U.S. patent number 10,288,975 [Application Number 15/803,996] was granted by the patent office on 2019-05-14 for electrophoretic dispersion including charged pigment particles, uncharged additive nanoparticles, and uncharged neutral density particles.
This patent grant is currently assigned to E INK CALIFORNIA, LLC. The grantee listed for this patent is E Ink California, LLC. Invention is credited to Peter B. Laxton, Robert A. Sprague, Bo-Ru Yang.
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United States Patent |
10,288,975 |
Sprague , et al. |
May 14, 2019 |
Electrophoretic dispersion including charged pigment particles,
uncharged additive nanoparticles, and uncharged neutral density
particles
Abstract
The present invention is directed to an electrophoretic
dispersion comprising charged pigment particles, in particular, an
electrophoretic dispersion including both uncharged or lightly
charged neutral buoyancy particles and uncharged or lightly charged
additive particles. The combination improves the performance of an
electrophoretic display, in particular the color state stability
over time.
Inventors: |
Sprague; Robert A. (Saratoga,
CA), Yang; Bo-Ru (Banqiao, TW), Laxton; Peter
B. (Marshfield, MA) |
Applicant: |
Name |
City |
State |
Country |
Type |
E Ink California, LLC |
Fremont |
CA |
US |
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Assignee: |
E INK CALIFORNIA, LLC (Fremont,
CA)
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Family
ID: |
61240481 |
Appl.
No.: |
15/803,996 |
Filed: |
November 6, 2017 |
Prior Publication Data
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Document
Identifier |
Publication Date |
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US 20180059500 A1 |
Mar 1, 2018 |
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Related U.S. Patent Documents
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Application
Number |
Filing Date |
Patent Number |
Issue Date |
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14715379 |
May 18, 2015 |
9835926 |
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13847888 |
Jun 9, 2015 |
9052564 |
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61613833 |
Mar 21, 2012 |
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Current U.S.
Class: |
1/1 |
Current CPC
Class: |
G02F
1/167 (20130101); G02F 2001/1678 (20130101) |
Current International
Class: |
G02B
26/00 (20060101); G02F 1/167 (20190101); G09G
3/34 (20060101); G02F 1/1675 (20190101) |
Field of
Search: |
;359/296 |
References Cited
[Referenced By]
U.S. Patent Documents
Foreign Patent Documents
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.
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.
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.
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|
Primary Examiner: Hasan; Mohammed A
Attorney, Agent or Firm: Bean; Brian D.
Parent Case Text
RELATED APPLICATIONS
This application is a continuation-in-part of U.S. application Ser.
No. 14/715,379, filed May 18, 2015, which is a continuation-in-part
of U.S. application Ser. No. 13/847,888, filed Mar. 20, 2013, now
U.S. Pat. No. 9,052,564, which claims priority to U.S. Provisional
Application No. 61/613,833, filed Mar. 21, 2012; the contents of
both are incorporated herein by reference in their entirety.
Claims
What is claimed is:
1. An electrophoretic dispersion comprising: a solvent or solvent
mixture; two different species of charged pigment particles having
opposite charge polarities, wherein each species has a different
color, and wherein each species of charged pigment particles has an
average diameter between 50 nm and 1 .mu.m; uncharged or lightly
charged additive particles having an average diameter between 10 nm
and 250 nm and being present in the electrophoretic dispersion at a
concentration between 5% and 40% by volume of the electrophoretic
dispersion; and uncharged or lightly charged neutral buoyancy
particles having an average diameter between 100 nm and 5 .mu.m and
being present in the electrophoretic dispersion at a concentration
between 0.3% and 20% by weight of electrophoretic dispersion.
2. The dispersion of claim 1, wherein the concentration of the
additive particles is between 5% and 30% by volume of the
electrophoretic dispersion.
3. The dispersion of claim 1, wherein the additive particles are
formed from a polymer, metal, or metal oxide.
4. The dispersion of claim 1, wherein the additive particles are
formed from polystyrene, poly(2-vinylnapthalene), poly(methyl
methacrylate), titanium dioxide, silicon dioxide, silver, or
gold.
5. The dispersion of claim 1, wherein the uncharged or lightly
charged neutral buoyancy particles comprise a polymeric
material.
6. The dispersion of claim 5, wherein the uncharged or lightly
charged neutral buoyancy particles are formed from polyacrylate,
poly(methacrylate), polystyrene, polyaniline, polypyrrole, or
polysiloxane.
7. The dispersion of claim 5, wherein the uncharged or lightly
charged neutral buoyancy particles are formed from
poly(pentabromophenyl methacrylate), poly(2-vinylnapthalene),
poly(naphthyl methacrylate), poly(alpha-methystyrene),
poly(N-benzyl methacrylamide), or poly(benzyl methacrylate).
8. The dispersion of claim 1, wherein the refractive index of the
uncharged or lightly charged neutral buoyancy particles is
different from that of the solvent or solvent mixture of the
electrophoretic dispersion.
9. The dispersion of claim 1, wherein the average diameter of the
additive particles is smaller than the average diameter of the
neutral buoyancy particles.
10. The dispersion of claim 1, further comprising a charge control
agent.
11. The dispersion of claim 1, wherein the uncharged or lightly
charged neutral buoyancy particles are white.
Description
FIELD OF THE INVENTION
The present invention is directed to an electrophoretic dispersion,
in particular, an electrophoretic dispersion comprising uncharged
or lightly charged additive particles for improving bistability of
an electrophoretic display.
BACKGROUND OF THE INVENTION
An electrophoretic display (EPD) is a non-emissive device based on
the electrophoresis phenomenon influencing charged pigment
particles suspended in a dielectric solvent. An EPD typically
comprises a pair of spaced-apart plate-like electrodes. At least
one of the electrode plates, typically on the viewing side, is
transparent. An electrophoretic dispersion composed of a dielectric
solvent with charged pigment particles dispersed therein is
enclosed between the two electrode plates.
An electrophoretic dispersion may have one type of charged pigment
particles dispersed in a solvent or solvent mixture of a
contrasting color. In this case, when a voltage difference is
imposed between the two electrode plates, the pigment particles
migrate by attraction to the plate of polarity opposite that of the
pigment particles. Thus, the color showing at the transparent plate
can be either the color of the solvent or the color of the pigment
particles. Reversal of plate polarity will cause the particles to
migrate to the opposite plate, thereby reversing the color.
Alternatively, an electrophoretic dispersion may comprise two types
of pigment particles of contrasting colors and carrying opposite
charges and the two types of pigment particles are dispersed in a
clear solvent or solvent mixture. In this case, when a voltage
difference is imposed between the two electrode plates, the two
types of pigment particles would move to opposite ends. Thus one of
the colors of the two types of the pigment particles would be seen
at the viewing side.
For all types of electrophoretic display, the dispersion contained
within the individual display cells of the display is one of the
most crucial parts of the device. The composition of the dispersion
determines, to a large extent, the lifetime, contrast ratio,
switching rate and bistability of the device.
BRIEF DESCRIPTION OF THE DRAWINGS
FIG. 1 depicts how the additive nanoparticles may induce
flocculation or weak agglomeration of the charged pigment
particles.
SUMMARY OF THE PRESENT INVENTION
The present invention is directed to an electrophoretic dispersion
comprising charged pigment particles and uncharged or lightly
charged additive particles dispersed in a solvent or solvent
mixture wherein the average diameter of the additive particles is
between 10 nm and 250 nm.
In one embodiment, the dispersion comprises two types of charged
pigment particles having opposite charge polarities and of
contrasting colors. In one embodiment, the additive particles are
formed from a polymer, metal or metal oxide. In one embodiment, the
additive particles are formed from polystyrene,
poly(2-vinylnapthalene), polymethylmethacrylate, titanium dioxide,
silicon dioxide or gold. In one embodiment, the concentration of
the additive particles is from about 5% to about 40% by volume of
the dispersion, e.g., between from about 10% to about 30% by volume
of the dispersion. In one embodiment, the charged pigment particles
have a hydrodynamic diameter in the range of 0.1 .mu.m to 1
.mu.m.
In one embodiment, the dispersion further comprises uncharged or
lightly charged neutral buoyancy particles. In one embodiment, the
uncharged or lightly charged neutral buoyancy particles are formed
from a polymeric material. In one embodiment, the uncharged or
lightly charged neutral buoyancy particles are formed from
polyacrylate, polymethacrylate, polystyrene, polyaniline,
polypyrrole, polyphenol or polysiloxane. In one embodiment, the
uncharged or lightly charged neutral buoyancy particles are formed
from poly(pentabromophenyl methacrylate), poly(2-vinylnapthalene),
poly(naphthyl methacrylate), poly(alpha-methystyrene),
poly(N-benzyl methacrylamide) or poly(benzyl methacrylate).
In one embodiment, the refractive index of the uncharged or lightly
charged neutral buoyancy particles is different from that of the
solvent or solvent mixture in which the particles are dispersed. In
one embodiment, the uncharged or lightly charged neutral buoyancy
particles are light-scattering. In one embodiment, the average
diameter of the uncharged or lightly charged neutral buoyancy
particles is in the range of about 100 nanometers to about 5
microns.
In one embodiment, the average diameter of the additive particles
is smaller than the average diameter of the neutral buoyancy
particles. For example, the average diameter is between 10 nm and
250 nm, e.g., between 20 nm and 100 nm. In one embodiment, the
concentration of the uncharged or lightly charged neutral buoyancy
particles in the electrophoretic dispersion is between 0.3% and 20%
by weight of electrophoretic dispersion, e.g., between 0.5% and 10%
by weight of electrophoretic dispersion. Alternatively, the
concentration may not exceeding about 30% by weight. For example,
the concentration may be at least 2.5% by weight, but not exceeding
about 25% by weight.
DETAILED DESCRIPTION OF THE INVENTION
Prior to the present invention, it was proposed that image
bistability of an electrophoretic display may be improved by
dissolving a polymer into an electrophoretic dispersion. However
the usefulness of this approach is limited because dissolving a
polymer in the dispersion would increase the viscosity of the
dispersion, resulting in an increase in the switching time.
The present inventors now have found that by adding uncharged or
lightly charged particles into an electrophoretic dispersion, the
bistability of an electrophoretic display may be improved, without
significantly affecting the switching speed. For brevity, this type
of particles is referred to as "additive particles" throughout this
application.
The term "lightly charged" is defined as having a charge which is
less than 50%, preferably less than 25% and more preferably less
than 10%, of the average charge carried by the positively charged
pigment particles or negatively charged pigment particles.
The charge intensity may be measured in terms of zeta potential. In
one embodiment, the zeta potential is determined by Colloidal
Dynamics AcoustoSizer IIM with a CSPU-100 signal processing unit,
flow through cell (K:127). The instrument constants, such as
density of the solvent used in the sample, dielectric constant of
the solvent, speed of sound in the solvent, viscosity of the
solvent, all of which at the testing temperature (25.degree. C.)
are entered before testing. Pigment samples are dispersed in the
solvent (which is usually a hydrocarbon fluid having less than 12
carbon atoms), and diluted to between 5-10% by weight. The sample
also contains a charge control agent (Solsperse 17000.RTM.,
available from Lubrizol Corporation, a Berkshire Hathaway company;
"Solsperse" is a Registered Trade Mark), with a weight ratio of
1:10 of the charge control agent to the particles. The mass of the
diluted sample is determined and the sample is then loaded into the
flow through cell for determination of the zeta potential.
The additive particles may be prepared from a material such as a
polymer, metal, metal oxide or the like. For example, they may be
formed from polystyrene, poly(2-vinylnapthalene),
polymethylmethacrylate, titanium dioxide, silicon dioxide, silver,
or gold.
Spherical polymer particles may be prepared in the usual way. For
example, in dispersion polymerization, a stabilizing agent which is
compatible with the electrophoretic dispersion may be added. In
this case, the size of the polymer particles can be precisely
controlled by the recipe of the polymerization reaction.
Specifically, a higher ratio of the stabilizing agent to the
monomer tends to result in smaller particles.
Silica particles of controlled size may be prepared by the Stober
process and its modern variants.
Metal nanoparticles, on the other hand, may be synthesized by
reduction of an aqueous metal salt solution, for example, citrate
synthesis of gold nanoparticles. In the case of metal particles,
any of several techniques for size control may be used. For
example, a higher concentration of a reducing agent tends to result
in smaller particles. In the case of metal and metal oxide
particles, care must also be taken to use an appropriate
stabilizing agent for the eletrophoretic dispersion.
FIG. 1 depicts how the additive particles (11) may induce
flocculation or weak agglomeration of the charged pigment particles
(12). In this FIGURE, the charged pigment particles (12) are shown
to have a depletion zone (13) where the additive particles (11) are
excluded due to their size. During switching, an electric field
forces the charged pigment particles to be packed densely, which
squeezes out the additive particles from the zone between the
charged pigment particles. In the packed state, the energy state of
the system tends to be at a lower level than that when the charged
pigment particles are dispersed. This is due to the fact that the
high energy depletion zones around the charged pigment particles
overlap, thus reducing the total depletion zone volume. The
resulting packed state therefore is stable and resists change, for
example, spontaneous redistribution of the charged pigment
particles by Brownian motion which in an electrophoretic display is
manifest as an image state decay, known as bistability loss.
When a change of the display state is desired, a reverse electric
field is applied which pulls the charged pigment particles apart,
allowing the additive particles to become uniformly dispersed among
the charged pigment particles. Because of the depletion
flocculation energy, this change in state requires a voltage to
separate the charged pigment particles. But once that happens, the
charged pigment particles move through the dispersion which has a
relatively low viscosity associated with the uniformly dispersed
state.
The additive particles have certain characteristics. First of all,
the particles must be colloidally stable against agglomeration,
sedimentation (or creaming) or adsorption. In other words, they
must energetically prefer the dispersed state over being adsorbed
onto the charged pigment particles or walls that surround the
electrophoretic dispersion.
Secondly, they must maintain a specific size relative to the
charged pigment particles. The average diameter of the additive
particles is about 1% to about 25% of the average hydrodynamic
diameter of the charged pigment particles. For example, the average
diameter of the additive particles may between 1 nm and 500 nm,
e.g., between 5 nm and 250 nm, e.g., between 10 nm and 100 nm.
While the primary particle size of the charged pigment particles is
often in the range of 50 nm to 500 nm, their dispersed hydrodynamic
size is often substantially larger. The charged pigment particles
usually have an average hydrodynamic diameter in the approximate
range of 0.1 .mu.m to 1 .mu.m. It is this larger hydrodynamic size
that must be considered when additive particles are included.
Therefore, the additive particles, in most cases, are
nanoparticles.
Thirdly, the concentration of the additive particles should be
controlled within from about 0.1% to about 40%, preferably about
0.3% to about 20%, by volume of the dispersion. This concentration
range is critical in order for the additive particles to be
effective in improving bistability of an electrophoretic display.
In addition, the refractive index of the additive particles is
preferably similar to that of the solvent or solvent mixture in
which they are dispersed. A final consideration unique to an
electrophoretic display is that it is preferred that the particles
are uncharged or lightly charged (i.e., substantially less charged
than the charged pigment particles). The additive particles may be
present in an electrophoretic dispersion comprising one type of
charged pigment particles, two types of charged pigment particles
or multiple types of charged pigment particles.
The charged pigment particles may be formed from an inorganic
pigment, such as TiO.sub.2, ZrO.sub.2, ZnO, Al.sub.2O.sub.3, CI
pigment black 26 or 28 or the like (e.g., manganese ferrite black
spinel or copper chromite black spinel). They may also be formed
from an organic pigment such as phthalocyanine blue, phthalocyanine
green, diarylide yellow, diarylide AAOT yellow, and quinacridone,
azo, rhodamine, perylene pigment series from Sun Chemical, Hansa
yellow G particles from Kanto Chemical, and Carbon Lampblack from
Fisher. The charged pigment particles may also be particles coated
with a polymer layer on their surface, and the polymer coating can
be prepared through various conventionally known polymerization
techniques. The charged pigment particles may carry a natural
charge or are charged through the presence of a charge controlling
agent.
The solvent or solvent mixture in which the charged pigment
particles are dispersed preferably has a low viscosity and a
dielectric constant in the range of about 2 to about 30, preferably
about 2 to about 15 for high particle mobility. Examples of
suitable dielectric solvent include hydrocarbons such as isopar,
decahydronaphthalene (DECALIN), 5-ethylidene-2-norbornene, fatty
oils, paraffin oil; silicon fluids; aromatic hydrocarbons such as
toluene, xylene, phenylxylylethane, dodecylbenzene and
alkylnaphthalene; halogenated solvents such as perfluorodecalin,
perfluorotoluene, perfluoroxylene, dichlorobenzotrifluoride,
3,4,5-trichlorobenzotri fluoride, chloropentafluoro-benzene,
dichlorononane, pentachlorobenzene; and perfluorinated solvents
such as FC-43, FC-70 and FC-5060 from 3M Company, St. Paul Minn.,
low molecular weight halogen containing polymers such as
poly(perfluoropropylene oxide) from TCI America, Portland, Oreg.,
poly(chlorotrifluoro-ethylene) such as Halocarbon Oils from
Halocarbon Product Corp., River Edge, N.J., perfluoropolyalkylether
such as Galden from Ausimont or Krytox Oils and Greases K-Fluid
Series from DuPont, Delaware, polydimethylsiloxane based silicone
oil from Dow-coming (DC-200). The solvent or solvent mixture may be
colored by a dye or pigment.
In addition to the uncharged or lightly charged additive particles,
the dispersion may further comprise uncharged or lightly charged
neutral buoyancy particles. The term "neutral buoyancy" refers to
particles which do not rise or fall with gravity. In other words,
the particles would float in the dispersion between the two
electrode plates. In one embodiment, the density of the neutral
buoyancy particles may be the same as the density of the solvent or
solvent mixture in which they are dispersed.
The uncharged or lightly charged neutral buoyancy particles may be
formed from a polymeric material. The polymeric material may be a
copolymer or a homopolymer. Examples of the polymeric material for
the uncharged or lightly charged neutral buoyancy particles may
include, but are not limited to, polyacrylate, polymethacrylate,
polystyrene, polyaniline, polypyrrole, polyphenol, polysiloxane or
the like. More specific examples of the polymeric material may
include, but are not limited to, poly(pentabromophenyl
methacrylate), poly(2-vinylnapthalene), poly(naphthyl
methacrylate), poly(alpha-methystyrene), poly(N-benzyl
methacrylamide) or poly(benzyl methacrylate). These materials are
suitable for the neutral buoyancy particles in one particle system,
two particle system, and multiple particle system.
More preferably, the uncharged or lightly charged neutral buoyancy
particles are formed from a polymer which is not soluble in the
dielectric solvent of the display dispersion, and also has a high
refractive index. In one embodiment, the refractive index of the
uncharged or lightly charged neutral buoyancy particles is
different from that of the solvent or solvent mixture in which the
particles are dispersed. However, typically the refractive index of
the uncharged or lightly charged neutral buoyancy particles is
higher than that of the solvent or solvent mixture. In some cases,
the refractive index of the uncharged or lightly charged neutral
buoyancy particles may be above 1.45.
In one embodiment, the materials for the uncharged or lightly
charged neutral buoyancy particles may comprise an aromatic
moiety.
The uncharged or lightly charged neutral buoyancy particles may be
prepared from monomers through polymerization techniques, such as
suspension polymerization, dispersion polymerization, seed
polymerization, soap-free polymerization, emulsion polymerization
or physical method, including inverse emulsification-evaporation
process. The monomers are polymerized in the presence of a
dispersant. The presence of the dispersant allows the polymer
particles to be formed in a desired size range and the dispersant
may also form a layer physically or chemically bonded to the
surface of the polymer particles to prevent the particles from
agglomeration.
The dispersants preferably has a long chain (of at least eight
atoms), which may stabilize the polymer particles in a hydrocarbon
solvent. Such dispersants may be an acrylate-terminated or
vinyl-terminated macromolecule, which are suitable because the
acrylate or vinyl group can co-polymerize with the monomer in the
reaction medium.
One specific example of the dispersant is acrylate terminated
polysiloxane (Gelest, MCR-M17, MCR-M22),
Another type of suitable dispersants is polyethylene macromonomers,
as shown below:
CH.sub.3--[-CH.sub.2-].sub.n--CH.sub.2O--C(.dbd.O)--C(CH.sub.3).dbd.CH.su-
b.2
The backbone of the macromonomer may be a polyethylene chain and
"n" may be 30-200. The synthesis of this type of macromonomers may
be found in Seigou Kawaguchi et al, Designed Monomers and Polymers,
2000, 3, 263.
If the dispersion system is fluorinated, the dispersants are then
preferably also fluorinated.
Alternatively, the uncharged or lightly charged neutral buoyancy
particles may also be formed from a core particle coated with a
polymeric shell and the shell may be formed, for example, from any
of the polymeric material identified above for the neutral buoyancy
particles.
The core particle may be of an inorganic pigment or an organic
pigment as described above.
In the case of core-shell uncharged or lightly charged neutral
buoyancy particles, they may be formed by a microencapsulation
method, such as coacervation, interfacial polycondensation,
interfacial cross-linking, in-suit polymerization or matrix
polymerization.
The average diameter of the uncharged or lightly charged neutral
buoyancy particles is preferably in the range of about 100
nanometers to about 5 micrometers. In one embodiment, the average
diameter of the additive particles is smaller than the average
diameter of the neutral buoyancy particles.
In one embodiment of this aspect of the present invention, the
uncharged or lightly charged neutral buoyancy particles added to
the dispersion may have a color substantially the same as the color
of one of the two types of charged pigment particles. For example,
in a display dispersion, there may be charged black particles,
charged white particles, the uncharged or lightly charged additive
particles and uncharged or lightly charged neutral buoyancy
particles and the uncharged or lightly charged neutral buoyancy
particles may be either white or black.
If the uncharged or lightly charged neutral buoyancy particles are
white, they may enhance the reflectivity of the display. If they
are black, they may enhance the blackness of the display.
In another embodiment, the uncharged or lightly charged neutral
buoyancy particles may have a color substantially different from
the color of either one of the two types of charged pigment
particles.
The presence of the uncharged or lightly charged neutral buoyancy
particles, especially if they are formed from a reflective
material, increases reflection of the incident light, thus
improving the contrast ratio.
In a further embodiment of the present invention, the concentration
of the uncharged or lightly charged neutral buoyancy particles in
an electrophoretic dispersion is preferably more than 0.1% by
weight, e.g., more than 0.3% by weight, e.g., more than 0.5% by
weight, e.g., more than 2.5% by weight, but not exceeding about 40%
by weight, e.g., not exceeding about 30% by weight, e.g., not
exceeding about 20% by weight. In another embodiment, the
concentration of the uncharged or lightly charged neutral buoyancy
particles is preferably in a range between about 0.3% to about 20%
by weight and more preferably in a range between about 0.5% to
about 10% by weight.
The electrophoretic dispersion of the present invention, in
addition to the uncharged or lightly charged additive particles and
uncharged or lightly charged neutral buoyancy particles, may also
comprise other additives such as a charge controlling agent. The
charge control agent (CCA) used in all embodiments of the present
invention is compatible with the solvent in the electrophoretic
dispersion and may interact with the surface of the charged
particles to effectively generate either positive or negative
charge for the particles. Useful charge control agents include, but
are not limited to, sodium dodecylbenzenesulfonate, metal soap,
polybutene succinimide, maleic anhydride copolymers, vinylpyridine
copolymers, vinylpyrrolidone copolymer, (meth)acrylic acid
copolymers or N,N-dimethylaminoethyl (meth)acrylate copolymers),
Alcolec LV30 (soy lecithin), Petrostep B100 (petroleum sulfonate)
or B70 (barium sulfonate), Solsperse 17000 (active polymeric
dispersant), Solsperse 9000 (active polymeric dispersant), OLOA
11000 (succinimide ashless dispersant), OLOA 1200 (polyisobutylene
succinimides), Unithox 750 (ethoxylates), Petronate L (sodium
sulfonate), Disper BYK 101, 2095, 185, 116, 9077 & 220 and
ANTI-TERRA series.
A further aspect of the present invention is directed to an
electrophoretic display wherein display cells are filled with any
of the display dispersions as described in the present
application.
The term "display cell" refers to a micro-container filled with a
display dispersion. A display cell may be a microcell as described
in U.S. Pat. No. 6,930,818, the content of which is incorporated
herein by reference in its entirety. A display cell may also be any
other micro-containers (e.g., microcapsules or microchannels),
regardless of their shapes or sizes. All of these are within the
scope of the present application.
While the present invention has been described with reference to
the specific embodiments thereof, it should be understood by those
skilled in the art that various changes may be made and equivalents
may be substituted without departing from the scope of the
invention. In addition, many modifications may be made to adapt a
particular situation, materials, compositions, processes, process
step or steps, to the objective and scope of the present invention.
All such modifications are intended to be within the scope of the
claims appended hereto.
* * * * *