U.S. patent number 3,622,281 [Application Number 04/865,350] was granted by the patent office on 1971-11-23 for high-temperature reaction vessel.
This patent grant is currently assigned to Hydrocarbon Research, Inc.. Invention is credited to Franklin D. Hoffert, John D. Milligan.
United States Patent |
3,622,281 |
Milligan , et al. |
November 23, 1971 |
HIGH-TEMPERATURE REACTION VESSEL
Abstract
A high-temperature, high-pressure vapor phase reactor for
chemical conversions requiring a quench to maintain the reaction
temperature substantially isothermal, which is capable of easy
field assembly and additionally allows for differential of
expansion.
Inventors: |
Milligan; John D. (Little
Silver, NJ), Hoffert; Franklin D. (Mountainside, NJ) |
Assignee: |
Hydrocarbon Research, Inc. (New
York, NY)
|
Family
ID: |
25345310 |
Appl.
No.: |
04/865,350 |
Filed: |
October 10, 1969 |
Current U.S.
Class: |
422/207; 220/917;
165/81; 196/133; 261/148; 585/401; 585/403; 165/101; 422/208;
585/402; 585/483; 220/560.04 |
Current CPC
Class: |
C07C
4/16 (20130101); B01J 3/04 (20130101); B01J
2219/1943 (20130101); B01J 2219/185 (20130101); Y10S
220/917 (20130101) |
Current International
Class: |
C07C
4/00 (20060101); B01J 3/04 (20060101); C07C
4/16 (20060101); B01j 003/02 () |
Field of
Search: |
;23/283,290,289,288.91,285,260,1B,1E,252
;260/300,698,672,683,688.4F ;165/101 ;261/148-155 |
References Cited
[Referenced By]
U.S. Patent Documents
Primary Examiner: Tayman, Jr.; James H.
Claims
We claim:
1. An elongated substantially cylindrical reactor to be operated
under conditions of elevated temperatures and pressures while
maintaining a highly exothermic reaction under substantially
isothermal conditions with the continuous addition of reactants
thereto and withdrawal of effluent therefrom which comprises:
a. a rigid outer cylindrical shell having a closed fixed lower end
and a removable upper end closure;
b. a first inner cylindrical shroud concentric with said shell and
extending upwardly from the fixed lower end to which it is
affixed;
c. a second inner cylindrical shroud concentric with said shell
extending downwardly from the upper end of the shell to which it is
affixed and telescopically joined to said first shroud;
d. a reactant inlet extending through the lower portion of the
rigid shell and the first shroud;
e. a reactant distributor conduit connected to said inlet and
extending vertically upward within the shell;
f. a distributor head telescopically joined to the upper portion of
the reactant distributor conduit for introducing reactant in the
top portion of the reactor;
g. means for mounting the distributor head on the second
cylindrical shroud;
h. multioutlet heat-quenching means extending centrally downwardly
from and supported by the removable upper closure, said
heat-quenching means having a plurality of vertically spaced
discharge outlets;
i. means within the shell for controlling flow of quenching medium
from the multioutlet heat-quenching means, and
j. a discharge outlet extending through the lower portion of the
shell and the first shroud.
2. The reactor of claim 1 wherein said first and second inner
shrouds are corrosion resistant.
3. The reactor of claim 1 wherein said heat-quenching means
comprises a nest of interdependently supported quench tubes said
tubes extending substantially throughout the reactor height with
different tubes having outlets at different levels within the
reactor for quench distribution at the respective level.
4. The reactor of claim 3 and wherein the nest of quench tubes is
provided with valve means for controlling flow in each of said
tubes.
5. The reactor of claim 4 and wherein the means within the shell
for controlling flow of quenching medium from the multioutlet
heat-quenching means comprises thermocouple devices extending
throughout the height of the reactor for separately controlling the
quench tube valve means.
6. The reactor of claim 1 and wherein the distributor head
comprises a vertical conduit telescopically joined to the upper
portion of the reactant distributor conduit and horizontally
disposed distributing outlet tubes connected to said vertical
conduit.
7. The reactor of claim 6 and wherein the outlets for the
heat-quenching means are annular members with openings in the outer
peripheral portion to introduce quenching medium evenly into the
reactor.
Description
BACKGROUND OF THE INVENTION
The thermal hydrodealkylation of alkylated aromatics such as
toluene to produce benzene is well known as described in the King
et al. U.S. Pat. No. 3,291,849. It is also recognized that in a
hydrogenation reaction, the temperature rise in the reaction zone
is on the order of 70.degree. F. per mol of hydrogen consumed and
in view of the fact that it is necessary to keep the operating
pressures in the range of 500 to 800 p.s.i.g., the reaction time
within the period of 10 to 50 seconds and with a temperature range
in the order of 1,100.degree.-1,500.degree. F., it is of critical
circumstances that the reactor be effectively designed. Quench
streams are used for control of the reactor conditions.
It is also known that high-temperature reactors, particularly in
the chemical field, must not only provide for maintaining desired
temperature conditions but also must permit an effective physical
assembly of the parts. With the large variations in a temperature
from the normally cold to the normally hot reactor environment,
suitable provision must be made for expansion and contraction of
the parts. Furthermore, corrosion of the structural materials must
be avoided or minimized; protecting the insulation through
temperature changes is also critical.
In addition to providing in the reactor for temperature changes, it
also becomes necessary to provide a structurally sound quench
system. The invention contemplates a unique arrangement of parts
whereby operating limits can be observed with an economical
construction.
Emphasis is placed on the economic factor inasmuch as reactors of
this type, which will operate in the temperature and pressure
ranges indicated, and frequently with a hydrogen atmosphere, are
necessarily constructed in sizes of 4 feet and more internal
diameter with an internal height of from 25 to 100 feet. For the
hydrodealkylation of toluene to make benzene, this requires wall
thickness in excess of 4 inches. The unit is preferably
freestanding and hence must be inherently rigid.
SUMMARY OF THE INVENTION
The invention applies particularly to a high-pressure
hydroconversion reactor, substantially free of catalyst or
catalytic surface which will permit the control of hydrogenation
reactions and will provide for the necessary differential of
expansion and permit the effective quench of the reaction to
establish for the reaction, a shallow saw tooth temperature
profile.
BRIEF DESCRIPTION OF THE DRAWINGS
FIG. 1 is a schematic substantially central vertical section
through a reactor with parts shown in elevation.
FIG. 2 is a part elevation, part section of the upper part of a
feed distributor unit.
FIG. 3 is a top plan view with parts in section of one of the
distributor units as shown in FIG. 2.
FIG. 4 is a horizontal section substantially on the line 4--4 of
FIG. 2.
FIG. 5 is a horizontal section substantially on the line 5--5 of
FIG. 1.
FIG. 6 is a partial elevation, partial section of a part of the
quench unit substantially on the line 6--6 of FIG. 5.
FIG. 7 is an enlarged vertical section approximately on the line
7--7 at the upper part of the reactor showing the details of
construction.
FIG. 8 is a partial horizontal cross section through the reactor at
line 8--8 of FIG. 9.
FIG. 9 is a vertical section at the lower part of the reactor at
right angles to FIG. 8.
FIG. 10 is a diagrammatic top plan view of the quench inlets to the
reactor .
DESCRIPTION OF THE PREFERRED EMBODIMENT
The reactor generally shown at 10 is a vertical cylindrical vessel
appropriately supported from the ground by a skirt or legs or
similar support indicated at 12. A removable head 14 is
appropriately secured at the upper part by the typical gaskets and
bolting devices, not shown in FIG. 1.
Reactant inlets are indicated at 16 and in a reactor of typical
commercial size it is appropriate to have at least two or more
which are equally spaced around the perimeter.
Each of the reactant inlets 16 is interconnected to internal
vertically extending distributions conduit 18 which are surmounted
by a distributor head 20 as shown in FIGS. 2 and 3. By this means,
the reactants are introduced at the lower part of the reactor and
are distributed at the upper part of the reactor through outlets 21
from which they pass downwardly and out at the bottom thereby
minimizing external piping. As indicated in FIG. 2, a suitable slip
joint 24 permits a predetermined expansion and contraction of the
elements. This becomes critical as hereinafter described.
In a similar manner the discharge outlet of outlets are mounted at
the bottom of the reactor which also simplifies piping and assures
adequate travel of the reactants through the reactor. A hollow cone
q uench spray nozzle 32 adjacent to outlet 30 serves to reduce the
temperature of the discharging product effluent so that any further
reaction is terminated. The quenching medium fed through nozzle 32
is preferably recycled cooled product and it is at a temperature
sufficiently different from that of the product to reduce the
effluent temperature to below about 1,200.degree. F.
In a reactor for a hydrodealkylation process which is normally
carried out at elevated temperatures and pressures, it is necessary
to have insulation. This is generally shown in detail in FIG. 7 at
36 and is supplemented by reinforcing openwork steel filled with
plastic at 38. We also find it desirable to provide a shroud or
liner 40 conveniently of stainless steel. This is preferably hung
at 40a from the plate 40d at the upper part of the reactor and is
sealed when the top 14 is added.
It is not necessary that the space 40 c between the liner 40 and
the wall 10 or the insulation 38 be pressuretight except that
normal flow of vapors is to be prevented. This is accomplished by a
suitable overlap of the lower edge of the liner 40 on the shroud
40b provided at the lower part of the reactor as indicated in FIGS.
8 and 9. Spacers 41 serve to center the shroud 40 in the shroud 40b
thus forming a slip joint.
The need for the various slip joints will be appreciated when it is
recognized that there may be as much as 11 inches of expansion
between the cold and the hot condition of the reactor.
As described in the patent hereinbefore indicated, it has been
found especially desirable with exothermic reactions such as the
hydrodealkylation of toluene, that the reaction be partially
quenched throughout the length of the reaction zone. As described
herein, we have found it preferable to quench the reactor by a
quench unit generally indicated at 42 which contains separate
vertical conduits 43.
As indicated more particularly in FIG. 5 and FIG. 6, each of the
vertical conduits 43 is blanked off as at 48 at an appropriate
horizontal location and is then in communication with a quench
distributor 45. As shown in FIG. 6, the quench distributor is
annular and has a series of holes 50 for distributing the quench
material which may be either liquid or gas at the horizontal
elevation. Cooled hydrogen gas is a preferable quench medium in a
hydrodealkylation reaction.
In a similar manner, the other vertical conduits 43 are in
communication with other quench units 44 so that an accurate
control of temperature, which is recorded by the usual temperature
reading means, can be accomplished by the control of the quench
material entering the upper part of the reactor chamber.
As shown in FIG. 10, a valve 52 is mounted on each quench line 43.
These valves are, in turn, actuated by usual controls from the
thermocouple assembly 60 shown in FIG. 1 which has a series of
stations 62 at vertical locations.
These individual quench valves 52 as controlled by the
thermocouples thus will give a shallow saw tooth temperature
profile with about a maximum 20.degree. F. temperature
difference.
While we have shown and described a preferred form of embodiment of
our invention, we are aware that modifications may be made thereto
within the scope and spirit of our description herein and only such
limitations should be made thereto as come within the terms of the
claims appended hereinafter.
* * * * *