U.S. patent number 3,622,434 [Application Number 05/042,924] was granted by the patent office on 1971-11-23 for creped fiber-film combination and process therefor.
This patent grant is currently assigned to The Kendall Company. Invention is credited to Nicholas S. Newman.
United States Patent |
3,622,434 |
Newman |
November 23, 1971 |
CREPED FIBER-FILM COMBINATION AND PROCESS THEREFOR
Abstract
A lightweight fibrous fleece is prepared, containing a
sufficient proportion of heat-retractable fibers to make the fleece
potentially capable of shrinking 20 percent or more in area if
heated without restraint. The fleece as prepared is bonded to a
soft film which does not shrink to any great extent when heated
under conditions which would cause the fleece to shrink. The
bonding of fleece to film is done under restraint, not allowing
shrinkage. Subsequently the fleece-film combination is heated
without restraint. The heat-retractable fibers shrink, creating a
pebbled or creped texture on both faces of the combination.
Inventors: |
Newman; Nicholas S. (West
Newton, MA) |
Assignee: |
The Kendall Company (Boston,
MA)
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Family
ID: |
21924474 |
Appl.
No.: |
05/042,924 |
Filed: |
June 3, 1970 |
Related U.S. Patent Documents
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Application
Number |
Filing Date |
Patent Number |
Issue Date |
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655881 |
Jul 25, 1967 |
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Current U.S.
Class: |
428/179; 156/183;
428/91; 428/394; 156/85; 428/153 |
Current CPC
Class: |
B32B
5/022 (20130101); B32B 27/308 (20130101); B32B
3/28 (20130101); B32B 27/40 (20130101); D04H
1/60 (20130101); D06N 3/0031 (20130101); B32B
27/12 (20130101); Y10T 428/24455 (20150115); Y10T
428/24669 (20150115); B32B 2262/0253 (20130101); Y10T
428/2967 (20150115); Y10T 428/2395 (20150401) |
Current International
Class: |
D04H
1/58 (20060101); D06N 3/00 (20060101); D04H
1/60 (20060101); B32b 003/28 () |
Field of
Search: |
;161/128,129,151,170,113,117 ;156/85,183 ;264/282,342 |
Foreign Patent Documents
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|
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727,591 |
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Apr 1955 |
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GB |
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742,295 |
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Dec 1955 |
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GB |
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Primary Examiner: Powell; William A.
Parent Case Text
This application is a continuation-in-part of my copending
application Ser. No. 655,881, filed July 25, 1967, now abandoned.
Claims
Having thus described my invention, I claim:
1. The process of producing a nonwoven fabric with a creped surface
which comprises
assembling an unspun and unwoven array of textile-length fibers
comprising at least a proportion of thermoretractive fibers capable
of shrinking at least 10 percent when heated,
bonding at least one layer of said fibrous array to at least one
face of a soft, deformable polymeric film under conditions which
allow substantially no shrinkage of said film or said fibrous
array,
said film being selected from the class consisting of polyurethane
films and modified cross-linkable acrylic films and being
characterized by a cantilever bending length of not greater than
0.25 inches,
and heating the laminate thus formed to the retractive temperature
of the thermoretractive fibers under conditions which allow
substantially uninhibited shrinkage of said laminate,
whereby the laminate is textured to possess a creped surface,
the hills and valleys of one face of the product corresponding to
valleys and hills on the opposite surface.
2. The process according to claim 1 in which between 25 percent and
75 percent of the fibers are thermoretractive.
3. The process according to claim 1 in which the laminate is caused
to shrink at least 20 percent in area in the uninhibited shrinkage
step.
4. The process according to claim 1 in which the thermoretractive
fibers are polyolefin fibers.
5. The process according to claim 1 in which a layer of
textile-length fibers comprising thermoretractive fibers is bonded
to one face of a film.
6. The process according to claim 1 in which a layer of
textile-length fibers comprising thermoretractive fibers is bonded
to both faces of a film.
7. An elastic, creped, and textured nonwoven laminate comprising a
layer of polymeric film and at least one layer of textile-length
fibers consisting essentially of thermally retracted fibers,
said polymeric film being selected from the class consisting of
polyurethane films and modified acrylic films, and being
characterized by a cantilever bending length of not greater than
0.25 inches,
at least one face of said film being bonded to said fibrous
layer,
the laminate formed by said fibrous layer and said film being
corrugated into a fine-grained pattern of hills and valleys,
the hills and valleys on one face of the laminate corresponding to
valleys and hills respectively on the other face thereof, said
laminate being soft and elastic, capable of substantially complete
recovery when extended 10 percent and allowed to relax.
Description
This invention relates to the preparation of nonwoven fabrics
consisting of fleeces of textile-length fibers bonded to soft,
deformable films, the combination being treated so as to impart a
pebbled or creped texture to both surfaces of the product. More
particularly it relates to relatively thin fiber-film bonded
combinations of creped surface texture wherein the hills and
valleys of the obverse surface are reflected as valleys and hills
on the reverse surface.
Bonded nonwoven fabrics, comprising textile-length dry-assembled
unspun and woven fibers bonded by polymeric binding materials, are
produced by a variety of well-known processes and are a staple
article of commerce. Since they are uniform and planar on their
surfaces, resembling generally a sheet of paper, they lack surface
interest. Attempts have been made to overcome this deficiency by
printing on the surface of thin, planar nonwoven fabrics a pattern
resembling interwoven yarns, or by embossing the surface under
pressure. Either expedient, however, merely creates a perfectly
repetitive pattern on the surface of the sheet, which therefore
lacks the desired casual, random, nonrepetitive appearance such as
that obtained in fabrics woven with slubbed or other types of
nonuniform yarns. The present invention is concerned with a novel
method for producing a truly randomized and nonrepetitive surface
textured effect, resembling a creped or pebbled surface, on both
faces of relatively thin and lightweight nonwoven fabrics. The
fabrics of this invention have good tensile strength coupled with
substantial elongation and recovery therefrom, a combination of
properties which renders them suitable for disposable garments,
draperies and the like.
Attempts have previously been made to impart surface texture to
thick, feltlike nonwoven fabrics by combining layers of
heat-retractable fibers with layers of nonretractable fibers
needled together and heated, as in U.S. Pat. No. 3,243,861.
It has also been proposed to bond together fibrous webs of
differing heat retractabilities by means of spaced-apart areas of
binder substance, leaving unbonded areas of free fibers. As
described in U.S. Pat No. 3,214,323, heating such an assembly puffs
the free fiber segments into ridges, imparting a lofty, bulky
appearance to the fabric. Such feltlike products are usually either
textured on one face only, or the ridges on one face are matched by
ridges on the other face. Various mechanical expedients, such as
mechanical creping between differentially moving surfaces, have
been employed to crepe nonwoven fabrics, as in U.S. Pat. No.
3,059,313. A mechanically imparted crepe, however, is a transient
state, removable or distortable under tension.
It is an object of this invention to provide a relatively thin and
sheetlike nonwoven fabric comprising a layer of textile-length
fibers bonded to a layer of film, said fabric having a textured
surface arranged in a pebbled or creped configuration in which the
ridges and valleys of one surface correspond to valleys and ridges
on the other surface.
It is a further object of the invention to provide a product as
above wherein the fabric has sufficient elasticity to allow it to
be elongated to at least 10 percent with substantially complete
retention of its surface texture upon recovery from elongation.
Other objects of the invention will be apparent from the following
description and drawings, in which:
FIG. 1 is a magnified cross-sectional view of a fiber-film bonded
combination before retraction of the fibers and,
FIG. 2 is the product of the invention, being the product of FIG. 1
after heat retraction has been effected.
FIG. 3 is a representative cross section of the product of FIG.
2.
FIGS. 2 and 3 are less highly magnified than FIG. 1.
As a first step in the practice of this invention, a fleece of
textile-length fibers is prepared. By textile-length is meant those
fibers, usually 0.5 inches in length or longer, which can be
processed on dry-assembling equipment met within the textile field,
such as cards, garnets, air-lay or cross-lay devices, and the like.
At least a portion of the fibers in the fleece are
heat-retractable: that is, capable of shrinking at least 10 percent
in length when heated to a suitable temperature. Typical
heat-shrinkable fibers include the polyolefins such as polyethylene
and polypropylene fibers; fibers known as vinyon which are formed
from a copolymer of vinyl acetate and vinyl chloride; certain
polyester fibers; fibers formed from copolymerized vinyl
chloride-vinylidene chloride; and the like. In general, it is
preferred that the fibrous fleece contain between 25 and 75 percent
of heat-retractable fibers, although with strongly retracting
fibers as little as 15 percent may be effective and over 75 percent
may be employed for maximum depth of the surface convolutions which
are to be formed.
The balance of the fibrous fleece will normally be between 75 and
25 percent of a textile-length fiber which is substantially
unaffected by the temperatures which cause the heat-retractable
fibers to shrink. Viscose rayon, cotton, cellulose acetate and
nylon are representative of such a class.
The thermoretractive fibers and the insensitive fibers are
intimately comingled and blended together in order to bring about
the fine-grained, pebbled effect desired in this invention. That
is, the operative shrinking force is that of a thermoretractive
fiber on a film, the fiber being bonded to the film at a
multiplicity of points along its length.
The film to which the fibrous fleece is to be bonded must satisfy
two criteria: at the temperature of the unrestricted shrinkage
step, explained below, it should be limp enough and conformable
enough to be readily drawn up into a creped or pebbled
configuration by the retraction of the thermosensitive fibers
adherent thereto. Second, the film must not melt, and shrink, or
lose its integrity at the retraction temperature of the
thermosensitive fibers. What is required is a film which is
thermally stable and nonshrinking at the fiber retraction
temperature, but which is soft and readily deformable at said
temperature.
The softness and deformability of the film is related to its
stiffness, which preferably does not exceed 0.25 inches when
measured by the Cantilever Bending Method, Textile Test Methods,
Federal Specification CCC-T-1,916, Method 5,206.2.
Films which are particularly suited to the practice of this
invention are certain types of polyurethane films and modified,
cross-linkable polyacrylic films. The polyurethane films are those
which are cast from polymers prepared by the reaction of an
isocyanate with a polyol, and are of the class known as
thermoplastic polyurethanes-- i.e., they are of the elastomeric,
nonfoamable type, processable by milling of calendering. They
generally are characterized by an initial softening range of
250.degree. -275.degree. F.
The cross-linkable polyacrylic films belong to a class of films
which have a temperature range within which they are tacky and
adhesive, but which contain cross-linking reactants so that on
heating or curing at elevated temperatures, the film becomes
irreversibly thermoset and cannot be reverted to a thermoplastic
condition. Such types of film may consist of an acrylic polymer
containing in the polymeric chain reactive groups capable of
cross-linking, at elevated temperatures, with a reactant such as
melamine formaldehyde, which is incorporated in the film substance.
Such films are soft and plastic at room temperature, flowing
readily under modest heat and pressure. When heated to 300.degree.
F., or more, the film cross-links internally and becomes thermostat
in nature.
The fibrous fleece described above is bonded to a layer of selected
film. In the case of thermoplastic as well as thermoretractive
fibers, or for thermoplastic films, the bonding may conveniently be
effected by heat and pressure, as by the use of heated press rolls
or heated plates. It is important at this stage that no significant
shrinkage be allowed to develop in the fibrous fleece.
If desired, the fibers may be bonded to the film by a suitable
flexible adhesive which will not interfere with or be adversely
affected by the subsequent heat treatment. Hot calendering,
however, is the preferred method of this invention, utilizing
pressures of from 700 to 1,500 pounds per inch of nip width and a
temperature sufficient to bond a major proportion of the
thermoretractive fibers to the base film at a multiplicity of
points along their length.
The resulting calendered product is presented in cross section by
FIG. 1, where 10 represents the layer of film and 12 represents a
fibrous fleece comprising thermoretractive fibers. The fibrous
fleece is adherent to and preferably partially embedded in the
film. Embedment should not be so extensive as to completely
surround and engulf the fibers, however, since this seems to impede
or inhibit the subsequent development of crepe.
The essentially planar product of FIG. 1 is then heated to a
temperature at which the thermoretractive fibers in the fleece will
decrease in length. This heating step must be carried out under
conditions which allow for free and unimpeded shrinkage of the
product, as is conveniently effected by passing the product
continuously through a heated oven while supporting it on a
conveyor belt. FIG. 2 represents the pebbled or creped film surface
of the product of FIG. 1 after the heat-retraction step. The
formerly planar film surface is found to be drawn up into a
decorative array of fine-grained ridges 14 and valleys 16, lending
an air of surface interest not possessed by conventional nonwoven
fabrics.
The invention will be illustrated by the following examples.
EXAMPLE 1.
A carded web of blended and intermingled 50 percent denier 1.5
-inch polypropylene fibers and 50 percent dull crimped viscose
rayon 1.5 denier 1-9/6 inch fibers, weighing 19 grams per square
yard, was laminated to a 1 mil cross-linkable acrylic film. The
film, being somewhat tacky, was supported on silicone-coated
release paper while the film and web were passed through the nip
formed by a cotton-filled roll heated to 200.degree. F., and a
steel roll heated to 300.degree. F., at a pressure of 1,250 pounds
per inch of nip. The essentially planar, unshrunken laminate was
then allowed to shrink, without restraint, in an oven at
330.degree. F.
The laminate shrank 20 percent in area while developing a soft,
drapeable hand and an interesting pebbled surface texture, wherein
the ridges and valleys on one surface corresponds to valley and
ridges on the other surface.
The product had a tensile strength per inch wide strip of 14 pounds
in the machine and 2 pounds in the cross direction. Elongation at
break was 70 percent machine direction, 140 percent cross
direction. The pebbled surface texture of the film was
substantially completely recoverable after elongations below the
ultimate, the film apparently being set in the textured
configuration. This may be due to the fact that he film, being an
acrylic polymer with cross-linking possibilities, is converted from
an adhesive, thermoplastic state to a cross-linked, thermoset state
during the curing step, during which it is simultaneously being
deformed into a textured configuration by the shrinkage of the
polypropylene fibers which are intermittently bonded thereto.
EXAMPLE 2.
Under physical conditions similar to those of example 1, a 75
percent viscose rayon- 25 percent polypropylene fibrous web
weighing 28 grams per square yard was bonded to 1.5 mil
thermoplastic polyurethane film. The product had a tensile strength
per inch wide strip of 14.2 pounds in the machine direction, 2.2
pounds in the cross direction. Elongation at break was 51 percent
in the machine direction, 15 percent in the cross direction, and
the product had a pebbled texture similar to the product of example
1.
Another embodiment of the present invention lies in the production
of creped or pebbled laminates with a fibrous surface on each face
of a film.
EXAMPLE 3.
Using the same 19 gram card webs and the same film as in example 1,
one card web was bonded at light pressure and a temperature of
about 200.degree. F. to one side of a layer of cross-linkable
acrylic film supported on release paper. The release paper was
removed and a second, similar carded web was plied with the fresh
side of the film by calendering at 300.degree. E. and 1,250 pounds
pressure as in example 1.
Shrinkage at 300.degree. F. in an oven converted the essentially
planar product to a highly creped material, resembling a nonwoven
seersucker, with a tensile strength of 36 pounds machine direction,
7 pounds cross direction, and an elongation of 90 percent machine
direction, 125 percent cross direction.
If increased air and water permeability in the film section of the
product is desired, the invention may be practiced employing slit
film, or perforated or netlike films such as are described in U.S.
Pat. Nos. 3,012,918 and 3,137,746. In this manner, practically any
desired degree of porosity and permeability may be built into a
surface-textured nonwoven fabric.
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