U.S. patent number 3,639,154 [Application Number 04/840,499] was granted by the patent office on 1972-02-01 for process for manufacturing fibrous structure having excellent recovery from extension by treatment with polyorganosiloxane and a polyethylene glycol or derivative thereof.
This patent grant is currently assigned to Kanegafucki Boseki Kabushiki Kaisha. Invention is credited to Takashi Itoh, Minoru Kojima, Yoshio Sawa, Mikio Sotomura.
United States Patent |
3,639,154 |
Sawa , et al. |
February 1, 1972 |
PROCESS FOR MANUFACTURING FIBROUS STRUCTURE HAVING EXCELLENT
RECOVERY FROM EXTENSION BY TREATMENT WITH POLYORGANOSILOXANE AND A
POLYETHYLENE GLYCOL OR DERIVATIVE THEREOF
Abstract
This invention is directed to fibrous structures such as crimped
yarns and fabrics made therefrom having excellent extensibleness,
recovery from extension and no water repellency. The process of the
invention comprises applying to said structures an aqueous emulsion
of polyorganosiloxane comprising essentially methyl hydrogen
polysiloxane having specified viscosity and subsidiarily dimethyl
polysiloxane if required, polyethylene glycol or a derivative
thereof and a catalyst for polymerization of polysiloxane and
curing preferably in a dry condition. Important fibrous structures
are composed of composite fibers or of conventional mechanically
crimped fibers. Crimp developing for the former or heat setting of
the latter can be advantageously effected simultaneously with the
aforementioned curing.
Inventors: |
Sawa; Yoshio (Kobe City,
JA), Itoh; Takashi (Toyonaka City, JA),
Kojima; Minoru (Osaka City, JA), Sotomura; Mikio
(Settsu City, JA) |
Assignee: |
Kanegafucki Boseki Kabushiki
Kaisha (Tokyo, JA)
|
Family
ID: |
27462610 |
Appl.
No.: |
04/840,499 |
Filed: |
July 9, 1969 |
Foreign Application Priority Data
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|
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Jul 20, 1968 [JA] |
|
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43/51267 |
Jul 20, 1968 [JA] |
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43/51268 |
Jul 20, 1968 [JA] |
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43/51269 |
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Current U.S.
Class: |
442/102; 28/166;
428/369; 442/105; 427/387; 428/395; 428/447 |
Current CPC
Class: |
D06M
15/643 (20130101); Y10T 442/2352 (20150401); Y10T
428/31663 (20150401); Y10T 428/2969 (20150115); Y10T
428/2922 (20150115); Y10T 442/2377 (20150401) |
Current International
Class: |
D06M
15/643 (20060101); D06M 15/37 (20060101); D06m
015/66 () |
Field of
Search: |
;117/161ZA,139.5A,138.8A
;161/175 ;28/74 |
References Cited
[Referenced By]
U.S. Patent Documents
Primary Examiner: Martin; William D.
Assistant Examiner: Husack; Ralph
Claims
What is claimed is:
1. A process for manufacturing a fibrous structure having an
excellent recovery from extension and reduced water repellency and
waxy hand which comprises applying homogeneously to a fibrous
structure an aqueous emulsion of 0.1 to 2.0 percent by weight based
on the emulsion of polyorganosiloxane comprising methyl hydrogen
polysiloxane having a viscosity at 25.degree. C. of 10-40
centistokes and polyethylene glycol or a derivative thereof having
an average molecular weight of 350-6,000, of the formula,
RO-(CH.sub.2 CH.sub.2 O).sub.n -R'
wherein R and R' are the same or different, and may each be an
hydrogen atom, an alkyl group having 1-20 carbon atoms or an
alkylphenyl group having at least one alkyl group of 1-20 carbon
atoms, with the proviso that at least one of said R and R' is a
hydrogen atom, and Mn has a value sufficient to give the said
molecular weight M, the weight ratio of said polyorganosiloxane to
said polyethylene glycol or derivative thereof being in a range of
9:1 to 1:2, and a catalyst for polymerization of said
polyorganosiloxane and thereafter subjecting the fibrous structure
to a curing treatment.
2. A process as claimed in claim 1, wherein the polyorganosiloxane
consists substantially of said methyl hydrogen polysiloxane.
3. A process as claimed in claim 1, wherein the polyorganosiloxane
consists of at least 5 percent by weight of said methyl hydrogen
polysiloxane and at most 95 percent by weight of dimethyl
polysiloxane having a viscosity at 25.degree. C. of 100-50,000
centistokes.
4. A process as claimed in claim 1, wherein the amount of
polyorganosiloxane applied and fixed to the fibrous structure is
0.05-10 percent by weight, based on said structure and the amount
of said polyethylene glycol or its derivative applied to the
fibrous structure is 0.05-5 percent by weight based on said
structure.
5. A process as claimed in claim 1, wherein the amount of
polyorganosiloxane applied and fixed to the fibrous structure is
0.2-5 percent by weight based on said structure and the amount of
said polyethylene glycol or its derivative applied to the fibrous
structure is 0.1-2 percent by weight based on said structure.
6. A process as claimed in claim 1, wherein said catalyst is at
least one organic metal compound selected from the group consisting
of: salts of a metal selected from the class consisting of tin,
zinc, lead and zirconium with an organic acid selected from the
class consisting of naphthenic acid, octylic acid and isooctylic
acid; dibutyl tin acetate; dibutyl tin laurate; and butyl
titanate.
7. A process as claimed in claim 6, wherein said catalyst is
contained in the aqueous emulsion in an amount of 0.01-5.0 percent
by weight based on the polyorganosiloxane.
8. A process as claimed in claim 1, wherein the fibrous structure
that said aqueous emulsion has been applied to is subjected to a
preliminary drying at a temperature between a room temperature and
60.degree. C. prior to the curing treatment.
9. A process as claimed in claim 1, wherein the curing treatment is
conducted at a temperature of 80.degree.-200.degree. C. for 10
seconds to 10 minutes.
10. A process as claimed in claim 1, wherein the curing treatment
is conducted at 120.degree.-170.degree. C. for 0.5-2 minutes.
11. A process as claimed in claim 1, wherein the curing treatment
is conducted for a period of time which satisfies the formula,
where, D is the total denier of fiber in denier, T is the curing
temperature in .degree.C. and t is the period of time for curing in
seconds.
12. A process as claimed in claim 1, wherein said emulsion further
contains at least one organic silane compound as a cross-linking
agent selected from the class consisting of isocyanates of silane
compounds, alkoxysilanes and acetates of silane compounds.
13. A process as claimed in claim 1, wherein said fibrous structure
has substantially no water repellency or waxy hand and wherein said
polyorganosiloxane and said polyethylene glycol or derivative
thereof are applied to the fibrous structure in a proportion by
weight of 3:1-1:1.
14. A process as claimed in claim 1, wherein the fibrous structure
comprises filaments of at least one fiber-forming thermoplastic
synthetic condensation polymer selected from the class consisting
of linear polyamides, linear polyesters and linear polyester
ethers.
15. A process as claimed in claim 1, wherein the fibrous structure,
before the application of said emulsion, has an extensibleness of
at least 5 percent.
16. A process as claimed in claim 15, wherein the fibrous structure
is a filament yarn.
17. A fibrous structure having excellent recovery from extension
and reduced water repellency and waxy hand prepared in accordance
with the process of claim 1.
Description
This invention relates to a process for manufacturing fibrous
structures, such as crimped yarns, knitted and woven fabrics
composed thereof and the like, which are provided with an excellent
recovery from extension, and more particularly to a method for
improving the hand and tensile elasticity of fibrous structures as
such by an application of polyorganosiloxane thereto followed by a
heat treatment.
By the term "fibrous structure" used in this specification and
claims is meant a structure composed of staple fibers, continuous
filaments or a mixture thereof, such as a yarn, strand, net,
knitted goods, woven fabrics, nonwoven fabrics, felt, filter cloth,
substrate for synthetic leather, garment and the like. The most
important fibrous structures in the present invention are crimped
yarns and knitted and woven fabrics composed thereof.
For manufacturing stretchable fibrous structures, there are various
well-known expedients, for instance, employment of polyamide or
polyester-textured crimped yarn as materials for fibrous
structures, utilization of elastic yarn such as rubber and
polyurethane elastomer yarns, and postfinish of knitted or woven
fabrics. However, polyamide or polyester yarn employed as material
for fibrous structures does not have satisfactory tensile recovery,
i.e., recovering force from extension, so that fibrous structures
made therefrom according to conventional process have not always
been provided with satisfactory tensile recovery. Particularly,
polyester fibers prevailing in the market such as polyethylene
terephthalate fibers are quite inferior in tensile recovery and
accordingly, in the past, highly stretchable knitted or woven
fabrics composed of polyester fibers have scarcely been
produced.
Furthermore, there have so far been proposed numerous composite
filaments wherein at least two adherent components of synthetic
fiber forming polymer differing in heat shrinkability are disposed
in an eccentric relation with each other along the entire length of
the filament, which can be manufactured by separately melting said
polymers and by extruding the melt simultaneously from the same
spinneret orifice to form a unitary filament. A principal object
for manufacturing such composite filaments is to produce a crimped
yarn having a woollike bulkiness, covering power and elastic or
tensile recovery. It can not always be said, however, that
composite filaments produced by a conventional process possess
satisfactory woollike properties. Namely, most of conventional
crimped composite filaments have some disadvantages which have to
be obviated, particularly such that they are not provided with a
woollike crimp recovering ability, whereas wools have an excellent
crimp recovering ability, so that their crimps can readily return
to their original configuration, even after suffering remarkably
large compressive, tensile or bending stress.
For instance, although a composite filament obtained by
melt-spinning concurrently from the same orifice, polyethylene
terephthalate and a copolymer of 90 mole percent of polyethylene
terephthalate with 10 mole percent of polyethylene
hexahydroisophthalate is excellent with respect to crimpability,
and can develop extremely superior crimps. However its crimps are
so inferior in the ability to recover from extension that the
crimps hardly return to their original form after the removal of a
load 1 gram per denier which has been applied on the filament for 2
minutes.
On the other hand, the postfinish often impairs the original
preferable hand of fibrous structures. It has heretofore been known
that a highly stretchable fibrous structure can be obtained by
applying polyorganosiloxane to the fibrous structure such as of
natural fibers and of synthetic fibers and then subjecting it to a
heat treatment. Such a conventional process as mentioned above
usually provides the fibrous structure with extensibleness as well
as water repellency, together with a waxy hand. Accordingly, it is
effective to improve the stretchability of a special fibrous
structure which requires water repellency and waxy hand, but it is
not appropriate for manufacturing a highly stretchable and elastic
fibrous structure which does not require the aforementioned
properties. Namely, for manufacturing an article that requires
water repellency or water-proofing ability, such as a raincoat,
practical use has so far been made of a process which comprises
applying to a knitted or woven fabric a methyl hydrogen
polysiloxane or a mixture of methyl hydrogen polysiloxane with
dimethyl polysiloxane, together with a catalyst for polymerization
of the polysiloxanes, and then subjecting the resultant fabric to a
dry heat treatment. Yet it cannot be denied that the conventional
process as mentioned above essentially provides a fibrous structure
with water repellency, while it impairs the original hand of the
structure.
We, the inventors, have made various studies and investigations, to
overcome the above-mentioned difficulties, on the finishing of
fibrous structures, particularly such as knitted or woven fabrics,
to impart an excellent stretchability thereto and at last
accomplished the present invention.
It is an object of the present invention to obtain fibrous
structures, particularly knitted or woven fabrics provided with
excellent stretchability and preferable hand, which have neither
water repellency nor waxy hand.
Another object of the present invention is to provide a useful
crimped yarn by imparting more excellent crimp-recovering ability
to a crimped composite filament.
Still another object of the present invention is to manufacture
knitted or woven fabrics having extremely high stretchability with
the aforementioned crimped yarn.
Other objects and attending advantages will become apparent from
the following description of the invention.
The present invention is characterized in that an aqueous emulsion
of polyorganosiloxane comprising methyl hydrogen polysiloxane
having a viscosity at 25.degree. C. of 10-40 centistokes is
homogeneously applied to a fibrous structure together with a
catalyst for polymerization of said polyorganosiloxane and
thereafter the fibrous structure is subjected to a curing
treatment.
As a polyorganosiloxane to be applied to the present invention, the
most suitable is that consisting substantially of methyl hydrogen
polysiloxane having a viscosity at 25.degree. C. of 10-40
centistokes or a blend of the methyl hydrogen polysiloxane and
dimethyl polysiloxane having a viscosity at 25.degree. C. of
100-50,000 centistokes. It is preferable that the blended
polyorganosiloxane which is most suitably applied to the present
invention contains at least 5 percent by weight of methyl hydrogen
polysiloxane and as long as the blend contains such an amount of
methyl hydrogen polysiloxane, the blending ratio of methyl hydrogen
polysiloxane, and dimethyl polysiloxane may be arbitrarily
determined.
If the viscosity of polysiloxanes is lower than the lower limits of
the above-mentioned preferable ranges, silicone film having
sufficient stability, adhesivity and elasticity is difficult to
form on the fibrous structures upon a heat treatment in a dry
state, due to the low degree of polymerization thereof, while on
the contrary, if the viscosity of polysiloxanes is higher than the
upper limits of the above-mentioned preferable ranges, elastic
silicone film having an excellent stability and adhesivity is
difficult to form as well and moreover, even when the amount of
polysiloxane applied is rather small, a sticking phenomenon may be
brought about on fibrous structures, and thus in either case,
fibrous structures comprising crimped fibers provided with a
satisfactory crimp recovery from extension cannot be obtained.
The aqueous emulsion of polyorganosiloxane to be employed in the
process of the present invention is prepared by the addition of an
ordinary surface-active agent, for instance, a nonionic
surface-active agent such as polyethylene lauryl ether and
polyoxyethylene octyl phenol ether, or a cationic surface active
agent such as lauryl amine acetate and the like to the polysiloxane
in an amount of 1-10 percent by weight based on the polysiloxane
and the resultant polysiloxane is emulsified to form a homogeneous
dispersion in water. The concentration of polyorganosiloxane in the
aqueous emulsion usually lies in the range of 0.1-2.0 percent by
weight, but it may be higher than the above under certain
circumstances.
Application of the mixture of polyorganosiloxane and catalyst for
its polymerization onto fibrous structures can be performed in
various manners, such as an application roller means by which the
emulsion is applied to running yarn before it is wound on a bobbin
or a pirn in a spinning or drawing process; soaking of yarn on a
bobbin having many perforations thereon or on a skein in the
aqueous emulsion, followed by removal of excess liquid on the yarn;
and soaking fabric such as knitted fabrics, woven fabrics and the
like in the aqueous emulsion in an ordinary way, followed by
squeezing by means of a roller mangle or by another appropriate
means to remove excess liquid. As far as the predetermined amount
of the polyorganosiloxane or of the polyorganosiloxane together
with the catalyst which can be incorporated to the fibrous
structure, the method of application is not specifically
limited.
In the process of the present invention, the amount of the
polyorganosiloxane fixed on the fibrous structure is preferably in
the range of 0.05-10 percent by weight based on the fibrous
structure and more preferably in the range of 0.2-5 percent by
weight. If the above-mentioned fixing amount is less than 0.05
percent by weight, an elastic silicone film having excellent
durability and adhesivity is difficult to form on fibrous
structures because the amount of polyorganisiloxane is too small,
while if the fixing amount is in excess of 10 percent by weight,
not only is the formed film insufficient with respect to stability
and adhesivity like the above, but also too much polyorganosiloxane
fixed on the structure may cause sticking between fibers in the
fibrous structure, and thus in either case, fibrous structures
provided with a high recovery from extension cannot be obtained.
When the amount of polyorganosiloxane fixed upon the fibrous
structure is in the above-mentioned preferable range, an elastic
silicone film of three dimensional structure which possesses an
extremely high durability and an excellent adhesivity to fibers can
be formed on fibers, so that fibrous structures having a superior
recovery from extension can be obtained.
The amount of polyorganosiloxane fixed upon fibers can be
determined, for instance, by the under-mentioned method.
A predetermined amount of fibrous structures on which
polyorganosiloxane has been fixed is taken as a specimen, and dried
at 60.degree. C. under a reduced pressure for 5 hours and then
weighed to determine its weight (a) grams. Further, another
predetermined amount of fibrous structure having no
polyorganosiloxane fixed thereupon is taken, dried under the same
conditions as above and weighed to determine its weight (b) grams.
Then, from the respective specimens as mentioned above the
polyorganosiloxane is extracted with benzene as a solvent in a
Soxhlet fat-extraction apparatus for 8 hours and thereafter the
specimens are dried at 60.degree. C. under a reduced pressure for 5
hours and weighed to determine their respective weights (c) grams
and (d) grams. The amount of polyorganosiloxane fixed upon fibers
is determined by the following equation:
The amount of polyorganosiloxane fixed (percent by weight)
An aqueous emulsion of polyorganosiloxane to be employed in the
practice of the present invention should contain a catalyst for
polymerization of the polyorganosiloxane in order to facilitate the
formation of elastic silicon films having a satisfactory durability
and a sufficient adhesivity to fibrous materials, which films are
to be formed by a cross-linking reaction of the polyorganosiloxane
adhered to fibers in the fibrous structure, and further to provide
the fibrous structure with an excellent elastic recovery from
extension. As substances having such catalytic abilities, mention
may be made of organic metal compounds, for instance, a metal salt
such as: a naphthenic acid salt, octylic acid salt and isooctylic
acid salt, of a metal such as tin, zinc, lead and zirconium;
dibutyl tin acetate; dibutyl tin laurate; butyl titanate or the
like. These catalysts may be used either individually or in
combinations of more than one.
The amount of the above-mentioned catalyst to be admixed with
polyorganosiloxane is suitably selected according to the kind of
the catalyst as well as of the polyorganosiloxane, concentration of
the polyorganosiloxane in the aqueous emulsion, treating
conditions, etc., and for the good result of the invention,
0.01-5.0 percent by weight of the catalyst based on the
polyorganosiloxane component may be usually employed.
Fibrous structures to which a polyorganosiloxane and a catalyst
have been applied are preliminarily dried at a temperature between
room temperature and about 60.degree. C. and thereafter subjected
to a heat treatment, preferably in a dry state, at
80.degree.-200.degree. C. for 10 seconds to 10 minutes, preferably
at 120.degree.-170.degree. C. for 30 seconds to 2 minutes, under a
tensioned or a relaxed condition. By the preliminary drying
treatment, solvent, i.e., water in the polyorganosiloxane aqueous
emulsion is evaporated and expelled and which treatment, however,
may be omitted as the case may be. By the above-mentioned heat
treatment, a polymerization reaction of the polyorganosiloxane is
performed, so that highly elastic silicone films having a
durability and a sufficient adhesivity to fibers are formed on the
fibers in the fibrous structure. Thus, a fibrous structure provided
with an excellent tensile elasticity is readily obtainable
substantially without deteriorating either its conformation or its
hand that the fibrous structure has originally been provided
with.
Moreover in the process of the present invention, in addition to
the above-mentioned catalyst, at least one organic silane compound,
such as an isocyanate of silane compound, an alkoxysilane, an
acetate of silane compound, etc., may be further added to the
emulsion as an accelerator of the cross-linking reaction, for the
purpose of improving adhesivity of the polyorganosiloxane to fibers
in the fibrous structure. If such an accelerator of the
cross-linking reaction is employed, it is possible to improve
remarkably the adhesivity to fibers constituting fibrous
structures, of elastic silicone films having a three dimensional
molecular structure which has been formed by the cross-linking
reaction of the polyorganosiloxane, and to provide the resultant
fibrous structure with an everlasting and excellent tensile
elasticity.
Furthermore, as the most preferable embodiment of the process of
the present invention, we, the inventors have disclosed a method
comprising incorporating a polyethylene glycol or its derivative
having its molecular weight of 350-6,000 to the aforementioned
aqueous emulsion of polyorganosiloxane together with a catalyst for
polymerization of the polyorganosiloxane. Namely, such a method is
carried out by treating fibrous structures with an aqueous emulsion
of polyorganosiloxane which has been incorporated with a
predetermined amount of the polyethylene glycol or its derivative.
Differing from a conventional simple treatment with
polyorganosiloxane that aims at a waterproof finish, the
above-mentioned method is appreciably effective in obtaining a
fibrous structure of an improved quality that has been provided
with a highly increased tensile elasticity without imparting
thereto water repellency and waxy hand as inherent to the
conventional polyorganosiloxane finish. In the practice of the
method mentioned above, a suitable amount of polyorganosiloxane to
be applied to fibrous structures is 0.05-10 percent by weight and
preferably 0.2-5 percent by weight, and a relevant amount of
polyethylene glycol or its derivative is also 0.05-5 percent by
weight and preferably 0.1-2 percent by weight. The proportion of
polyorganosiloxane to polyethylene glycol or its derivative to be
applied to fibrous the structure is preferably 9:1-1:2 and more
preferably 3:1-1:1, and still however it is changeable arbitrarily
in accordance with the stretchability, water repellency, waxy hand,
etc., desired. If the proportion of polyorganosiloxane to
polyethylene glycol or its derivative is more than 9:1, that is,
too much polyorganosiloxane is employed compared with polyethylene
glycol or its derivative, undesirable water repellency and waxy
hand of the fibrous structure increase, though its stretchability
can be improved. On the contrary, if said proportion is less than
1:2, namely, too much polyethylene glycol or its derivative is used
as compared with polyorganosiloxane, a fibrous structure provided
with satisfactory stretchability as well as recoverability is
difficult to obtain.
Polyethylene glycols and derivatives thereof are represented by the
following general formula:
RO--(CH.sub.2 CH.sub.2 0).sub.n --R'
where, R and R' are respectively a hydrogen atom, an alkyl group
having its 1-20 carbon atoms or an alkyl-phenyl group having at
least one alkyl group of 1-20 carbon atoms, and at least one of the
terminal groups thereof is a hydroxy group. n has a value such that
the molecular weight of such polyethylene glycol or its derivative
is preferably in the range of 350-6,000. If polyethylene glycol or
its derivative having a molecular weight of less than 350 is
employed, it is difficult to attain the aforesaid objects of the
present invention, since the treated fibrous structure is not
satisfactory in its stretchability, though it does not exhibit waxy
hand and water repellency. On the other hand, if the molecular
weight is in excess of 6,000, although the stretchability of the
structure may be improved to a great extent, it is not preferable,
because not only is it difficult to decrease the waxy hand and
water repellency to a satisfactory degree, but also a rather stiff
and harsh hand is imparted to the fibrous structure.
As fiber materials which constitute fibrous structures to be
applied to the present invention, mention may be made of natural
fibers such as wool, silk, cotton, hemp and the like; regenerated
cellulosic fibers such as viscose rayon, cupra, cellulose acetate,
cellulose triacetate and the like; synthetic fibers such as
polyamides, polyesters, polyester ethers, polyurethanes, polyureas,
polyacrylonitrile, polyvinyl alcohol, polyvinyl chloride,
polyvinylidene chloride, polyolefins and the like; and their
blends. Those fiber materials may be in the form of staple,
filament, spun yarn or their mixture and further crimpable or
crimped composite filament, textured yarn and the like are
effectively usable. Particularly, filaments consisting of a
fiber-forming synthetic condensation polymer, specifically, of a
linear polyamide and of a linear polyester, and knitted and woven
fabric therefrom lead to a good result of the present
invention.
The term hereinafter referred to as "polyesteric fibers" implies
fibers consisting essentially of either polyester or polyester
ether.
The above-said polyester means polyethylene terephthalate, a
modified polyesters manufactured by copolymerizing or polymer
blending a predominant component of polyethylene terephthalate and
a subsidiary component different therefrom.
The modified polyesters include, for instance, a copolymer of
components of polyethylene terephthalate with a small amount of at
least one of: an aliphatic dicarboxylic acid such as adipic acid,
sebacic acid, 1, 10-decane dicarboxylic acid and the like; an
aromatic dicarboxylic acid such as isophthalic acid, sodium
sulfoisophthalic acid, naphthalene dicarboxylic acid and the like;
an alicyclic dicarboxylic acid such as hexahydro terephthalic acid
and the like; an aliphatic diol such as trimethylene glycol,
tetramethylene glycol, diethylene glycol, polyethylene glycol and
the like; and an alicyclic diol such as 1, 4-cyclohexane
dimethanol, 1,4 -cyclohexane diol and the like. Among the above,
the modified polyesters also include a polymer blend of
polyethylene terephthalate and a small amount of polymer or
copolymer manufactured from a combination of dicarboxylic component
and diol component selected from those listed above, and further
include polyethylene terephthalate blended with a small amount of
polyalkylene ether.
The aforementioned polyester ether means poly ethylene
paraoxybenzoate or a modified polyester ether manufactured by
copolymerizing a predominant component of polyethylene
paraoxybenzoate with at least one subsidiary component selected
from the group listed in the foregoing paragraph, or by polymer
blending a predominant amount of polyethylene paraoxybenzoate and a
small amount of polymer of copolymer same as mentioned in the
illustration of polymer blend of polyethylene terephthalate in the
foregoing paragraph.
The polyamide to be applied to the process of the present invention
is a fiber-forming linear polymer or copolymer manufactured by
polymerizing at least one polyamide-forming material selected from
the group consisting of cyclic lactams such as
.epsilon.-caprolactam, enantholactam, laurylolactam and the like,
and nylon salts formed from a diamine such as tetramethylene
diamine, hexamethylene diamine, nonamethylene diamine,
undecamethylene diamine, metaxylylene diamine, paraxylylene
diamine, N,N'-bis(.gamma.-aminopropyl) piperazine,
.gamma.,.gamma.'-aminopropyl ether and the like and a dicarboxylic
acid such as adipic acid, sebacic acid, terephthalic acid,
isophthalic acid, hexahydroterephthalic acid and the like.
It is desirable that a fibrous structure to be applied to the
process of this invention possess an extensibleness of at least 5
percent, because treatment of fibrous structures with
polyorganosiloxane cannot newly impart extensibility and
recoverability from extension to the fibrous structure which has
originally had neither extensibility nor recoverability from
extension, but does improve elastic properties such as
extensibility and recoverability which has been originally
possessed by the fibrous structure. Namely, if the extensibleness
of a fibrous structure is lower than 5 percent, it may be very
difficult to improve substantially its extensibleness and
recoverability from extension by the polyorganosiloxane
treatment.
From the reason as stated above, it is preferable for a fibrous
structure which is to be subjected to the polyorganosiloxane
treatment according to the present invention to have a
extensibleness of at least 5 percent at least in the direction
towards which imparting of a high tensile elasticity has been
contemplated. In case the extensibleness of a fibrous structure
such as knitted and woven fabrics to be treated is lower than 5
percent, it is hard to provide the structure with an excellent
tensile elasticity.
In the present invention, for instance, "a knitted or woven fabric
having its extensibleness of 5 percent" is defined as follows:
A rectangular test piece having a width of 5 cm. and a length of 10
cm. is cut out of a knitted or woven fabric. The both lengthwise
ends of the test piece are clasped by clamps so that the distance
between clamps may be 8 cm. and the extended length of the test
piece between the clamps, when a load of 2 kg. has been applied to
one end thereof, is measured. If the percentage of the difference
between the extended length and the original length (8 cm.) against
the original length be 5, then such a fabric is defined to have an
extensibleness of 5 percent.
A fibrous structure to be applied to the present invention may be
composed of crimped fibers which have been processed in a
conventional mechanical crimping process such as a false-twisting
process, stuffing box process and the like. In case fibers or yarns
are subjected to a process according to the present invention in
advance, whereupon they are cured simultaneously with the
mechanical crimping, then the fibers or yarns can be given
concurrently a high tensile elasticity and crimps. A process for
treating a textured crimped yarn as such will be illustrated
hereinafter in detail.
Polyester fibers or polyamide fibers to which polyorganosiloxane
has been applied may be subjected to a preliminary drying which is
followed by a heat treatment in a dry state at 80.degree. -
200.degree. C. under a tensioned or relaxed condition as explained
hereinbefore, and thereafter crimped by a conventional mechanical
crimping process such as false-twisting and stuffing box. Further
those fibers which have been through the preliminary drying step
may be subjected directly to the crimping process without
performing the independent step of curing. Still further, omitting
the preliminary drying step, the crimping process may succeed the
heat treatment. In either way, there can be obtained crimped fibers
having a high tensile elasticity and having desirable
characteristics inherent to the original fibers, bulkiness,
workability, etc., which have not at all been impaired.
Especially, when fibers are subjected to a crimping process
comprising steps of mechanical deforming and of heat setting,
immediately after a drying process, without performing the
independent step of heating, it is extremely advantageous from an
industrial viewpoint that the three dimensional cross-linking
reaction of polyorganosiloxane and the heat setting of fibers are
simultaneously effected.
It has been ascertained by the inventors' experimental works that
the most preferable period of time (t seconds) for keeping the
fibers in the heater during the heat setting process satisfies the
following inequality:
where, D is total denier of the fiber and T(.degree.C) is the
temperature of the heater.
If the above condition is not satisfied, the reaction of
polyorganosiloxane is insufficiently performed, and therefore
elastic silicone films having a durability and an excellent
adhesivity are difficult to form on fibers, so that the
stretchability and recovery from elongation of the resultant the
fibers are not entirely satisfactory.
Another important embodiment of fibrous structures to be suitably
applied to the present invention is that composed of composite
filaments having latent crimps which are manufactured by melting
separately two fiber-forming thermoplastic polymers differing in
heat shrinkability and by extruding the two melts simultaneously
from the same spinneret orifice to form a unitary filament wherein
said two polymers are disposed in an eccentric relation with each
other extending throughout the entire length of the filament, which
fibrous structure is a yarn or a knitted or woven fabric composed
thereof that exhibits an extensibleness of at least 5 percent in
the direction to which extension has been originally required.
Composite filaments which have been through a dry heat treatment in
a tensioned or restrained condition develop excellent crimps by
further subjection to a conventional crimp-developing treatment in
a relaxed condition providing crimped filaments which have
excellent extensibility and recoverability of crimps. Moreover, in
case the dry heat treatment is conducted in a relaxed condition,
the crimp frequency of the resultant crimped filaments varies
according to the kind of conjugated components forming the
composite filaments, temperature of the curing treatment and degree
of relaxation of the filament during the curing treatment.
Accordingly, if the curing treatment is conducted in a relaxed
condition as above, the three-dimensional cross-linking reaction of
polyorganosiloxane and crimp development are simultaneously
effected, which is extremely advantageous from an industrial
viewpoint.
A knitted or woven fabric having an excellent stretchability which
is one of the objects of the present invention is obtainable by
knitting or weaving into fabric a composite filament yarn on which
polyorganosiloxane has been applied solely or together with a
catalyst for the polymerization thereof and thereafter a curing
treatment has been effected, or in addition to those steps, a
crimp-developing treatment has been further performed, and then by
crimp developing or shrinking the resultant fabric in hot or
boiling water.
A knitted or woven fabric comprising composite filaments to be
applied to the precess of this invention is either a fabric that
has developed its crimps by a heat treatment after fabrication from
the composite filaments, or that has developed its crimps after
fabrication from the composite filaments which have been through a
preliminary crimping process prior to the fabrication. Individual
fibers which constitute such a structure retain their respective
crimps in the structure or adjacent fibers are not in close contact
with each others, so that they may be movable in the structure and,
therefore, when a tensile stress acts upon the structure,
individual fibers can move freely according as the tensile
stress.
Polymers to be conjugated, manner of conjugation and proportion of
polymers to be conjugated for a crimpable composite filament to be
applied to the process of this invention are appropriately selected
in consideration of the adhesivity of two polymers employed,
crimpability required for the composite filament to possess and so
forth.
Various composite filaments are obtainable in combinations of the
aforementioned numerous polymers and preferable combinations of
polymers which provide composite filament having an excellent
crimpability are those of polyamides with polyesters or polyester
ethers, those of homopolyamides with copolyamides or modified
polyamides, those of polyethylene terephthalate with copolyesters
or modified polyesters, those of polyethylene terephthalate with
polyethylene oxybenzoate, copolyester ethers or modified polyester
ethers and those of two polyethylene terephthalates differing in
their degree of polymerization.
Thus, according to the process of the present invention,
polyorganosiloxane applied to composite filaments forms, upon a
curing treatment, elastic films having excellent durability and
adhesivity to fibers and a three-dimensional molecular structure,
on the composite filaments, so that there can be obtained composite
filaments and knitted or woven fabrics therefrom having excellent
extensibleness and recoverability of their crimps, and further
without deterioration of any bulkiness and crimp extensibility
inherent to composite filaments.
The present invention will be illustrated in detail with reference
to examples hereinafter. The word "part" used in the examples means
"part by weight." The inherent viscosity of the polyamide was
determined in m-cresol solution at 30.degree. C. and that of
polyesters and polyester ethers was determined in o-chlorophenol
solution at 30.degree. C.
Methods for determining degree of crimp, recovery of crimp and
residual crimp in the examples are as follows:
A specimen of multifilament yarn of 20 composite filaments is
soaked in boiling water under a relaxed condition and dried. An
initial load of 2 mg. per denier is applied to the specimen, the
length (l.sub.o) of which is then measured. Next, a load of 100 mg.
per denier is applied to the specimen and two minutes later, its
length (l.sub.1) is measured. And then, after a load of 500 mg. per
denier is applied to the specimen for 2 minutes, the load is
exchanged for a load of 100 mg. per denier and 2 minutes later, its
length (l.sub.2) is measured. Finally the load is exchanged for the
initial load and 2 minutes later, the length (l.sub.3) of the
specimen is measured. Degree of crimp, recovery of crimp and
residual crimp are calculated by the following equations:
##SPC1##
Methods for determining total shrinkage, linear shrinkage, crimp
shrinkage and C.R. value are as follows:
A specimen of multifilament yarn of 20 filaments having a length of
L.sub.0 is soaked in boiling water for 10 minutes, water on the
yarn is removed by filter paper and air-dried. The length (L.sub.1)
of the air-dried specimen is measured, a load of 100 mg. per denier
is then applied thereto and 30 seconds later, the length (L.sub.2)
is measured. The load is exchanged for a load of 2 mg. per denier
and 2 minutes later, the length (L.sub.3) of the specimen is
measured.
Total shrinkage (percent)=(L.sub.0 -L.sub.1)/L.sub.0 .times.100
Linear shrinkage (percent)=(L.sub.o -L.sub.2)/L.sub.0
.times.100
Crimp shrinkage (percent)=(L.sub.2 -L.sub.1)/L.sub.0 .times.100
C.R. value (percent)=(L.sub.2 -L.sub.3)/L.sub.2 .times.100
Tensile elasticity of knitted or woven fabrics is determined by the
following procedure:
A specimen having an effective length of 20 cm. and a width of 5
cm. is stretched on an Instron universal tension tester at a
stretching rate of 2 inches per minutes to a predetermined degree
of elongation, allowed to stand for 1 minute and the length (L cm.
) is recorded. The specimen is restored to a relaxed condition and
1 minute later, the length (L' cm.) of the specimen is measured.
Tensile elasticity is represented by the following formula:
Tensile elasticity (percnt)=(L-L')/(L-20).times.100
With respect to waxy hand, a fabric that no waxy hand had been
appreciated on was designated as grade 1, that a slight waxy hand
appreciated on was as grade 2, that a waxy hand is clearly
appreciated on was as grade 3, that a waxy hand is much appreciated
on was as grade 4, that a waxy hand is extremely appreciated on was
as grade 5 and evaluations made by 10 persons was averaged.
Measurement of water repellency is conducted according to JIS
(Japanese Industrial Standard)-L-1079-19665.24.2: Water
repellency-A method (spraying method).
EXAMPLE 1
One hundred parts of dimethyl terephthalate, 70 parts of ethylene
glycol and 0.02 part of zinc acetate were put into a stainless
steel autoclave. After they had been reacted at 190.degree. C. for
4 hours, methanol was distilled off. Then 0.02 part of antimony
trioxide and 0.02 part of tricresyl phosphate were added to the
reaction mixture, the temperature was raised up to 230.degree. C.
to distil out while excess ethylene glycol, and thereafter the
temperature was further raised while reducing the pressure, up to
280.degree. C. at which temperature a condensation polymerization
was effected under a pressure of 0.5 mm. Hg to yield polyethylene
terephthalate having an inherent viscosity of 0.63 which was later
formed into chips.
In an extruder, those chips were melted at 280.degree. C. and the
melt was extruded from a nozzle having a diameter of 0.3 mm. to
form a filament yarn which was subsequently wound on a bobbin at a
winding speed of 500 meters per minute. The yarn was then drawn to
4.07 times its original length at 90.degree. C. to obtain polyester
fiber (A) of 70 denier of 36 filaments.
An aqueous emulsion comprising 3 parts of methyl hydrogen
polysiloxane having a viscosity of 25 centistokes at 25.degree. C.,
0.08 part of zinc octoate, 0.01 part of nonionic surface-active
agent and 100 parts of water was applied on the yarn by means of an
application roller before the yarn was wound on a bobbin, and the
yarn was air-dried. The amount of methyl hydrogen polysiloxane
fixed on the air-dried yarn was 0.8 percent by weight. The
resultant dried undrawn yarn was drawn to 4.07 times its original
length at 90.degree. C. to obtain polyester fiber (B) of 70
denier.
Thus-obtained polyester fibers (A) and (B) were false-twisted under
conditions of: the number of twist of 3,000 turns per meter, the
heater temperature of 210.degree. C., the heater length of 60 cm.,
the first feeding rate of 2.0 percent, the second feeding rate of
+10.0 percent and the winding speed of 40 meters per minute, to
manufacture respective textured yarns (A) and (B).
Characteristics of the crimps of the resultant textured yarn are
shown in the table 1 which follows:
---------------------------------------------------------------------------
TABLE 1
Item Total Linear Crimp C.R. shrinkage shrinkage shrinkage value
Specimen (%) (%) (%) (%)
__________________________________________________________________________
Textured yarn(A) (Comparative) 81.0 5.9 75.1 29.4 Textured yarn(B)
(present invention) 82.7 5.3 77.4 39.2
__________________________________________________________________________
As is apparent from the above table 1, the yarn manufactured
according to the present invention had a remarkably large C.R.
value in comparison with the comparative yarn, though they showed
substantially the same crimp shrinkage. This face proved that the
yarn manufactured according to this invention possessed an
excellent crimp recoverability.
Furthermore, even after the textured yarn (B) had been washed
continuously for 2 hours at 25.degree. C. in a bath having a bath
ratio of 50:1 and containing 2 g/l. of Monogen (a trade name of a
neutral soap manufactured by Daiichi Kogyo Seiyaku K.K.) in a
reversible automatic washing machine, yet its C.R. value was not
lowered and its excellent durability was ascertained.
EXAMPLE 2
A polyester false-twist textured yarn of 75 denier of 36 filaments
manufactured by a conventional process having a twist of S
direction and another polyester yarn as such having a twist of Z
direction were combined into a two-ply yarn having a twist of Z
direction 150 turns. A plain fabric having densities of its warp
and filling respectively of 70 per inch was woven with the
above-mentioned yarn. After soaking in boiling water for 30 minutes
in a relaxed condition, the fabric was subjected in sequence to
desizing, scouring, presetting and dyeing processes in conventional
manners. The resultant woven fabric exhibited an extensibleness in
the warp direction of 12 percent and that in the weft direction of
7 percent.
Six pieces of the fabric thus obtained were soaked in respective
aqueous emulsions of six kinds consisting of 0.2 part of methyl
hydrogen polysiloxane having a viscosity of 30 centistokes at
25.degree. C., 0.3 part of dimethyl polysiloxane having a viscosity
of 1,000 centistokes at 25.degree. C., 0.02 part of zinc issootoate
and 100 parts of water, which emulsions further containing
polyoxyethylene lauryl ether having an average molecular weight of
about 800 in such different amounts that proportions of the
polysiloxane to the polyoxyethylene lauryl ether in emulsion were
10:1, 7:1, 3:1, 1:1, 1:2 and 1:4 respectively, squeezed by means of
a roller mangle to the pickup of 100 percent, dried at 100.degree.
C. in hot air and subjected to 1-minute cure at 170.degree. C. to
obtain fabrics (C), (D), (E), (F), (G) and (H). On the other hand,
the aforementioned dyed fabric was subjected to 1-minute cure at
170.degree. C. without subjecting to the polysiloxane treatment and
thus fabric (I) was obtained. With respect to all those fabrics, an
elastic recovery at 10 percent extension, waxy hand and water
repellency were measured and the results is shown in table 2 which
follows:
---------------------------------------------------------------------------
TABLE
2 Elastic recovery Water at 10% extension Waxy repel- Specimen (%)
hand lency
__________________________________________________________________________
C (comparative) 90.3 4.6 90 D (present invention 89.5 3.4 70 E
(present invention) 89.0 1.3 0 F (present invention) 88.6 1 0 G
(present invention) 87.7 1 0 H (comparative) 84.1 1 0 I
(comparative) 82.5 1 0
__________________________________________________________________________
As is apparent from the above table 2, the fabrics treated
according to the process of the present invention had a
satisfactory recovery from extension and a desirable hand free from
waxy hand and water repellency.
EXAMPLE 3
According to a conventional process, chips of a copolymer of 90
mole percent of polyethylene terephthalate and 10 mole percent of
polyethylene isophthalate, having a inherent viscosity of 0.6 in
o-chlorophenol solution at 30.degree. C., and chips of polyethylene
terephthalate having an inherent viscosity of 0.63 in
o-chlorophenol solution at 30.degree. C. were respectively
manufactured and the two kinds of chips were spun, according to a
conventional conjugate spinning method, with an extrusion ratio of
one to one, to produce a crimpable polyester composite filament
yarn of 75 denier of 36 filaments, which yarn was then fed at a
rate of 200 meters per minute into a stainless steel tube having an
inside diameter of 2 mm. and a length of 500 mm., heated at
170.degree. C. and withdrawn at a rate of 125 meters per minute to
obtain a crimped yarn. To the resultant crimped yarn was imparted a
Z-twist of 150 turns per meter and the twisted yarn was doubled
into a unitary doubled yarn with which a plain fabric having a warp
density of 70 and a weft density of 70 was woven according to a
conventional method. After relaxing for 30 minutes in boiling
water, the fabric was scoured, preset and dyed according to a
conventional manner. The resultant fabric exhibited an elongation
of 15 percent in the warp direction and that of 10 percent in the
weft direction, and the fabric was then soaked in an aqueous
emulsion consisting of 1.2 parts of methyl hydrogen polysiloxane
having a viscosity of 15 centistokes at 25.degree. C., 0.8 part of
dimethyl polysiloxane having a viscosity of 10,000 centistokes at
25.degree. C., 0.7 part of polyoxyethylene octylphenol ether having
an average molecular weight of about 800, 0.02 part of zinc
naphthenate and 97.6 parts of water; squeezed to remove an excess
solution up to a pickup of 100 percent by weight based on the
fabric; and thereafter subjected to a preliminary drying at
100.degree. C., followed by one minute cure at 170.degree. C. Thus,
a fabric (J) having an excellent elastic recovery from extension
and decreased waxy hand and water repellency resulted. The elastic
recoveries at 15 percent extension in the warp direction with
respect to the fabric (J) as well as a fabric (K) which had not
been subjected to the treatment of the present invention were
determined, that of the former being 93.8 percent and that of the
latter being 88.2 percent. The values of waxy hand of those fabrics
(J) and (K) were determined as 1.3 and 1.0 respectively and the
values of water repellency of those fabrics were both 70.0.
EXAMPLE 4
One hundred parts of dimethyl terephthalate, 70 parts of ethylene
glycol and 0.02 part of zinc acetate were put into a stainless
steel autoclave. After they had been reacted at 190.degree. C. for
4 hours, methanol was distilled off. Then 0.02 part of antimony
trioxide and 0.02 part of tricresyl phosphate were added to the
reaction mixture, the temperature was raised up to 230.degree. C.
to distil out excess ethylene glycol, and thereafter the
temperature was further raised, while reducing the pressure, up to
280.degree. C. at which temperature a condensation polymerization
was effected under a pressure of 0.5 mm. Hg to yield polyethylene
terephthalate having an inherent viscosity of 0.63 which was later
formed into chips.
One hundred parts of .beta.-hydroxyethoxy benzoic acid methyl
ester, 0.02 part of zinc acetate and 0.03 part of antimony trioxide
were put into a stainless steel autoclave equipped with an
agitator. After they had been reacted at 240.degree. C. for 1 hour
in an environment of nitrogen gas, the temperature was raised up to
260.degree. C. and the polymerization reaction was carried out for
5 hours under a pressure of 0.5 mm. Hg to yield polyethylene
oxybenzoate having an inherent viscosity of 0.60 which was later
formed into chips.
Into two hoppers, thus obtained two kinds of chips were separately
supplied, which were then melted individually at 280.degree. C. and
the melts were simultaneously extruded from the same orifices of a
spinneret provided with 36 orifices having diameters of 0.4 mm., in
a side-by-side relation with an extrusion ratio by weight of one to
one to form a composite filament yarn which was wound up on a tube
at a winding speed of 500 meters per minute and which was
thereafter drawn to 4.07 times its original length at 90.degree. C.
During the drawing operation, before winding on a pirn, to the
drawn yarn was applied, by means of an application roller, an
aqueous emulsion consisting of 0.3 part of dimethyl polysiloxane
having a viscosity of 10,000 centistokes at 25.degree. C., 0.045
part of methyl hydrogen polysiloxane diol having a viscosity of 30
centistokes at 25.degree. C., 0.008 part of zinc octoate, 0.01 part
of a nonionic surface active agent and 99.7 parts of water. The
amount of polysiloxane adhered to or adsorbed by the yarn was 0.2
percent by weight. After air drying, the yarn was fed at a rate of
200 meters per minute into a stainless steel tube having an inside
diameter of 2 mm. and a length of 500 mm., heated at 170.degree.
C., withdrawn at a rate of 130 meters per minute, soaked in boiling
water for 10 minutes under a tensionless condition and air dried to
obtain a crimped fiber yarn (M).
For the purpose of comparison, a crimped fiber yarn (N) was
manufactured according to the same process as above with the
exception that it was not treated with the aqueous emulsion of
polysiloxane.
Characteristics of crimps with respect to the crimped fiber yarns
(M) and (N) are shown in table 3 which follows:
TABLE 3
Item Degree of Recovery of Residual crimp crimp crimp Specimen (%)
(%) (%)
__________________________________________________________________________
Yarn (M) (present invention) 27.1 75.1 20.3 Yarn (N) (comparative)
31.4 70.5 22.1
__________________________________________________________________________
The aforementioned composite filament yarns which had been
subjected to the heat treatment in the stainless steel pipe
followed by the relaxed treatment were doubled into respective
two-ply yarns were then woven into respective plain fabrics having
both warp and weft densities of 70 per inch. The resultant fabrics
were soaked in boiling water for 30 minutes, then scoured and dyed.
A recovery at 10 percent extension in the direction of the weft was
determined with respect to the thus obtained fabrics and the result
is shown in table 4 which follows:
---------------------------------------------------------------------------
TABLE
4 Item Recovery at Tensile 10% extension stress (kg.) Specimen (%
__________________________________________________________________________
Fabric of the invention 91.5 2.2 Comparative 87.3 3.2
__________________________________________________________________________
As is apparent from the above tables 3 and 4, it was proved that
articles manufactured according to the present invention were
extremely excellent in their elastic recoverability from
extension.
Furthermore, for the purpose of comparison, the aforementioned
composite filament yarn consisting of polyethylene terephthalate
and polyethylene oxybenzoate was subjected to a polysiloxane
application treatment, cure and crimp developing treatment in the
same process and under the same conditions as the above with the
exception that dimethyl polysiloxane having a viscosity of 80,000
centistokes at 25.degree. C. and methyl hydrogen polysiloxane
having a viscosity of 60 centistokes at 25.degree. C. was employed
in lieu of the above-mentioned mixed polysiloxane. However, the
resultant crimped fiber yarn exhibited considerable stickiness and
its crimp recovery at 10 percent extension was no more than 79.7
percent.
EXAMPLE 5
One hundred parts of hexamethylene diammonium adipate together with
10 parts of water and 0.3 part of acetic acid was put into a
stainless steel autoclave and polymerized at 250.degree. C. for 2
hours under a pressure of 6 kg./cm..sup.2. Then the temperature was
raised up to 270.degree. C. the pressure reduced to atmospheric
pressure in 1 hour and the reaction was carried out for 3 hours in
an environment of nitrogen gas, which was followed by further 2
hour polymerization under a reduced pressure of 100 mm. Hg, to
yield nylon-66 having an inherent viscosity of 1.10 which was later
formed into chips.
The thus obtained nylon-66 chips and polyethylene terephthalate
chips prepared in the foregoing example 4 were individually
supplied into two hoppers, which were then melted separately at
280.degree. C. and the melts were simultaneously extruded from the
same orifices of a spinneret provided with its 24 orifices having
their diameter of 0.4 mm. with an extrusion ratio by weight of one
to two, to form a composite filament yarn, individual filament of
which consisted of an eccentric core of nylon-66 and of a sheath of
polyethylene terephthalate.
In the spinning process, an aqueous emulsion consisting of 1 part
of a conventional spinning oil, 2 parts of dimethyl polysiloxane
having a viscosity of 5,000 centistokes at 25.degree. C., 1 part of
methyl hydrogen polysiloxane having a viscosity of 30 centistokes
at 25.degree. C., 0.01 part of dibutyl tin laurate and 97 parts of
water, was applied to the as-spun yarn by means of a rotatory
application roller before the yarn was wound on a takeup tube. The
undrawn yarn was air dried and drawn at 90.degree. C. to 4.19 times
its original length to obtain a composite filament yarn of 70
denier. The drawn composite filament yarn had 0.43 percent by
weight of polysiloxane adhered thereon.
The resultant composite filament yarn was then taken up on a skein
which was allowed to stand under a relaxed condition in a dryer
heated at 190.degree. C. to obtain a crimped yarn (O).
For the purpose of comparison, a crimped yarn (P) was prepared in
the same manner as the above with the exception that the
polysiloxane was not applied to it.
Characteristics of crimps determined with respect to the crimped
yarns (O) and (P) are shown in table 5 which follows:
---------------------------------------------------------------------------
TABLE
5 Item Degree Recovery Residual of crimp of crimp crimp (%)
Specimen (%) (%)
__________________________________________________________________________
Crimped yarn (O) (present invention) 54.7 73.8 40.3 Crimped yarn
(P) (Comparative) 56.2 65.1 36.6
__________________________________________________________________________
The crimped yarns (O) and (P) were knitted into respective knitted
fabrics, of which an elastic recovery from 100 percent extension
was determined. The knitted fabric which had been knitted from the
crimped yarn manufactured according to the present invention had
its value of 94.5 percent, whereas the knitted fabric from the
comparative crimped yarn exhibited the recovery of 88.2 percent
EXAMPLE 6
Polyethylene oxybenzoate chips having an inherent viscosity of 0.6
and polyethylene terephthalate chips having an inherent viscosity
of 0.63 which were prepared in a conventional process, were
separately melted and extruded simultaneously in a side-by-side
relation from the same orifices of a spinneret with an extrusion
ratio of one to one to form a polyesteric composite filament yarn
which was thereafter drawn in a conventional manner to obtain a
crimpable drawn yarn of 75 denier of 24 filaments. The drawn yarn
was fed at a rate of 200 meters per minute into a stainless steel
tube having an inside diameter of 2 mm. and a length of 500 mm.,
heated at 170.degree. C. and withdrawn at a rate of 180 meters per
minute, whereby the yarn developed its crimps. A two-ply yarn of 75
denier of 24 filaments provided with an S-twist of 150 turns per
meter was prepared from the above-obtained yarn, and employing the
said two-ply yarn as warps and wefts, a fabric was woven with
designed densities of 70 per inch both of warp and of weft. After
soaking and relaxing in boiling water for 30 minutes, the woven
fabric was desized, scoured, preset and dyed according to a
conventional manner. The resultant fabric exhibited an
extensibleness of 15 percent in the warp direction and that of 22
percent in the weft direction.
The thus obtained fabric composed of crimpable polyester composite
filament yarns was soaked sufficiently in an aqueous emulsion
consisting of 0.3 part of dimethyl polysiloxane having a viscosity
of 5,000 centistokes at 25.degree. C., 0.045 part of methyl
hydrogen polysiloxane having a viscosity of 30 centistokes at
25.degree. C., 0.08 part of zinc octoate, 0.01 part of a nonionic
surface active agent and 99.7 parts of water; withdrawn from the
emulsion; squeezed to remove excess liquid; preliminarily dried at
80.degree. C. and cured at 170.degree. C. for 1 minute. The treated
fabric had 0.5 percent by weight of polysiloxane fixed thereupon.
The fabric treated according to the process of the present
invention showed an elastic recovery at 15 percent extension of
90.2 percent in the warp direction and of 92.5 percent in the weft
direction, whereas the same fabric before treated with polysiloxane
showed an elastic recovery at 15 percent extension of 85.7 percent
in the warp direction and of 88.7 percent in the weft direction.
Thus, a remarkable improvement in elastic extensibleness effected
and attained by the present invention has been proved by comparison
of the two fabrics mentioned above.
* * * * *