U.S. patent number 3,569,610 [Application Number 04/866,611] was granted by the patent office on 1971-03-09 for ethylene-propylene rubber insulated cable with cross-linked polyethylene strand shielding.
This patent grant is currently assigned to General Cable Corporation. Invention is credited to Louis A. Bopp, George S. Eager, Jr., Oscar G. Garner.
United States Patent |
3,569,610 |
Garner , et al. |
March 9, 1971 |
ETHYLENE-PROPYLENE RUBBER INSULATED CABLE WITH CROSS-LINKED
POLYETHYLENE STRAND SHIELDING
Abstract
A high-tension cable is made with a strand shield of
cross-linked, conductive polyethylene compound and with insulation
that is a proprietary compound of ethylene-propylene rubber. The
insulation is approximately 48 percent ethylene-propylene amorphous
copolymer; approximately 12 percent crystalline polyethylene
homopolymer; and reinforcing fillers to provide adequate physical
properties. The shield and insulation are extruded and cured
simultaneously to obtain void-free bonding.
Inventors: |
Garner; Oscar G. (Riverside,
CT), Eager, Jr.; George S. (Upper Montclair, NJ), Bopp;
Louis A. (Fair Haven, NJ) |
Assignee: |
General Cable Corporation (New
York, NY)
|
Family
ID: |
25347984 |
Appl.
No.: |
04/866,611 |
Filed: |
October 15, 1969 |
Current U.S.
Class: |
174/102R;
174/107; 29/828; 174/110AR |
Current CPC
Class: |
H01B
3/441 (20130101); B29C 48/06 (20190201); H01B
13/14 (20130101); B29C 48/304 (20190201); H01B
13/141 (20130101); B29C 48/022 (20190201); H01B
7/02 (20130101); B29C 48/05 (20190201); B29L
2031/3462 (20130101); Y10T 29/49123 (20150115); B29K
2105/20 (20130101); B29K 2301/10 (20130101); B29K
2101/10 (20130101) |
Current International
Class: |
B29C
47/00 (20060101); B29C 47/06 (20060101); H01B
3/44 (20060101); H01B 13/06 (20060101); H01B
13/14 (20060101); H01B 7/02 (20060101); H01b
011/06 () |
Field of
Search: |
;174/102,102.2,105.1,106.2,107,110.3,110.4,110.44,(Shield) ;156/51
;264/174 |
References Cited
[Referenced By]
U.S. Patent Documents
Foreign Patent Documents
|
|
|
|
|
|
|
653,518 |
|
Dec 1962 |
|
CA |
|
703,930 |
|
Feb 1965 |
|
CA |
|
1,150,690 |
|
Apr 1969 |
|
GB |
|
Primary Examiner: Askin; Laramie E.
Assistant Examiner: Grimley; A. T.
Claims
We claim:
1. An electrical cable comprising a conductor, semiconducting
polydetin shield on the conductor, and insulation surrounding the
shield and said insulation comprising an ethylene-propylene rubber
compound containing also a polyolefin that fusion bonds to the
shield.
2. The electrical cable described in claim 1 characterized by the
shield being polyethylene and the ethylene-propylene rubber
compound containing polyethylene that fusion bonds to the
shield.
3. The electrical cable described in claim 2 characterized by the
ethylene-propylene copolymer of the insulation compound being
amorphous and the polyethylene of the insulation being
crystalline.
4. The electrical cable described in claim 1 characterized by the
conductor being stranded, the shield being a smooth coating on the
conductor, and the ethylene-propylene rubber compound being cured
and bonded to the shield but free of radial pressure sufficient to
force the shield into the interstices of the stranded
conductor.
5. The electrical cable described in claim 3 characterized by the
ethylene-propylene rubber compound containing approximately 20 to
80 percent by weight of ethylene-propylene copolymer and
approximately 0 to 46 percent by weight of polyethylene, the
balance being reinforcing and filler materials.
6. The electrical cable described in claim 5 characterized by the
ethylene-propylene copolymer being approximately 48 percent of the
insulation and the polyethylene being approximately 12 percent of
the insulation.
7. The electrical cable described in claim 1 characterized by the
conductor shield being a cross linked polyethylene having a higher
softening point than that of the insulation before curing of the
shield and insulation.
8. The electrical cable described in claim 1 characterized by both
the shield and the insulation being circumferentially and
longitudinally continuous layers extruded over the conductor and
the shield, respectively.
9. The electrical cable described in claim 2 characterized by the
materials for the shield and for the insulation being both
formulated with a dicumyl peroxide curative system so that the
shield and the insulation are cross linked to one another.
10. The electrical cable described in claim 2 characterized by an
insulating shield of material from the group consisting of
conducting cross linked polyethylene, conducting
ethylene-propylene, and rubber.
Description
SUMMARY OF THE INVENTION
This invention provides an improved electrical cable for
high-voltage power transmission. The cable has improved resistance
to ozone and corona discharge; excellent insulating characteristics
and aging properties, and greater flexibility that permits bending
through shorter radii. The invention also provides a construction
in which the conductor shielding is not forced into the interstices
of a stranded conductor and this aids splicing and terminating
operations by leaving a clean, free stripped conductor. The
invention includes also a method of making the improved cable.
The two compounds are applied to a suitable conductor (i.e., copper
stranded wire), preferably in a tandem extrusion operation, and are
cured simultaneously. The strand shield of conductive chemically
cross-linkable polyethylene is applied in the first stage of the
tandem extrusion process, and provides a smooth outer surface upon
which to apply the insulating compound. Being firm and of high
green strength, and having a low coefficient of friction after a
short period of air cooling following extrusion at elevated
temperature, the strand shielding compound of conductive
cross-linkable polyethylene may be passed through the guide tip of
the second extruder, which applies the insulation compound, while
still preserving the electrically desirable smooth outer surface of
the strand shielding material. At this stage of the process, the
lower processing temperature of the ethylene-propylene rubber
compound, as opposed to the processing temperature of the
cross-linked polyethylene shielding compound, plays an important
part in maintaining the original smooth shape of the cross-linkable
conductive polyethylene layer previously extruded.
Extruded strand shielding of chemically cross-linked polyethylene
has numerous desirable features compared with an extruded rubber or
rubber-like material such as an ethylene-propylene rubber
conductive compound. The low coefficient of friction makes it
unnecessary to use a lubricant in order to pass it through the
guider tip of the second extruder. Such lubricant is commonly an
oil such as dimethyl naphthalene or naphthenic petroleum oil having
penetrating properties that can produce side effects such as
gassing at the interface of the compounds during subsequent curing
operations, or may promote an undesired softening of both compounds
at the interface, and may also have a deleterious effect on
physical, aging and electrical characteristics due to migration
into the insulation compound. The advantages of an extruded shield
in lieu of a semiconducting fabric tape are, of course, well
known.
The ethylene-propylene rubber compound is advantageous because it
is extremely resistant to ozone and corona discharge, and has
excellent electrical insulating characteristics, and aging
properties. It is flexible, and enables bending through much
shorter radii than a similar cable utilizing cross-linked
polyethylene as the insulation.
Unlike cross-linked polyethylene compounds which shrink
considerably after curing, the ethylene-propylene rubber compound
can be extruded through a die with a diameter equal to the desired
diameter of the cured insulation. The lack of shrinkage of the
ethylene-propylene rubber wall during and after cure, enables the
concentricity and surface smoothness of the underlying strand
shielding compounds to be maintained, and further does not force it
into the interstices of the stranded conductor, thereby aiding in
splicing and terminating operations associated with cable
installations by leaving a clean, free stripped conductor.
Other objects, features and advantages of the invention will appear
or be pointed out as the description proceeds.
BRIEF DESCRIPTION OF DRAWING
In the drawing, forming a part hereof, in which like reference
characters indicate corresponding parts in all the views:
FIG. 1 is a sectional view of a power cable made in accordance with
this invention;
FIG. 2 is a diagrammatic illustration of apparatus for making the
power cable of this invention; and
FIG. 3 is a flow diagram for the method of this invention.
DESCRIPTION OF PREFERRED EMBODIMENT
FIG. 1 shows a power cable having a stranded conductor 10; a
conductor shield 12; and insulation 14. This invention is concerned
with the application of the shield 12 and the insulation 14 and
with the combination of material used for the shield and
insulation. The cable shown in FIG. 1 has insulation shielding 16
and an outer jacket 18 which may be conventional. The insulation
shielding may be conducting cross-linked polyethylene, conducting
polyethylene, conducting ethylene-propylene amorphous terpolymer of
copolymer, conducting tapes, etc.
In the preferred method of making a cable in accordance with this
invention, the conductor 10 is supplied to a strand shield extruder
22 (FIG. 2) in which the strand shield 12 is applied to the
conductor 10 by an extrusion die 24.
The material used for the shield or shield layer 12 is a compound
of conductive cross-linked polyethylene. This material is applied
in a thin layer of between.
The strand shielding 12 cools rapidly because of its thin section
and because of the heat sink effect of the conductor 10.
FIG. 2 shows a second extruder 26, arranged in tandem with the
extruder 24, for extruding a layer of insulation over the shielded
conductor which is indicated by the reference character 10'. The
shielded conductor 10' passes from the extruder 22 to a guide tip
28 of the second extruder 26.
The low coefficient of friction of the polyethylene shield on the
shielded conductor 10' makes it unnecessary to use a lubricant in
order to pass the shielded conductor through the guide tip 28, as
previously explained.
The extruder 26 applies the insulation 14 to the shielded conductor
10' through an extruder die 30; and the insulated conductor is
indicated by the reference character 10".
The insulation applied by the extruder 26 is a particular
formulation of an ethylene-propylene rubber compound having a
higher-than-normal polymer content. Ordinarily, ethylene-propylene
copolymer rubber compounds designed for high-voltage service,
contain about 30 to 45 percent by weight of polymer. The compound
used for this invention contains approximately 48 percent of
ethylene-propylene copolymer, which is amorphous, and 12 percent
polyethylene homopolymer which is crystalline. However, other
compounds containing as little as 51 percent or as much as 80
percent ethylene-propylene copolymer and as little as 0 percent,
and as much as 49 percent polyethylene homopolymer may be used
equally well for this invention. The total of polymer can be as
high as 95 percent and as low as 20 percent.
The amorphous ethylene-propylene copolymer requires reinforcing
filler to provide adequate physical properties, while the addition
of filler actually reduces the physical properties of the
polyethylene component.
In the insulating compound of this invention, however, the
polyethylene does provide reinforcement and raises the physical
properties to a desired level while also enhancing the electrical
properties of the compound. Thus, the necessary but electrically
undesirable filler is kept to a minimum, while the polymer content
can be maintained at a much higher level than is generally
considered processable. The balance of processing properties,
desired physical strength level, and extraordinarily good
electrical properties is, therefore, achieved by this invention.
The insulated conductor 10' passes from the extruder 26 to a curing
oven 34 in which the shielding layer and insulating layer are cured
simultaneously. By use of chemically cross-linked polyethylene as
the conductor strand shield, and an ethylene propylene copolymer
insulation which contains polyethylene, excellent adhesion of the
shield and insulation is achieved. The lack of shrinkage of the
ethylene-propylene rubber insulation during and after cure enables
the concentricity and surface smoothness of the underlying strand
shielding compound to be maintained and avoids forcing of the
shielding compound into the interstices of stranded conductor, as
previously explained.
The cocured layers of shield and insulation are chemically cross
linked to one another in the oven 34 by formulating both compounds
with a dicumyl peroxide curative system, or with an equivalent
agent which causes both layers to cure at about the same rate. Any
gasses which form at the interface of the shield and insulation as
byproducts of the cure, are rapidly and readily absorbed by the
ethylene-propylene rubber compound so as to produce a void-free
interface. The higher-than-normal polymer content of the rubber
insulation further provides for higher-than-normal reactive sites
at the interface so that a strong, uniform degree of bonding is
obtained along the full length of the cable.
The preferred embodiment of the invention has been illustrated and
described and the invention is defined in the appended claims.
* * * * *