U.S. patent number 3,644,203 [Application Number 04/782,469] was granted by the patent office on 1972-02-22 for fabric softener.
This patent grant is currently assigned to Lever Brothers Company. Invention is credited to Vincent Lamberti, Ralph R. Sepulveda.
United States Patent |
3,644,203 |
Lamberti , et al. |
February 22, 1972 |
**Please see images for:
( Certificate of Correction ) ** |
FABRIC SOFTENER
Abstract
An improved fabric softener is disclosed comprising a mixture of
a softener such as a quaternary ammonium compound or an imidazoline
with an antiyellowing agent which is a complex of C.sub.12 to
C.sub.22 alkyl alcohol and C.sub.12 to C.sub.19 alkylsulfate.
Inventors: |
Lamberti; Vincent (Upper Saddle
River, NJ), Sepulveda; Ralph R. (Suffern, NY) |
Assignee: |
Lever Brothers Company (New
York, NY)
|
Family
ID: |
25126152 |
Appl.
No.: |
04/782,469 |
Filed: |
December 9, 1968 |
Current U.S.
Class: |
510/331; 510/496;
510/500; 510/504; 510/524; 510/515 |
Current CPC
Class: |
C11D
3/001 (20130101); C11D 3/2044 (20130101); C11D
1/62 (20130101); C11D 1/14 (20130101); D06M
13/46 (20130101); C11D 3/2013 (20130101); D06M
13/473 (20130101); D06M 13/322 (20130101) |
Current International
Class: |
C11D
1/14 (20060101); C11D 1/02 (20060101); D06M
13/473 (20060101); D06M 13/46 (20060101); D06M
13/322 (20060101); C11D 1/38 (20060101); D06M
13/00 (20060101); C11D 1/62 (20060101); C11D
3/20 (20060101); C11D 3/00 (20060101); D06m
013/38 (); C11d 001/12 (); C11d 001/86 () |
Field of
Search: |
;252/8.75,8.8,8.7,138,137,161,152 ;117/139.5CQ |
References Cited
[Referenced By]
U.S. Patent Documents
Other References
reference cited by Applicant-Goddard et al., "MOdified Detergent
Properties," Soap and Chemical Specialties, Feb. 1966..
|
Primary Examiner: Guynn; Herbert B.
Assistant Examiner: Pitlick; Harris A.
Claims
we claim:
1. A fabric softening composition having a reduced tendency to
cause yellowing, consisting essentially of a complex of (a) an
alcohol selected from the group consisting of alkanols and alkane
diols of 12 to 22 carbon atoms and an alkali metal alkyl sulfate of
12 to 18 carbon atoms in combination with (b) a cationic fabric
softener selected from the group consisting of ##SPC3##
wherein R.sub.1 and R.sub.2 are each substantially linear alkyl
groups of about 16 to 22 carbon atoms, R.sub.3 and R.sub.4 are each
alkyl groups of about one to three carbon atoms, R.sub.5 and
R.sub.6 are each substantially linear alkyl groups of about 15 to
21 carbon atoms, R.sub.7 is a divalent alkylene group of about one
to three carbon atoms, and X is an anion imparting water
dispersibility to said fabric softener; the weight ratio of said
fabric softener (b) to said complex (a) being between about 1.4:1
and 10:1, and the molar ratio of the alcohol to the alkali
metal-alkyl sulfate in the complex (a) being from between about 1:1
and 1:2.
2. A composition according to claim 1 wherein the weight ratio of
said fabric softener (b) relative to the amount of said complex (a)
is between about 2:1 and 4:1.
3. A composition according to claim 1 wherein said complex is
formed from a linear alkanol having from 12 to 22 carbon atoms and
an alkali metal alkyl sulfate having from 12 to 18 carbon atoms and
in which the alkali metal is selected from the group consisting of
sodium and potassium.
4. A composition according to claim 3 wherein said complex is
formed from octadecanol and lauryl sulfate.
5. A composition according to claim 3 wherein said complex is
formed from hexadecanediol and lauryl sulfate. ##SPC4##
Description
This invention relates to an improved fabric softener formulation
having antiyellowing properties.
It has been known for some time that the conventional cationic
fabric softeners tend to cause yellowing of fabrics treated with
them where the fabrics have been first washed using nonionic-based
detergents. The reasons for the occurrence of yellowing are not
fully understood. However, it is generally believed that yellowing
involves an interaction between the cationic fabric softener,
electronegative absorption sites on the part being treated, and
color bodies contained in the rinse water, typically attributable
to water hardness.
Yellowing may be mitigated by providing for an anionic surfactant
in combination with the cationic fabric softener. The anionic
surfactant forms a complex with the cationic fabric softener,
which, under proper conditions, may be deposited on the fabric to
be softened without causing yellowing. This approach to the control
of the discoloration caused by fabric softeners, however, is not
without difficulties. The principal disadvantage of it is that the
presence of an anionic surfactant interferes with the softening
efficiency of most cationic fabric softeners .
In accordance with the present invention it has been found that the
complex between alkyl alcohols and alkyl sulfates may be used as an
antiyellowing agent in combination with cationic fabric softeners.
On a weight basis, a mixture in which the ratio of softener to
complex is between about 1.4:1 and 10:1 is generally effective to
reduce discoloration. Preferably the ratio of softener to complex
is between 2:1 and 4:1. The use of the complex in excess of about
0.7 parts per part of softener continues to give still further
improvement in reduction of discoloration. However, these higher
levels of the complex tend to cause disproportionate losses in
fabric softening efficiency.
The complex between alkyl alcohols and alkyl sulfates has
previously been described in the art as having a ratio of alcohol
to alkyl sulfate of either 1:1 or 1:2. It is generally assigned the
formula 2ROSO.sub.3 Na.sup.. R'OH where an alkanol is employed.
Similar complexes are believed to be formed also from
alkanediols.
Alkanols suitable for use in the present invention usually contain
from 12 to 22 carbon atoms. In general, linear alcohols may be
used, whether of natural or synthetic origin, such as dodecyl
alcohol, myristyl alcohol, stearyl alcohol, and mixed alcohols such
as C.sub.16 to C.sub.18 alcohols prepared by Ziegler polymerization
of ethylene. Alkane diols such as octadecane diol may also be used
if desired.
Suitable alkyl sulfates for use in the present invention have from
about 12 to about 18 carbons atoms. Typically, the alkyl group is
linear, such as n-dodecyl, myristyl, stearyl, etc. The alkyl
sulfates may be either substantially pure or mixed. The alkyl
sulfate is used in the form of its alkali metal salt. For
commercial convenience, the sodium or potassium salts are
preferred, but other alkali metals may be substituted if
desired.
Fabric softeners with which the antiyellowing agents of the present
invention have been found effective include the quaternary ammonium
compounds of the formula
in which R.sub.1 and R.sub.2 are each long chain, substantially
linear groups from about 16 to 22 carbon atoms, R.sub.3 and R.sub.4
are each lower alkyl groups of from about one to three carbon atoms
and X is a cation imparting water dispersibility such as chloride,
bromide, iodide, sulfate, methosulfate, etc.
Another class of fabric softeners with which the antiyellowing
agent of the present invention may be used are the imidazolines of
the general formula
in which R.sub.5 and R.sub.6 are each substantially linear alkyl
groups of about 15 to 21 carbon atoms, R.sub.7 is a divalent alkyl
group of one to three carbon atoms, and R.sub.3 and X are as
defined above.
In preparing fabric softener compositions in accordance with the
present invention, the fabric softener, the alkyl alcohol and the
alkyl sulfate may be combined in any convenient order. Thus, while
the alkyl alcohol-alkyl sulfate complex may be formed prior to
combination of these ingredients with the fabric softener if
desired, it is not necessary to do so.
An important application of the present invention is in the
formulation of multifunctional detergents. Because of the
well-known cationic-anionic interaction, leading to a loss in both
detergency and fabric softening efficiency, those skilled in the
art of formulating multifunctional detergents conventionally choose
to employ a nonionic detergent and a cationic fabric softener. This
system, however, presents a most severe test of the yellowing
characteristics of cationic fabric softeners in the presence of
nonionic detergents. For this reason, antiyellowing agents will be
particularly useful in the formulation of multifunctional
detergents based upon nonionic detergent actives and cationic
fabric softeners.
Typical multifunctional detergents employing the present invention
will have the following composition:
% by weight
__________________________________________________________________________
Nonionic detergent active 5% to 25% Builder 5% to 60% Fabric
softener 1% to 10% Alkyl sulfate 0.05% to 6% Alkyl alcohol 0.02% to
3%
__________________________________________________________________________
Preferred compositions generally are formulated with the
proportions:
Preferred % by weight
__________________________________________________________________________
Nonionic detergent active 10% to 20% Builder 25% to 50% Fabric
Softener 2% to 6% Alkyl sulfate 0.2% to 4% Alkyl alcohol 0.1% to 2%
__________________________________________________________________________
The nonionic detergent active contemplated is a conventional kind.
Typically these are condensates of hydrophobic compounds having a
reactive hydrogen with ethylene oxide, the amount of ethylene oxide
in the condensate being sufficient to impart surface-active
properties to it. Typical nonionic detergents which may be used
include the ethylene oxide-polypropylene oxide block polymers
commercially available as the so-called "Pluronic" series; ethylene
oxide condensates of alkyl alcohols having from eight to 20 carbon
atoms in the alkyl group and containing up to 80 percent ethylene
oxide; ethylene oxide condensates of the fatty acids such as
ethoxylated tall oil fatty acids, etc.; ethylene oxide condensates
of the fatty amines; and many others. This class of detergents is
well known to those skilled in the art.
As builders, the conventional alkaline builders may be employed
such as the alkali metal phosphates, pyrophosphates,
tripolyphosphates, hexametaphosphates, etc., as well as other
alkali metal compounds such as alkali metal carbonates, etc.
Organic builders are also known such as nitrilotriacetic acid. The
amount of builder will be in the amounts conventionally employed.
Normally, when builders are used in a detergent system, the amount
used is in the order of 25 to 50 percent of the complete
formulation.
The fabric softening actives, alkyl alcohols, and alkyl sulfates
for use in the foregoing composition have already been described
above.
While not specifically mentioned in the foregoing skeleton
formulation, it will be obvious to those skilled in the art that
many other materials may be included. Adjuvants may be provided
such as suds boosters, such as fatty acid amides; soil suspending
agents, such as carboxymethyl cellulose, hydroxyethyl cellulose;
anticorrosion agents, such as sodium silicate; as well as optical
brighteners, colorants, perfumes, fillers, germicides, enzymes
etc.
Another important application of the present invention is in the
formulation of rinse cycle fabric softeners. Because of carryover
from the wash cycle to the rinse cycle, yellowing has been a
persistent problem when detergent formulations are employed in the
wash. The use of a mixture of a cationic fabric softener and a
complex in accordance with the present invention mitigates this
problem.
For a better understanding of the present invention, reference may
be had to the following examples:
EXAMPLE 1
Antiyellowing agents in accordance with the present invention were
tested in a multifunctional detergent composition composed of a
conventionally built nonionic detergent employing and containing
sodium tripolyphosphate builder, distearyldimethyl ammonium
chloride as a fabric softener, sodium lauryl sulfate and various
alkyl alcohols. Five 4.times.6 inch terry cloth swatches were
treated in a Terg-O-Tometer pot for 15 minutes with 1,000 ml. of 90
p.p.m. hard water artificially hardened with calcium and magnesium
in a 2:1 ratio and additionally containing 4 p.p.m. of
Fe.sup.+.sup.3. The washing temperature was 120.degree. F. 1.94
grams of built nonionic detergent composition and 0.1 grams of
distearyl dimethyl ammonium chloride were added. The amounts of
sodium lauryl sulfate and alkyl alcohol were varied as set forth
below.
In each test conducted, improvements in softness and yellowing were
measured relative to the softness and yellowness observed on
swatches washed in nonionic detergent only. By recording the
differences in softness (.DELTA.S) and yellowing (.DELTA.b), more
meaningful comparisons may be made between successive experiments.
In the data reproduced below, an increase in the value of .DELTA.S
indicates an improved softness in the final product relative to the
softness of the control. An increase in the value of .DELTA.b
indicates a deterioration in whiteness or an increase in yellowness
of the washed swatches. ##SPC1##
EXAMPLE 2
The test described in Example 1 was repeated substituting the
fabric softener 1-methyl-1-alkylamido-ethyl-2-alkylimidazolinium
methosulfate as the fabric softener for distearyldimethyl ammonium
chloride previously described. The following results were obtained:
##SPC2##
In like manner a series of complexes were prepared from alkyl
sulfates having from 12 to 18 carbon atoms and alkyl alcohols
having from 12 to 22 carbon atoms and tested as antiyellowing
additives.
Complexes found to be effective were the following:
Alkyl Sulfate, ROSO.sub.3 Na Alkyl Alcohol, R'OH R R'
__________________________________________________________________________
nC.sub.12 H.sub.25 nC.sub.12 H.sub.25 nC.sub.14 H.sub.29 nC.sub.16
H.sub.33 mixed nC.sub.16 -C.sub.18 fatty alcohol nC.sub.18 H.sub.37
nC.sub.20 H.sub.41 nC.sub.22 H.sub.45 nC.sub.14 H.sub.29 nC.sub.12
H.sub.25 nC.sub.14 H.sub.29 nC.sub.16 H.sub.33 nC.sub.18 H.sub.37
nC.sub.16 H.sub.33 nC.sub.12 H.sub.25 nC.sub.14 H.sub.29 nC.sub.16
H.sub.33 nC.sub.18 H.sub.37 nC.sub.18 H.sub.37 nC.sub.18 H.sub.37
__________________________________________________________________________
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