surface will cause
deterioration of the dielectric properties of the insulating wall
and may eventually lead to cable failure. One known method of
making intimate contact between the insulation surface and the
shielding layer is to employ a semiconducting polymeric composition
for shielding and to extrude this composition directly over the
insulated cable conductor. A disadvantage of known cables, made in
this manner, resides in the fact that when the insulating and
shielding compositions comprise different polymers the walls of
insulation and shielding will have different thermal coefficients
and, in addition, may require some adhesive interface to assure
adequate contact. When, on the other hand, the same polymer is used
for the insulation and the shielding layer, the latter bonds so
firmly to the former that it is difficult and costly to strip the
shielding layer at joints and terminations.
SUMMARY
I have overcome the deficiencies of known cables by the invention
of an electric power cable comprising an elongated conductor and a
wall of electrical insulating composition comprising an olefinic
terpolymer and a first curing system, surrounding the conductor. A
wall of semiconducting composition directly surrounds the wall of
insulating composition. This semiconducting composition comprises
an olefinic terpolymer and a second curing system for olefinic
terpolymers differing essentially from the first curing system. The
semiconducting composition is cured by means of this second curing
system. The first curing system of my invention may advantageously
comprise an organic peroxide such as di-.alpha.-cumyl peroxide, and
the second curing system may advantageously comprise sulfur.
In a method of my invention for making an electric power cable I
continuously extrude a wall of insulating composition, comprising
an olefinic terpolymer and a first curing system over an elongated
conductor, and before curing this insulating composition I
continuously extrude a wall of semiconducting composition
comprising the olefinic terpolymer and a second different curing
system over it. Then I continuously heat the cable so as to cure
both the insulating and semiconducting compositions.
I have found that by the use of olefinic terpolymer compositions
for both the insulation and shielding jacket of my cable I can
realize the good electrical and water resistant properties of the
terpolymer for an insulation and its excellent abrasion resistance
and toughness for a jacket which combines on a shield. At the same
time the interface between the insulation and shield is
sufficiently intimate, because the surfaces are so essentially
compatible. Furthermore, there is no separation due to thermal
effects during the life of the cable. At the same time, since I
have applied different curing systems to each layer, the shielding
layer does not bond so firmly to the insulation as to create
difficulties in stripping. Particularly my present cable can have
the semiconducting jacket stripped from the insulation without, as
frequently occurred with prior art cables, tearing any of the
insulation from the outer insulation surface.
BRIEF DESCRIPTION OF THE DRAWING
FIG. 1 shows a cross-sectional view of a cable of my invention.
FIG. 2 shows a diagram of the steps of the method of my
invention.
DETAILED DESCRIPTION OF A PREFERRED EMBODIMENT
Referring to FIG. 1 the cable of my invention, indicated generally
by the numeral 10, comprises a conductor 11 which is conventional
and will usually be copper or aluminum and may comprise a plurality
of wires, stranded together in a known manner. Particularly where
the conductor is stranded it is known to surround it with a layer
12 of semiconducting strand-shielding composition which, in this
application, is considered as being included in the expression
"conductor."
Surrounding the conductor 11 I have provided a wall 13 of
insulation to a thickness determined by the voltage for which the
cable is intended. This insulating wall 13 comprises an olefinic
terpolymer such as that sold by E. I. duPont de Nemours and Company
under the trademark Nordel. Terpolymers suitable for use in the
practice of my invention are described in U.S. Pat. No. 2,933,480
and are characterized by the fact that they can be cured by a
sulfur curing system as well as being curable by peroxide. A
composition which I prefer for the wall of insulation 13 is given
in Example 1.
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EXAMPLE 1.
Parts by weight Nordel olefinic terpolymer 100 ZnO 5 polymerized
trimethyl- dihydroquinoline 1.5 fine thermal carbon black 10 **clay
filler, silicone treated 110 paraffinic oil 15 paraffin 5 ***vinyl
silane 1 red lead 5 di-.alpha.-cumyl peroxide 3.5
__________________________________________________________________________
*Age-Rite Resin D, R. I. Vanderbilt Co. Inc. **described in U.S.
Pat. No. 3,148,169 ***A-172 Silane, Union Carbide Corp.
Although I prefer the composition of Example 1, I have found that
compositions within the ranges shown in Example 2 are particularly
advantageous for the wall 13 in the practice of my invention.
EXAMPLE
2 Parts by weight Nordel olefinic terpolymer 100 ZnO 2-10
polymerized trimethyl- dihydroquinoline 0.5-3 fine thermal carbon
black 2-20 clay filler, silicone treated 50-150 paraffinic oil 5-25
paraffin 2-10 vinyl silane 0.5-3 red lead 2-10 di-.alpha.-cumyl
peroxide 2-5
Directly over the wall 13 my cable has a layer 14 of semiconducting
composition which also comprises the olefinic terpolymer of the
wall 13 or another olefinic terpolymer, as described in U.S. Pat.
No. 2,933,480. The layer 14 makes intimate, void-free contact with
the layer 13 over its entire surface and serves not only as an
electrical shielding but as a mechanical jacket to protect the
insulation from abrasion, dirt, and physical injury. My preference
for the composition of the jacket layer 14 is shown in Example 3.
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EXAMPLE 3
Parts by weight Nordel olefinic terpolymer 100 ZnO 5
*semiconducting carbon black 50 paraffinic oil (plasticizer) 10
**copper diethyldithiocar- bamate 0.75 sulfur (accelerator) 2.5
***n-oxydiethylene benzothizole-2-sulfenamide 2 (accelerator)
__________________________________________________________________________
*Vulcan XC-72, Godfrey L. Cabot, Inc. **Cumate, R. T. Vanderbilt
Co. ***NOBS special accelerator, American Cyanamide Co.
Although I prefer the composition of Example 3 for my layer 14 I
have found that compositions within the range of Example 4 are
particularly useful for the layer 14 in the practice of my
invention.
EXAMPLE 4
Parts by weight olefinic terpolymer 100 ZnO 3-15 semiconducting
black 30-100 plasticizer 5-20 sulfur 1-5 accelerators 2-9
To test the stripability of the insulation-shielding combinations
of my invention a sheet of the composition of Example 1 and a sheet
of the composition of Example 3 were pressed together during
vulcanization. The bonding force was then determined by measuring
the force required to pull apart a 1/2 -inch strip of the double
sheet. This force varied between 3 and 4 pounds. Compared to this,
a force in excess of 20 pounds has been required when the same test
has been applied to two sheets both employing the same curing
system.
The advantages of my invention are most greatly realized in a
method of manufacture of my cable where the shielding is extruded
over the insulation without intermediate curing, because the
likelihood of excessive bonding of prior art cables would be the
greatest under these circumstances. This method is shown
diagrammatically in FIG. 2. Here the conductor 11 is being
continuously paid from a source, not shown, into a dual extrusion
head 16 wherein a stock 17 of a composition of Example 2 is being
extruded to form the wall of insulation 13 and a stock 18 of a
composition of Example 4 is being extruded directly over the
insulation to form the shielding jacket 14. The cable then passes
directly into a continuous vulcanizing tube 19 wherein both the
compositions 17 and 18 are cured by the heat and pressure of steam
that is supplied through the pipe 21. This improved cable making
method and cable has particular application to cables where drain
wires are embedded in the semiconducting shield jacket, exemplified
by the disclosures of U.S. Pat. No. 3,474,189.
I have made a new and useful invention of which the foregoing
description has been exemplary rather than definitive and for which
I desire an award of Letters Patent as defined in the following
claims.
* * * * *