U.S. patent number 3,589,289 [Application Number 04/604,027] was granted by the patent office on 1971-06-29 for printing members and methods for graphic composition.
This patent grant is currently assigned to Burroughs Corporation. Invention is credited to Robert L. Edsberg, Earl J. Gosnell.
United States Patent |
3,589,289 |
Gosnell , et al. |
June 29, 1971 |
PRINTING MEMBERS AND METHODS FOR GRAPHIC COMPOSITION
Abstract
Apparatus for a gravure-type printing process utilizing a
composing member having a multicellular surface pattern, and a pick
sheet coated on one side with a layer of polymer-containing,
thermoplastic material. All of the cells of the composing sheet are
initially filled with a solid material which is selectively
removable from individual cells. The cell-fill material is
specially formulated to exhibit a specific affinity for the
thermoplastic coating on the pick sheet when the coating is
activated through localized heating. Graphic representations that
are infrared absorbent are recorded on the uncoated side of the
pick sheet which is then exposed to infrared radiation while the
coated side is held in close contact with the filled cellular
surface of the composing member resulting in an adhesive attraction
between the coating and the solid material in the cells beneath the
indicia. Separation of the two elements removes the cell-fill
material from only those cells which define imaged areas
corresponding to the indicia to be reproduced. The empty cells are
receptive to filling with an ink, while nonimaged areas of the
sheet contain no printing cells, so that the composing member can
then be used as a printing master. The pick sheet, carrying a
discontinuous, raised image, comprising a multiplicity of uniformly
distributed, discrete particles of solid material bonded to the
thermoplastic coating, can be employed as a relief printing
plate.
Inventors: |
Gosnell; Earl J. (Irondequoit,
NY), Edsberg; Robert L. (Pittsford, NY) |
Assignee: |
Burroughs Corporation (Detroit,
MI)
|
Family
ID: |
25656686 |
Appl.
No.: |
04/604,027 |
Filed: |
December 22, 1966 |
Current U.S.
Class: |
101/401.1;
101/170; 101/470; 427/146; 428/207; D18/50; 101/395; 427/144 |
Current CPC
Class: |
B41M
5/46 (20130101); B41N 1/12 (20130101); B41C
1/055 (20130101); Y10T 428/24901 (20150115) |
Current International
Class: |
B41M
5/46 (20060101); B41N 1/12 (20060101); B41M
5/40 (20060101); B41C 1/055 (20060101); B41c
001/00 (); B41n 001/00 () |
Field of
Search: |
;101/395,401.1,401.2,426,150,170,401,1,33,34,376,379,453,463,470,473,128.2,471
;156/59,63 ;117/9,38,36.1,8,13,17.5,100 ;161/5,6,138,159 |
References Cited
[Referenced By]
U.S. Patent Documents
Foreign Patent Documents
Other References
Winding C. C. and Hiatt G. D.; POLYMERIC MATERIALS; McGraw-Hill
Book Co., New York, 1961; pp. 309--310.
|
Primary Examiner: Pulfrey; Robert E.
Assistant Examiner: Crowder; Clifford D.
Claims
What we claim is:
1. A composing member for use in a process for transferring an
image of indicia to be reproduced, comprising
a support having a multicellular nonmetallic printing surface
formed of uniformly distributed cells opening onto said
surface,
each of said cells being filled completely with a composing element
of solid material substantially nonabsorbing of near-infrared
radiation having a wave length in the range of from 7,500 to 30,000
Angstroms,
said composing elements being adapted to withstand repeated
exposure to fluid ink and the wiping action of a doctor blade, but
being selectively removable intact from individual cells under the
influence of localized heat treatment initiated by the application
of near-infrared radiation,
whereby said composing elements can be removed from selected cells
to define imaged areas in said surface corresponding to indicia to
be reproduced.
2. The method of making a printing plate for reproducing indicia,
comprising,
providing a support having a multicellular nonmetallic printing
surface formed on uniformly distributed cells opening onto said
surface,
filling each of said cells completely with a composing element of
solid material which is capable of withstanding repeated exposure
to a fluid ink and the wiping action of a doctor blade, but which
is selectively removable intact from individual cells under the
influence of localized treatment initiated by the application of
external agents, and
removing composing elements intact from selected cells to define
imaged area corresponding to indicia to be reproduced whereby the
emptied cells are accessible for inking.
3. The method of making a printing plate for reproducing indicia
comprising, providing a support having a multicellular nonmetallic
printing surface formed of uniformly distributed cells opening onto
said surface, each of said cells being filled completely with a
composing element of solid material which is capable of
withstanding repeated exposure to fluid ink and the wiping action
of a doctor blade, but which is selectively removable intact from
an individual cell under the influence of localized treatment
initiated by the application of external agents, bonding selected
composing elements to a layer of thermoplastic material which, when
heated to an activated temperature, has a specific adhesive
affinity for said elements and removing said bonded composing
elements from selected cells to define imaged areas corresponding
to indicia to be reproduced, whereby the cells thus emptied are
accessible for inking.
4. The method of making a printing plate for reproducing indicia
comprising, providing a support having a multicellular nonmetallic
printing surface formed of uniformly distributed cells opening onto
said surface, each of said cells being filled with a composing
element of solid material which is capable of withstanding repeated
exposure to a fluid ink and the wiping action of a doctor blade,
but which is selectively removable from individual cells under the
influence of localized treatment initiated by the application of
external agents, providing a layer of thermoplastic material which
when heated to an activated temperature has a specific affinity for
said composing elements, raising selected areas of said layer of
thermoplastic material to an activated temperature by localized
heat treatment initiated by the application of infrared radiation,
bonding composing elements from selected cells to said layer of
thermoplastic material, and removing composing elements from said
selected cells to define imaged areas corresponding to indicia to
be reproduced, whereby the cells thus emptied are accessible for
inking.
5. The method of making a relief printing member, which comprises,
providing a composing member comprising a nonmetallic support
having a multicellular composing surface formed of substantially
uniformly distributed cells opening onto said surface, each of said
cells being completely filled with an indicia-composing element of
solid material substantially nonabsorbing of near-infrared
radiation having a wave length in the range of from 7,500 to 30,000
Angstroms which is selectively removable intact from individual
cells, providing a stream of polymer-containing thermoplastic
material, and bonding an array of composing elements from selected
cells of said composing member to the surface of said stratum to
form a discontinuous raised image consisting of a multiplicity of
spaced, minute, protuberances uniformly distributed over the areas
defined by said image.
6. A method in accordance with claim 5, wherein each of said cells
is filled with a solid material having a specific bonding affinity
for a thermoplastic material under the influence of localized heat
treatment initiated by the application of infrared radiation.
7. The method of making a relief printing member, which
comprises
providing a composing member comprising a support having a
multicellular composing surface formed of substantially uniformly
distributed cells opening onto said surface,
filling selected cells with indicia-composing elements of solid
material which are removable from said cells under the influence of
localized treatment, to form an arrayment of indicia-composing
elements defining an image to be printed,
providing a stratum, transferring said arrayment from the filled
cells to the surface of the stratum, and simultaneously
bonding each individual element to said stratum to form a
discontinuous raised image consisting of a multiplicity of spaced,
minute protuberances uniformly distributed over the area defined by
said image.
8. The method of making a relief printing member, which
comprises
providing a recording medium having opposed record and printing
faces,
said printing face having thereon a coating of polymer-containing
thermoplastic material which is solid below 40.degree.C.,
recording on said record face graphic representations that are
infrared absorbent,
applying to the surface of said printing face, at least in areas
opposite the graphic representations on said record face, a
monolayer of discrete particles of solid material each having
essentially the same dimensions and shape, and
subjecting the recording medium to infrared radiation for a period
of time sufficient to bond said particles to said thermoplastic
coating and form a discontinuous raised image corresponding to the
graphic representations of the opposed record face.
9. A method in accordance with claim 8, wherein said recording
medium comprises a web, one face of which is coated with a
film-forming thermoplastic material.
10. A method in accordance with claim 8, wherein said recording
medium comprises an original sheet of thin, lightweight paper.
11. A method in accordance with claim 8, wherein said recording
medium comprises a heat-transmitting synthetic polymeric film.
12. A composing unit for use in a thermographic process comprising,
in combination,
a support having a multicellular printing surface formed of
uniformly distributed cells opening onto said surface,
indicia-composing elements of solid near-infrared transmitting
material filling each of said cells,
each of said elements being adapted to withstand repeated exposure
to a fluid ink and the wiping action of a doctor blade without
dislodgment from said cells, but each being selectively removable
intact from individual cells under the influence of localized
treatment,
a heat transfer original sheet having an indicia-receiving
surface,
a substantially infrared transparent coating on the back of said
sheet comprising a polymer-containing thermoplastic material having
a latent specific affinity for the solid material filling said
cells
said support and said original sheet being assembled with said
coating of thermoplastic material operatively associated with said
indicia-composing elements in said cells,
whereby infrared-absorbent indicia placed on said original sheet
can be heated preferentially to raise the temperature of the
thermoplastic material to an active state in areas directly
underlying said indicia, so that, upon separation of the original
sheet from the multicellular surface, composing elements from cells
defining imaged areas corresponding to the indicia to be reproduced
are selectively removed from the multicellular surface and are
bonded to the coating on said original sheet which is thereby
adapted to function as a relief printing member and whereby said
support is thereby adapted to function as an intaglio printing
member.
13. The composing unit of claim 12, wherein the solid material of
said composing elements is a composition having a specified bonding
affinity for a heat-softened thermoplastic material.
14. The composing unit of claim 2, wherein the solid material of
said composing elements is a meltable resin.
15. The composing unit of claim 12, wherein the solid material of
said composing elements is a fused plastisol.
16. The composing unit of claim 12, wherein the solid material of
said composing elements is a cross-linked thermoset polymer.
17. The composing unit of claim 12, wherein the solid material of
said composing elements consists of a mixture of thermoplastic and
thermosetting materials.
18. The composing unit of claim 12, wherein said support is formed
of a synthetic plastic.
19. The composing unit of claim 12, wherein said support is a
polypropylene sheet.
20. The composing member of claim 12, wherein said multicellular
surface contains in the range of from 10,000 to 160,000 individual
cells per square inch substantially uniformly distributed over said
surface, all said cells being of substantially the same depth and
having a depth in the range of from about 10 to 50 microns, and
wherein said cells are substantially uniformly separated from each
other by the cell walls of the composing member with a separation
in the range of from about 2 to 20 microns.
21. The composing member of claim 12, wherein all of the cells have
substantially the same shape and dimensions.
22. The composing unit of claim 12, wherein said original sheet
comprises a sheet of thin, lightweight paper coated on one side
with a film-forming, polymer-containing, thermoplastic
material.
23. The composing unit of claim 12, wherein said original sheet
comprises a heat-resistant, near-infrared-transmitting, synthetic
polymeric film coated on one side with a coating of film-forming,
polymer-containing, thermoplastic material.
24. The composing unit of claim 12, wherein said coating has a
thickness in the range of about 0.05 to 2.0 mils.
25. The composing unit of claim 12, wherein said thermoplastic
material has an activation temperature above 50.degree. C.
26. The method of composing indicia to be reproduced,
comprising,
providing a composing member comprising a support including a
cellular printing surface formed of a multiplicity of uniformly
distributed cells opening onto said surface, each of said cells
being filled with an indicia-composing element of solid
near-infrared-transmitting material which is capable of
withstanding repeated exposure to a fluid ink and the wiping action
of a doctor blade, but which is selectively removable intact from
individual cells under the influence of localized treatment,
providing an original sheet having an indicia-receiving surface,
the back of said sheet being provided with a coating of a
polymer-containing, thermoplastic material,
said coating being adapted to bond, in areas underlying indicia
placed upon said receiving surface, to the exposed surface of
indicia composing elements filling the cells of the composing
member, when the coated surface of the original sheet is placed in
contact with the cellular printing surface of the composing member
under the influence of localized heat and pressure,
recording indicia on the receiving surface of said original sheet
to produce graphic representations highly absorptive of infrared
rays,
superposing the indicia-bearing original sheet and the composing
member,
exposing the superposed original sheet and composing member to
infrared radiation to activate said coating in areas underlying
said indicia, and
separating the original sheet from the composing member to thereby
remove composing elements from selected cells defining imaged areas
corresponding to the indicia to be reproduced, whereby said
composing member is adapted to function as an intaglio printing
member and said original sheet is adapted to function as a relief
printing member.
27. A method in accordance with claim 26, wherein said
indicia-bearing original sheet is exposed to an infrared source
producing radiation in the range of from about 10,000 to 20,000
angstroms.
Description
SUMMARY OF THE INVENTION
This invention relates to materials and processes useful in the
field of graphic arts. More particularly, it relates to a
simplified gravure plate-making procedure, a method of composition
for office duplication, and to printing plates of both intaglio and
relief image type, which are produced thereby.
Presently used methods of duplicating typewritten copy in offices
are through the use of transfer papers such as carbon paper,
pressure-sensitive papers, spirit duplicating, mimeograph, offset
duplicating, electrostatic duplication, thermography, diffusion
transfer, dye-gelatin transfer, diazo duplication and photoelectric
facsimile duplication.
Most, if not all, of such previously known processes have one or
more rather serious disadvantages or deficiencies such as severe
limitations on the number of copies obtainable, slow duplication
speed, the necessity for handling chemicals such as highly colored
transfer coatings or printing inks, the complexity of the
duplicating process requiring skilled operators, high equipment
cost, difficulties in correcting errors on plates or masters, and
the necessity for the use of special copy papers.
Heretofore, the good quality of print obtainable and the simplicity
of the printing operation has made the photogravure process
attractive for duplication uses. However, the principles of gravure
printing have never been adopted for shortrun duplication because
of the great complexity and high cost of the photographic and
etching processes necessary for producing intaglio printing plates
or cylinders.
Accordingly, it is an object of the present invention to provide
novel thermographic materials and methods which overcome many of
the disadvantages of prior-art methods of office duplication and
offer advantages heretofore available only in gravure printing
processes and materials. More specific objects are to provide
methods for composing intaglio images suitable for use in gravure
printing and for producing printing reliefs suitable for use as
letterpress printing plates and the like. A further object is to
provide such methods which utilize economical materials in
convenient process steps. Other objects, features, capabilities and
advantages which are comprehended by the invention will be apparent
from the description and claims which follow.
Briefly, the present invention includes a composing member
comprising a support having a multicellular printing surface formed
of uniformly distributed cells opening onto the surface and
indicia-composing elements of solid material filling each of the
cells, which elements are selectively removable from individual
cells. A recording medium, termed herein a "picksheet," carrying
the graphic representations to be reproduced is coupled with the
composing member and the cellular material is removed from selected
cells to define imaged areas in the cellular surface corresponding
to indicia to be reproduced. The empty cells are receptive to
filling with a gravure ink while nonimaged areas of the cellular
surface contain no printing cells, so that the composing member can
be used as a printing master. When provision is made to transfer
the indicia-composing elements removed from the cellular surface to
the surface of a stratum where such elements are bonded in orderly
array, there is produced a relief printing member comprising a
discontinuous raised image consisting of a multiplicity of spaced,
minute protuberances uniformly distributed over the areas defined
by the image.
BRIEF DESCRIPTION OF THE DRAWING
Objects and advantages of the present invention will become more
apparent from a consideration of the following specification and
claims, when taken in conjunction with the accompanying drawing,
wherein:
FIG. 1 is a diagrammatic view of a composing unit showing a pick
sheet coupled with a composing member to produce a composed
printing plate in accordance with one embodiment of the present
invention;
FIG. 2 is an enlarged fragmentary view of a portion of the printing
plate of FIG. 1, showing the emptied cells inked for printing;
FIG. 3 is an enlarged, fragmentary, cross-sectional view of a
printing plate taken along the line 3-3 of FIG. 2;
FIG. 4 is an enlarged cross-sectional view of a pick sheet taken
along the line 4-4 of FIG. 1, showing the discontinuous raised
image bonded to the coated side of the pick sheet opposite indicia
placed on the recording surface of the sheet;
FIG. 5 is an enlarged fragmentary view of a portion of the raised
image carried by the pick sheet shown in FIG. 1;
FIG. 6 is a side elevational view of a pick sheet coupled with a
composing member during the process of composing indicia to be
reproduced;
FIG. 7 is an enlarged plan view of a portion of the composing
member shown in FIG. 1 after composition has been completed and the
two sheets have been separated; and
FIG. 8 is an enlarged side elevational view of another embodiment
of the present invention.
DETAILED DESCRIPTION OF THE INVENTION
The Composing Member
Apparatus used in the practice of the present invention includes a
composing member, which may be in the form of a sheet, cylinder,
plate, belt, or the like, comprising a support having a
multicellular printing surface formed of uniformly distributed
cells opening onto the surface, and indicia-composing elements
formed of solid material which fill each of the cells and which are
selectively removable therefrom under the influence of localized
treatment initiated by the application of external agents. By
removing composing elements only from selected cells, imaged areas
which correspond to indicia to be reproduced are formed in the
cellular surface.
Preferably, the multicellular printing surface is formed on a
moldable support made of a solid nonmetallic material which is not
deformable at temperatures used in practicing the invention, such
as for example, a synthetic plastic. The material of the cellular
surface must be tough, resistant to scratching or marring during
processing operations and essentially chemically inert to other
substances used in the composing or printing processes of the
invention. Also this material should have a low coefficient of
friction across its surface to facilitate the movement of a doctor
blade thereacross. In addition, it must have a bonding affinity for
the solid material filling each of the cells so that selected
indicia-composing elements can be removed from the composing member
while the remainder will remain firmly secured in the cellular
surface during the operation of the invention.
Referring now to the drawing, and more particularly to FIG. 1, for
purposes of illustration there is shown diagrammatically a
composing unit for use in a thermographic process which comprises,
in combination, a composing member 10 combined with an overlying
pick sheet 40 to form an assembly in which the two elements
utilized in the composing process are coupled together at a common
edge 11. In this embodiment the composing member 10 is shown as a
generally rectangular sheet of plastic having a multicellular
surface 20 of individual cells each initially filled with a solid
material 25. The assembly also includes a pick sheet 40 consisting
of an original sheet 42 of paper or the like coated with a coating
45 of polymer-containing, thermoplastic material having a latent
specific affinity for the solid material 25 filling the cells of
the composing member. The two elements are assembled with the
coating 45 of thermoplastic material operatively associated with
the solid material in the filled cells 20, whereby infrared
absorbent indicia 64 placed on the original sheet 42 can be heated
preferentially to raise the temperature of the thermoplastic
coating 45 to an active state in areas underlying the indicia, so
that, upon separation of the original sheet 42 from the
multicellular surface 20, solid material 25 from cells defining
imaged areas 15 corresponding to indicia to be reproduced are
selectively removed from the multicellular surface and are bonded
as a raised image 15' to the coating 45 on the original sheet which
is thereby adapted to function as a relief printing member and
whereby said composing member is thereby adapted to function as an
intaglio printing member.
Suitable plastic sheet is made from one or more of the following
resins which may be modified with plasticizers or other modifying
agents in accordance with conventional plastics technology:
1. acrylic resins, i.e. thermoplastic polymers or copolymers of
acrylic acid, methacrylic acid, esters of these acids, or
acrylonitrile, e.g. polymethylmethacrylate.
2. cellulose resins, e.g. ethyl cellulose, cellulose acetate,
cellulose acetate butyrate, and cellulose acetate propionate.
3. polyolefins e.g. polyethylene, polypropylene and copolymers
thereof.
4. polyamides formed by the polymerization of amino acids or by the
condensation of polyamines with polycarboxylic acids, e.g.
nylon.
5. polycarbonates which are resins produced by reacting polyphenols
such as bisphenol A with phosgene, e.g. Lexan.
6. vinyl polymers and copolymers of vinyl acetate and vinyl
chloride.
7. polystyrene
8. polyformaldehyde resins derived by the polymerization of
anhydreous formaldehyde in a hydrocarbon solvent with the aid of an
ionic catalyst.
Preferably, the composing member will be made from a synthetic
plastic sheet material having a thickness of at least 0.003 inch.
Advantageously, polypropylene or cellulose acetate sheet materials
having a thickness in the range of about from 0.005 to about 0.040
inch will be employed. Utilizing a master matrix or mold of a
screened cellular pattern, plates, cylinders or belts made from
thin synthetic plastic sheet material can be prepared by continuous
or even automated processes involving compression molding the
overall cellular pattern of any predetermined screen size and depth
into the plastic film or sheet surface. In accordance with the
present invention the multicellular surface 20, contains in the
range of from about 10,000 to about 160,000 individual cells per
square inch uniformly distributed over the surface. As is more
clearly shown in FIG. 3, all of the cells are substantially the
same depth and have a depth in the range of about from 10 to 50
microns. Each of the cells are uniformly separated from each other
by the cell walls 24 of the composing member with a separation in
the range of about 2 to 20 microns. In a preferred embodiment all
of the cells will have substantially the same shape and dimensions
although it is understood that a pattern of variable-shaped cells
can be utilized. The plastic sheet material having a multicellular
printing surface is to all intents and purposes a gravure printing
member which when all the cells are empty would print as a solid,
overall color by virtue of the fact that all of the cells in the
printing surface are receptive to filling with ink.
According to the invention, all of the cells forming a cellular
printing surface on a composing member are filled with
indicia-composing elements 25 of solid material which are
selectively removable from individual cells under the influence of
localized treatment initiated by the application of external
agents. The composing elements must adhere to the inner cell wall
surfaces under normal conditions of use of the composing member,
but can be removed from selected cells under special conditions to
create imaged areas 15 in the printing surface consisting of empty
cells 26 which are than available for inking. In preferred
embodiments, the composing elements 25 are adapted to withstand
repeated exposure to a fluid ink and the wiping action of a doctor
blade without dislodgment from the cells in which they are
contained.
In broad scope, any solid material capable of meeting the above
requirements can be utilized as a suitable cell-fill material in
the fabrication of composing members in accordance with the present
invention. Preferably, the material used to fill the cells is a
viscous essentially nonvolatile organic fluid dispersion having a
high solids content which can be knife coated over the
multicellular surface and which is capable of being hardened after
deposition in the cells. It should also be thixotropic so that it
can hold a predetermined shape during the preparation of the
composing member. It should have a hardening temperature below the
distortion point of the material of the cellular surface in which
it is to be cast and should maintain a stable viscosity over
prolonged storage periods. After hardening the cell-fill material
must be tough. Further it must exhibit minimum shrinking during
hardening and thereafter be resistant to extraction of its
components by the ink used in the ultimate printing operation and
by the materials used to clean the printing surface. Suitable
organic materials include meltable resins, fused plastisols,
cross-linked thermoset polymers and mixtures of these. The
preferred material in accordance with this invention is a fused
vinyl plastisol.
For present purposes, a "plastisol" is defined as a paste
dispersion of one or more resins in a suitable liquid plasticizer
and optionally containing other ingredients such as stabilizers,
fillers, wetting agents, gelling agents and the like. Resins
employed include polyvinyl chloride or polyvinylidene chloride, or
copolymers of these. Polyethylene possessing an extremely fine
(approximately 1 micron) particle size is also suitable. The
plasticizer at room temperature is a nonaqueous liquid that does
not dissolve the resin. At an elevated temperature the resin
undergoes solvation and goes into solid solution in the
plasticizer. Obviously, any equivalent composition which meets the
requirements of the present invention is to be included in this
definition. Since plastisols become solid solutions at relatively
moderate temperatures, fusing can be carried out uniformly by any
suitable heating technique by which the temperature and time of
fusing can be accurately ascertained and controlled.
In the present invention, a preferred primary resin for use in
preparing a suitable plastisol is polyvinyl chloride (PVC) having a
molecular weight of more than about 10,000, preferably soap free
and finely divided having a particle size in the micron and
submicron range. The term "polyvinyl chloride" as used herein is
inclusive not only of polyvinyl chloride homopolymers of all types,
but also of copolymers of vinyl chloride, such as copolymers of
vinyl chloride and vinyl acetate, copolymers of vinyl chloride and
vinylidene chloride, copolymers of vinyl chloride with maleic or
fumaric acid esters, copolymers of vinyl chloride with styrene, and
copolymers of vinyl chloride with acrylonitrile, as well as
mixtures of polyvinyl chloride resins in a major proportion with a
minor proportion of other synthetic resins conventionally used to
modify vinyl dispersions, such as chlorinated polyethylene, or
copolymers of acrylonitrile, butadiene and styrene.
The viscosity and flow characteristics of the plastisol are
dependent upon the nature of the particular resin, the plasticizing
or solvating efficiency of the plasticizers employed, the
plasticizer concentrations, the quantity and type of fillers, and
the stabilizer system used. Of all the components mentioned, the
plasticizers appear to exert the largest influence on plastisol
viscosity and flow behavior. It has now been found that the type
and concentration of plasticizers employed can be selected to
achieve optimum degrees of viscosity, thixotropy, cohesiveness and
infrared radiation reflectance, while at the same time producing a
fused plastisol having a specific bonding affinity for a specific
thermoplastic material.
Plasticizers employed in plastisol formulations should have
negligible volatility at the fusion temperature of the plastisol,
favorable viscosity so that the other components can be added
without affecting adversely the workability of the plastisol, and
be a good solvent for the plastisol resin at fusion temperature,
yet must provide viscosity stability for considerable periods at
room temperature.
In accordance with the present invention the primary plasticizing
component of the vinyl plastisols preferably consists essentially
of a major proportion of a monomeric plasticizer pivoted from the
class consisting of simple esters and mixtures thereof capable of
solvating vinyl dispersions at a temperature which is less than
160.degree. C., in admixture with a minor but shrinkage-reducing
proportion of a polymeric plasticizer.
Suitable monomeric plasticizers include citrate esters such as
acetyl tributyl citrate; phthalate esters such as dioctyl, butyl
benzyl, dibutoxyethyl, and diisodecyl phthalate; phosphate esters
such as octyl diphenyl, tris (dichloropropyl), and cresyl diphenyl
phosphate; adipate esters such as benzyl octyl adipate; azelate
esters such as di-2-ethyl hexyl azelate; sebacate esters such as
dibenzyl sebacate; dibenzoate esters such as dipropylene glycol and
hydrogenated terphenyl dibenzoate. Suitable polymeric plasticizers
include polyesters such as Harflex 340 and epoxidized oils such as
Plastolein 9717 and Paraplex G-62.
Generally, the plastisol will contain from about 45 to about 80
parts by weight of the primary plasticizing component per hundred
parts by weight of primary resin, depending upon the particular
plasticizer, the particular resin and the particular properties
desired in the final product.
Stabilizers, conventional fillers, thickening agents and surface
active agents, if employed, can be used in minor quantities, in
accordance with conventional procedures. Where any particular color
is desired, pigments having a relatively high refractive index are
preferred so as to provide opacity to the material filling the
cells. Particles of pigment filler in amounts in the range of from
about 1 to 15 weight percent also assist in providing hardness and
cohesiveness after the plastisol has been fused.
Stabilizers in amounts up to about 1.5 weight percent can be used
to prevent heat deterioration of the plastisol during processing
Suitable stabilizers include metal salts of organic acids such as
lead carbonate, barium-cadmium laurate and stearate, zinc laurate,
zinc stearate, as well as organic tin compounds, epoxies, organic
phosphites and chelators. Conventional thickening agents, such as,
the colloidal silicas and aluminum silicates are generally employed
to provide thixotropy and other necessary rheological
characteristics to the composition prior to fusion. Preferably,
from about 0.3 to 8 weight percent of thickening agent will be
utilized.
Advantageously, about 0.3 to 3 weight percent of a suitable surface
active agent will be incorporated into the plastisol composition.
Such agents promote the particulate dispersion of resin and pigment
in the liquid plasticizer phase by destroying the tendency of the
small particles to cluster together. These surfactants also help to
stabilize viscosity and by lowering the interfacial tension between
plasticizer and air bubbles, aid in the removal of entrapped air
from the plastisol. Because the surface characteristics of the
various primary resins used in plastisol formulations are often
quite different, it may be necessary in some instances to
experiment with various anionic, cationic and nonionic surfactants
in order to select the proper agent to obtain the optimum effect.
However, the polyglycol ethers and esters of fatty acids have been
found to be generally effective with any of the resins referred to
above.
The method of formulating the organic material used to fill the
cells of the composing member, is in accordance with conventional
practice. If a vinyl plastisol is utilized, a preferred method
involves the use of a shear-type mixer having a cooling jacket to
prevent excessive buildup of heat which might cause premature
solidification of the plastisol. Generally the resin is added to
the mixing apparatus first, after which a quantity of plasticizer
is added slowly, with agitation. The filler and other modifying
agents are generally disbursed in the remainder of the plasticizer
and added to the mixture in that manner. The components are then
mixed until the plastisol is homogeneous and a stable emulsion or
dispersion formed. Alternatively, the entire amount of plasticizers
can be combined with the resin and the additional fillers,
stabilizers and the like can then be added as finely divided
solids. Deaeration is accomplished in accordance with conventional
practice through the application of vacuum on a thin layer of
plastisol or on a larger scale by mastication of the mixture on a
three-roll paint mill.
In accordance with this invention a semifluid plastisol composition
is formulated to achieve optimum degrees of viscosity, thixotropy,
cohesiveness and infrared radiation reflectance. The composition is
doctored across the cellular surface of the plastic sheet 10 to
fill each cell so that its meniscus is convex without coating the
surfaces of the surrounding cell walls 24. Thereafter, the plate or
cylinder with its plastisol filled cells is subjected to a
temperature sufficient to permit fusion of the resin. The required
fusion temperature will depend upon the particular components of
the plastisol and the mass of material in each cell, but it is
generally of the order of about 160.degree. C. or less. Exposure of
the plastisol filled cells to the fusion temperature for a
sufficient period of time results in plastisol fusion to a solid
mass and a slight shrinkage of the plastisol in each cell so that
its surface is plane with the surrounding cell wall surfaces.
Generally a heating period of from about 1 to 5 minutes will be
required depending upon the formulation and the temperature
employed.
The Pick Sheet
The apparatus of the present invention also includes a recording
medium which conveniently can be termed a pick sheet. In one
embodiment of the invention the pick sheet is used with the
composing member 10. As shown in FIGS. 1 and 4, the recording
medium 40 comprises an original sheet 42 having an
indicia-receiving surface 44. In accordance with the invention the
back of the sheet carries a coating 45 of polymer-containing
thermoplastic material having a latent specific affinity for
specific indicia-composing elements 25 and is adapted to bond to
the solid material of the composing elements when the thermoplastic
material 45 is activated at selected sites under the influence of
localized heat treatment. The original sheet 42 can be composed of
any suitable heat-resistant, near-infrared nonabsorbing material
such as for example a synthetic plastic film or a thin, lightweight
paper capable of being coated on one side with a film of
polymer-containing thermoplastic material.
The original sheet 42 shown in FIGS. 1 and 4 is a thin sheet of
paper of sufficient density to provide heat transfer but having
sufficient rigidity or stiffness that it will handle well in a
typewriter. For example, it has been found that a well-calendered
11-pound paper is suitable, this paper being defined as one of
which 500 17.times.22-inch sheets will weigh 11 pounds. In this
example the thickness of the sheet generally will be of the order
of 0.002 inch. Carbonizing tissue of the dense type can also be
used in a sheet having a thickness of for example about 0.0016 or
0.0017 inch.
Preferably, the polymer-containing thermoplastic material 45 will
be coated on one side of the recording medium 40 in a thickness in
the range of from about 0.05 to about 2.0 mils and more preferably
in the range of from about 0.1 to 1.0 mils. This thermoplastic
material is formulated to have a latent specific affinity for the
solid material 25 filling the cells of the composing member 10 and
is adapted to bond thereto when heated to activated i.e. tacky,
temperature. Generally, thermoplastic material having an activation
temperature above 50.degree. C. will be employed. Broadly, any
polymer-containing thermoplastic material having a specific bonding
affinity at its tackifying temperature for the cell-fill material
can be employed in accordance with this invention. Illustrative of
suitable thermoplastic coating material is polyvinylacetate,
cellulose acetate butyrate, homo and copolymers of polyvinyl and
polyvinylidene chlorides, and ethyl cellulose.
A preferred thermoplastic resin is cellulose acetate butyrate which
is a thermoplastic resin formed by the reaction of purified
cellulose with acetic and butyric anhydrides in the presence of
sulfuric acid as catalyst and glacial acetic acid as solvent. This
resin is commercially available in the form of white flakes or
granules readily convertible into a plastic film. The ratio of
acetic and butyric components can be varied over a wide range to
tailor desired physical properties. A preferred thermoplastic resin
which can be utilized in accordance with the present invention, is
a cellulose acetate butyrate having the following approximate
composition:
combined cellulose residue 46 percent
free hydroxy in cellulose residue 0.7 percent
combined butyryl 48 percent
combined acetyl 6 percent
This material having a softening point in the range of from
165.degree.--175.degree. C. is marketed by Tennessee Eastman
Corporation under the trademark EAB 500-1.
The resinous material of which the thermoplastic coating is formed
may be modified with softeners, plasticizers or the like to provide
for a softening point within the temperature range of 50.degree. to
200.degree. C. It will be understood that where the conditions for
developing higher temperatures are achieved, the softening range of
suitable thermoplastic material may be correspondingly broadened or
moved upwards.
Suitable plasticizers, softeners and the like for specific resinous
materials can be selected readily by those skilled in the art from
the data available in the plastics and resins fields. For example,
polyvinyl chloride and vinyl chloride-vinyl acetate copolymers can
be plasticized with dibutyl phthalate, diamyl phthalate, dioctyl
phthalate, dibutyl cellosolve phthalate, tricresyl phosphate and
triglycol di-(2 ethyl hexanoate). Polyvinylidene chloride may be
plasticized to the desired degree with any one of a number of
plasticizers or combinations thereof such as polychloro biphenyl,
dibenzyl ether, tricresyl phosphate, and the like. Acrylic acid
ester polymers, such as butyl methacrylate, ethyl acrylate, methyl
methacrylate and the like may be plasticized with dibutyl
phthalate, dibutoxy ethyl phthalate, chlorinated biphenyl,
tricresyl phosphate, and the like. Amounts up to about 30 percent
by weight, based upon the weight of the resin, may be successfully
used with the above resins to impart the desired results.
The polymer-containing thermoplastic material can be coated on a
paper or plastic sheet using conventional coating methods.
Generally, the thermoplastic resin will be applied to the sheet 42
in a solvent solution. Suitable solvents include methylethyl
ketone, acetone, methyl, ethyl, and isopropyl alcohols, toluene,
xylene, esters such as methyl, ethyl, and isopropyl formates and
acetates, and the like, low boiling point chlorinated aliphatic
solvents such as methylene chloride, trichloroethylene and the like
and low-boiling glycol ethers. Generally the coating will be
sufficient to increase the weight of an 11 pound paper by about 1
to 5 pounds.
METHOD OF OPERATION
The novel process of the instant invention is more fully
illustrated by the following examples which are given for
illustrative purposes only and are not to be construed as limiting
in any way the scope of the present invention.
The basic unit of this gravure duplicating discovery is the
composing member used for transferring the image. Initially, a base
plate is prepared by etching or molding an overall cellular pattern
into sheets of flexible material such as plastic, metal,
impregnated paper, fabric, or the like. In this example a plastic
base plate was prepared from a 10 mil sheet of nonoriented
polypropylene, one surface of which had an overall cellular pattern
consisting of 90,000 cells per square inch. In order to produce the
cellular printing surface a 300-line gravure screen was
photographically transferred to a rigid copper photoengraving plate
and chemically etched to a depth of 25 microns. Cell walls having a
thickness of 28 microns in the film positive were reduced by the
etching to approximately 10 microns. The master plate was then used
to produce a phenolic resin matrix by compression molding and the
matrix in turn similarly was used to produce the molded cellular
pattern in the polypropylene sheet.
Each of the cells of the multicellular surface was then filled with
an indicia-composing element of solid material 25 which is
selectably removable from individual cells. The solid material in
this example was a fused plastisol especially formulated to impart
the desired chemical and physical properties to the finished
composing member. The essential constituents of a suitable
plastisol formulation are given below: ##SPC1##
In this example, the auxiliary resins vinyl toluene copolymer and
vinyl toluene acrylate copolymer were mixed with the octyl diphenyl
phosphate plasticizer and dissolved at approximately 120.degree. C.
After cooling, the polyester resin and the surface active agent
were blended into the mixture. Thereafter, the polyvinylchloride
resin was added with stirring and finally the titanium dioxide
filler and the silica pigment thickening agent were blended into
the mixture. The final mixture was ground on a three-roll mill to
achieve optimum dispersion and to eliminate entrapped air.
The semifluid plastisol composition was then doctored across the
cellular surface of the polypropylene sheet to fill each cell so
that its meniscus was convex without coating the surfaces of the
surrounding cell walls. This can be accomplished by using a
beveled, stainless steel doctor blade designed so that the angle
between the lower surface and the upper surface of the beveled
portion of the blade is approximately 35.degree.. The lower surface
of the doctor blade should be oriented at an angle of approximately
30.degree. to the cellular surface.
After all of the cells had been filled with the plastisol
composition the composing member was heated to a temperature in the
range of about 300.degree. to 380.degree. F. for about 1 to 5
minutes during which time the resin components were completely
solvated and fused. When the filled plastic sheet was subsequently
cooled, the quantities of plastisol had solidified and shrunk so
that each had a substantially flat surface which was level with the
surface of the sheet. In addition, each quantity of plastisol had
good mechanical adherence to the depressed surfaces of the cell in
which it was seated.
The composing member is converted into a printing plate for
transferring an image simply by removing the solid material 25 from
selected cells to define imaged areas 15 in the surface 20
corresponding to indicia 64 to be reproduced. The term "image" is
used herein to designate any form of graphic representations, such
as writing, lettering, pictures, designs, etc. Creation of such
images by removal of selected indicia-composing elements can be
accomplished in any desired manner so long as the composing
elements which are left in place 25 are not disturbed and will
continue to adhere to the walls of the cells in which they are
contained under normal conditions of use of the composing member as
a printing plate. Preferably of course, the composing elements
which remain in the printing plate will be able to withstand
repeated exposure to an ink and the wiping action of a doctor blade
without dislodgment from the cell. Following composition, the
composed printing plate can be secured by any suitable means in a
flat bed press or curved over the plate cylinder of a rotary press
and secured thereto by suitable fastening means. As previously
mentioned, the flexibility of the printing member depends largely
upon the material employed as the support.
In a preferred embodiment of the present invention the composing
member described above is converted into a printing plate utilizing
a recording medium 40 comprising an original sheet 42 coated on one
side with a coating 45 of polymer-containing, thermoplastic
material, which has a latent specific affinity for the solid
material 25 filling the cells of the composing member and is
adapted to bond thereto when the thermoplastic material is raised
to its activated, i.e., bonding, temperature.
A suitable recording medium is fabricated in accordance with the
following procedure. A well-calendered, 11-pound paper in which
each sheet was approximately 2 mils thick was coated with a solvent
solution of the cellulose acetate-butyrate resin previously
described. The coating solution was formulated by mixing 25 weight
percent of cellulose acetate-butyrate with 25 weight percent of
heptane and 50 weight percent of ethyl acetate. Solutions of the
above composition together with from about 10 to 30 weight percent
(based upon the weight of the thermoplastic resin) of dibutyl
phthalate have been successfully employed to produce suitable
coatings in accordance with the present invention. The coatings
were applied by conventional techniques including reverse roll,
knife overroll, or the air knife process. The dried coatings were
nonblocking and nontacky at ambient temperatures but exhibited a
specific adhesive attraction to the plastisol cell-fill material at
elevated temperatures while exhibiting essentially no attraction
for the material of the composing member.
The thermoplastic resin coated recording medium produced according
to the method outlined above can then be used to image a suitable
composing member in the following manner. The indicia or copy 64 to
be reproduced is typed, written or printed on the uncoated side 44
of the recording medium 40 using graphic representations that are
infrared absorbent. In this embodiment the ribbon, printing ink or
writing material composition must contain a substantial amount of
carbon, metallic pigment or other infrared absorbing substance. The
printed recording medium, from which it is desired to produce a
master sheet, is then placed coated side down over a
plastisol-filled gravure plate or cylinder so that the
thermoplastic coating 45 of the original sheet is in contact with
the plastisol filled cells 20 of the gravure plate or cylinder. The
printed surface 44 of the assembled composing unit 60 is then
subjected to infrared radiation 62 in the manner exemplified by
FIG. 6 of the drawing.
Radiant energy capable of the phenomenon of heat generation upon
absorption in the materials comprising the representations 64
placed on the recording medium can be derived from the light
sources rich in infrared which includes sources producing rays
having a wave length in the range of from about 7,500 to 30,000
angstroms. These are above the visible range but below the extreme
end of the infrared range. Radiant energy capable of the phenomenon
of the type described may be found in the rays of the sun and
therefore exists in ordinary daylight. However, they can only be
developed in sufficiently high concentration by infrared sources
such as a tungsten filament in a glass bulb or quartz tube
operating at 3,000.degree.--4,000.degree. F. Most advantageously,
an infrared source producing radiation in the range of from about
10,000 to 20,000 angstroms will be utilized. The amount of heat
developed depends chiefly upon the duration of exposure and the
intensity of the usable radiant energy of the infrared-emitting
source. It also depends upon the depth and character of the
material in which it is formed. In this example, preferably the two
components, the composing member 10 and the recording medium 40,
will be held in close contact with each other as for example by the
use of pressure, such as can be supplied by the use of a roller and
a tightly tensioned, infrared transparent belt or tape. A
satisfactory source of radiation and pressure is a conventional
thermo-type copier.
After an exposure time of from about 2 to 10 seconds the composing
unit 60 is removed and the two components separated at which time
it will be seen that the plastisol component 25 of each composing
member cell, which was directly under an infrared-absorbent
character 64 on the surface 44 of the recording medium 40, has been
removed and is now adhering tightly to the coated side of the
recording medium 40. As is shown in FIG. 1, the indicia facing the
infrared source have been copied as direct-reading images 15 in the
multicellular surface of the composing member 10. At the same time,
as best illustrated in FIGS. 4 and 5, the indicia facing the
infrared source have been copied in reverse on the coated side of
the recording medium in the form of a discontinuous raised image
15' comprising a multiplicity of minute protuberances 46 uniformly
distributed over the areas defined by the image.
In the above example, the infrared radiation does not generate heat
until it is absorbed by the representations 64 on the indicia
receiving surface 44 of the original sheet 42. Therefore, if the
infrared radiation is directed onto the original sheet which is in
surface contact with the plastisol-filled cells of the composing
member 10, the radiation is absorbed by the representations of the
original sheet and converted into heat only in the indicia. The
heat generated by the absorbed radiation in the indicia penetrates
the recording medium to the underlying layer of thermoplastic
material 45 which is heated to its bonding temperature in areas
corresponding to the indicia areas of the top surface of the
recording medium. The cells in the printing surface of the
composing member which define the imaged areas to be reproduced are
now empty and receptive to filling with a gravure ink while the
nonimaged areas of the composing member effectively contain no
printing cells. The composed member can then be mounted in a
gravure offset press or duplicator or the like designed to flood
the cell surface with ink, doctor the surface to remove all excess
ink from nonprinting areas, transfer the ink image to a rubber or
other transfer roll, and then transfer the ink image to a sheet or
web of copy paper. FIG. 2 illustrates diagrammatically, such a
printing plate in which the empty cells have been filled with ink
27 in preparation for printing.
Following separation of the two components, the recording medium
used to remove cell-fill material from selected cells of the
composing member can be used directly as a relief printing plate.
In this case the printing plate comprises a multiplicity of
discrete, indicia-composing elements of preselected shape 46,
bonded to the surface of a suitable substrate to define a
discontinuous, raised image 15', corresponding to indicia 64
recorded on the record face 44 of the sheet. This sheet alone or
carried on a suitable support can be used with a transfer member of
the carbon ribbon or carbon paper type to produce direct reading
copies of the indicia recorded on the upper surface of the sheet.
Further, the relief printing member can be attached to a suitable
support and be inked for use as a marking stamp or the like. A
particular advantage of producing a relief printing member in
accordance with the above process is that it is possible by this
method to obtain a level printing surface of essentially uniform
caliber.
A polypropylene printing plate produced in the manner described
above has been used to produce high-quality copies using a
nonvolatile, nondrying ink comprising hexylene glycol containing
from about 2 to 10 percent of maleic anhydride rosin condensate
resin (Arochem 404 made by Archer-Daniels-Midland Corporation).
This resin is water insoluable but because of its high acid number
is quite polar. Further it is highly soluble in glycol which is
itself water soluble and somewhat hydroscopic. The ink is stable on
an applicator felt but will precipitate the resin on absorption of
moisture from the paper.
It will be understood that various modifications in the methods of
fabrication and in the structure and use of the composing and the
printing members may be affected by the application of knowledge
familiar to those skilled in the pertinent arts without departing
from the spirit and scope of the invention. For example,
advantageous results can be obtained by employing a magnetic
material to fill the cells of the composing member. Further, as
shown in FIG. 8, relief printing plates 80 of the type described
herein can be produced by bonding to the activated areas of the
recording medium discrete particles 82 of solid material having
essentially the same dimensions, such as for example nonfriable
particles having a diameter in the range of from about 10 to 80
microns. Suitable particles are for example, ceramic or glass beads
of suitable dimensions which can be applied to the tacky areas of
the recording medium. Another aspect of the invention involves the
utilization of indicia-composing elements having a liquid-filled
synthetic resin structure comprising a porous resin base and
liquids expressible therefrom under pressure or the use of micro
capsules containing ink. In another embodiment of the present
invention suitable printing plates can be prepared utilizing a
plastic sheet having a multicellular surface prepared in the manner
described above in which only selected cells are filled with solid
material and the unfilled cells define imaged areas in the printing
surface. Such printing plates can be prepared, for example, by the
use of masking techniques in which selected cells are masked so
that these will remain empty when the plastisol is doctored across
the multicellular surface. A number of such modifications have been
mentioned above, and others will surely occur as aforesaid in
adapting the teachings of the present invention to specific
printing applications.
* * * * *